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Anomalous transport properties of the halfmetallic ferromagnets Co2TiSi, Co2TiGe, and Co2TiSn
In this work the theoretical and experimental investigations of Co2TiZ (Z =
Si, Ge, or Sn) compounds are reported. Half-metallic ferromagnetism is
predicted for all three compounds with only two bands crossing the Fermi energy
in the majority channel. The magnetic moments fulfill the Slater-Pauling rule
and the Curie temperatures are well above room temperature. All compounds show
a metallic like resistivity for low temperatures up to their Curie temperature,
above the resistivity changes to semiconducting like behavior. A large negative
magnetoresistance of 55% is observed for Co2TiSn at room temperature in an
applied magnetic field of 4T which is comparable to the large negative
magnetoresistances of the manganites. The Seebeck coefficients are negative for
all three compounds and reach their maximum values at their respective Curie
temperatures and stay almost constant up to 950 K. The highest value achieved
is -52muV/K m for Co2TiSn which is large for a metal. The combination of
half-metallicity and the constant large Seebeck coefficient over a wide
temperature range makes these compounds interesting materials for
thermoelectric applications and further spincaloric investigations.Comment: 4 pages 4 figure
Local probing of ionic diffusion by electrochemical strain microscopy: spatial resolution and signal formation mechanisms
Electrochemical insertion-deintercalation reactions are typically associated
with significant change of molar volume of the host compound. This strong
coupling between ionic currents and strains underpins image formation
mechanisms in electrochemical strain microscopy (ESM), and allows exploring the
tip-induced electrochemical processes locally. Here we analyze the signal
formation mechanism in ESM, and develop the analytical description of operation
in frequency and time domains. The ESM spectroscopic modes are compared to
classical electrochemical methods including potentiostatic and galvanostatic
intermittent titration (PITT and GITT), and electrochemical impedance
spectroscopy (EIS). This analysis illustrates the feasibility of spatially
resolved studies of Li-ion dynamics on the sub-10 nanometer level using
electromechanical detection.Comment: 49 pages, 17 figures, 4 tables, 3 appendices, to be submitted to J.
Appl. Phys
Spin polarized tunneling in MgO-based tunnel junctions with superconducting electrodes
We prepared magnetic tunnel junctions with one ferromagnetic and one
superconducting Al-Si electrode. Pure cobalt electrodes were compared with a
Co-Fe-B alloy and the Heusler compound Co2FeAl. The polarization of the
tunneling electrons was determined using the Maki-Fulde-model and is discussed
along with the spin-orbit scattering and the total pair-breaking parameters.
The junctions were post-annealed at different temperatures to investigate the
symmetry filtering mechanism responsible for the giant tunneling
magnetoresistance ratios in Co-Fe-B/ MgO/ Co-Fe-B junctions.Comment: 11 pages, 5 figure
Improving thermoelectric performance of TiNiSn by mixing MnNiSb in the half-Heusler structure
The thermoelectric properties of n type semiconductor, TiNiSn is optimized by
partial substitution with metallic, MnNiSb in the half Heusler structure.
Herein, we study the transport properties and intrinsic phase separation in the
system. The Ti1-xMnxNiSn1-xSbx alloys were prepared by arc-melting and were
annealed at temperatures obtained from differential thermal analysis and
differential scanning calorimetry results. The phases were characterized using
powder X-ray diffraction patterns, energy dispersive X-ray spectroscopy, and
differential scanning calorimetry. After annealing the majority phase was
TiNiSn with some Ni rich sites and the minority phases was majorly Ti6Sn5, Sn,
and MnSn2. Ni rich sites were caused by Frenkel defects, this led to a
metal-like behavior of the semiconducting specimens at low temperature. For x
up to 0.05 the samples showed an activated conduction, whereas for x>0.05 they
showed metallic character. The figure of merit for x=0.05 was increased by 61%
(ZT=0.45) in comparison to the pure TiNiSn.Comment: 7 pages and 5 figures. Submitted to Physical Chemistry Chemical
Physics - RSC Publishing on 6th of October, 201
Don't Stop Thinking About Leptoquarks: Constructing New Models
We discuss the general framework for the construction of new models
containing a single, fermion number zero scalar leptoquark of mass GeV which can both satisfy the D0/CDF search constraints as well as
low energy data, and can lead to both neutral and charged current-like final
states at HERA. The class of models of this kind necessarily contain new
vector-like fermions with masses at the TeV scale which mix with those of the
Standard Model after symmetry breaking. In this paper we classify all models of
this type and examine their phenomenological implications as well as their
potential embedding into SUSY and non-SUSY GUT scenarios. The general coupling
parameter space allowed by low energy as well as collider data for these models
is described and requires no fine-tuning of the parameters.Comment: Modified text, added table, and updated reference
Causes and consequences of tipping points in river delta social-ecological systems
The sustainability of social-ecological systems within river deltas globally is in question as rapid development and environmental change trigger "negativeâ or âpositiveâ tipping points depending on actorsâ perspectives, e.g., regime shift from abundant sediment deposition to sediment shortage, agricultural sustainability to agricultural collapse or shift from rural to urban land. Using a systematic review of the literature, we show how cascading effects across anthropogenic, ecological, and geophysical processes have triggered numerous tipping points in the governance, hydrological and land use management of the worldâs river deltas. Crossing tipping points had both positive and negative effects that generally enhanced economic development to the detriment of the environment. Assessment of deltas that featured prominently in the review revealed how outcomes of tipping points can inform the long-term trajectory of deltas towards sustainability or collapse. Management of key drivers at the delta scale can trigger positive tipping points to place social-ecological systems on a pathway towards sustainable development
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