SO₂ emissions from basaltic eruptions, and the excess sulfur issue

Volcanic SO2 can affect the Earth's environment. Where no direct measurements of SO2 in the atmosphere are available, a petrologic method of assessing sulfur release from the magma must be used. However, in studies of arc-derived eruptions, satellite-based measurements of SO2 emissions using Total Ozone Mapping Spectrometer (TOMS) data are orders of magnitude greater than those calculated petrologically, implying that a separate S-rich gas phase in the magma chamber may be responsible for the excess sulfur. We test whether this applies in other settings. For Icelandic and Hawaiian basalts we find that petrologic SO2 values are comparable to measurements of SO2 by TOMS. Thus, for non-arc basalts, the petrologic method gives reliable estimates of SO2 released. The implied absence of excess sulfur in non-arc basaltic magmas is a reflection of source magma conditions, notably lower fO2 and volatile contents than arc magmas, inhibiting the exsolution of a S-rich gas prior to eruption

An investigation of volcanic gases and dust (aerosols) in the stratosphere

There are no author-identified significant results in this report

Interpretation of dispersion relations for bounded systems

Constructing normal modes for bounded systems from infinite dispersion relation roots for interpretation of plasma wave and instability studies on finite cylinder

New ⁴⁰Ar/³⁹Ar dating of the Grande Ronde lavas, Columbia River Basalts, USA: Implications for duration of flood basalt eruption episodes

Grande Ronde Basalt (GRB) lavas represent the most voluminous eruptive pulse of the Columbia River-Snake River-Yellowstone hotspot volcanism. With an estimated eruptive volume of 150,000 km3, GRB lavas form at least 66% of the total volume of the Columbia River Basalt Group. New 40Ar/39Ar dates for GRB lavas reveal they were emplaced within a maximum period of 0.42 ± 0.18 My. A well-documented stratigraphy indicates at least 110 GRB flow fields (or individual eruptions), and on this basis suggests an average inter-eruption hiatus of less than 4,000 years. Isotopic age-dating cannot resolve time gaps between GRB eruptions, and it is difficult to otherwise form a picture of the durations of eruptions because of non-uniform weathering in the top of flow fields and a general paucity of sediments between GR lavas. Where sediment has formed on top of the GRB, it varies in thickness from zero to 20-30 cm of silty to fine-sandy material, with occasional diatomaceous sediment. Individual GRB eruptions varied considerably in volume but many were greater than 1000 km3 in size. Most probably eruptive events were not equally spaced in time; some eruptions may have followed short periods of volcanic repose (perhaps 102 to 103 of yrs), whilst others could have been considerably longer (many 1000 s to > 104 yrs). Recent improvements in age-dating for other continental flood basalt (CFB) lava sequences have yielded estimates of total eruptive durations of less than 1 My for high-volume pulses of lava production. The GRB appears to be a similar example, where the main pulse occupied a brief period. Even allowing for moderate to long-duration pahoehoe flow field production, the amount of time the system spends in active lava-producing mode is small – less than c. 2.6% (based on eruption durations of approximately 10,000 yrs, as compared to the duration of the entire eruptive pulse of c. 420,000 yrs). A review of available 40Ar/39Ar data for the major voluminous phases of the Columbia River Basalt Group suggests that activity of the Steens Basalt-Imnaha Basalt-GRB may have, at times, been simultaneous, with obvious implications for climatic effects. Resolving intervals between successive eruptions during CFB province construction, and durations of main eruptive pulses, remains vital to determining the environmental impact of these huge eruptions

Analysis of Pt/SnO(sub x) during catalysis of CO oxidation

Temperature-programmed reduction using 6kPaH2 suggests that a sample consisting of 3 percent Pt supported directly on SnO2 is, under conditions of catalysis of CO oxidation used here, best represented as 3 percent Pt/SnO sub x, since the support is likely to partially reduced, probably in the vicinity of the metal/oxide interface. Catalytic measurements at 421 to 424 K show that this 3 percent Pt/SnO sub x is significantly more active per unit area of Pt than 6 percent Pt/SiO2 in catalyzing the oxidation of CO. In situ micro-FTIR reveals that while the latter has predominantly linearly bound CO on the surface under reaction conditions, the Pt/SnO sub x also has a species absorbing at 2168 cm(exp -1) which may be CO upon Pt in a positive oxidation state or weakly chemisorbed CO on zero-valent Pt. This may be directly involved in the low temperature oxidation of CO on the Pt/SnO sub x, since being weakly held the activation energy for its surface diffusion to the metal/oxide interface will be low; such mobile species could allow the high rates of surface transport and an increase in the fraction of the surface over which the CO oxidation occurs. FTIR also reveals carbonate-type species on the P/SnO sub c surface

Sulfur, Chlorine and Fluorine Degassing and Atmospheric Loading by the Roza eruption, Columbia River Basalt Group, Washington

In this study we attempt to quantify the amount of S, Cl and F released by the 1300 cu km Roza member (approximately 14.7 Ma) of the Columbia River Basalt Group, which was produced by a moderate-size flood basalt eruption in the mid-Miocene. Our results are the first indication of the potential atmospheric SO2 yield from a flood basalt eruption, and indicate the mechanism by which flood basalt eruptions may have seriously affected the environment. Glass inclusions in phenocrysts and quenched glass in products from various stages of the eruption were analyzed for concentrations of S, Cl and F and major elements. Glass inclusions contain 1965 +/- 110 ppm S, 295 +/- 65 ppm Cl and 1310 +/- 110 ppm F. Groundmass glass of Roza dike selvages contains considerably lower concentrations: 1110 +/- 90 ppm S, 245 +/- 30 ppm Cl and 1020 +/- 25 ppm F. Scoria clasts from near vent deposits contain 665 +/- 75 ppm S, 175 +/- 5 ppm Cl and 950 +/- 20 ppm F, and the groundmass glass of lava selvages contains 520 +/- 30 ppm S, 190 +/- 30 ppm Cl and 890 +/- 55 ppm F. In crystalline lava, the concentrations are 195 ppm S, 100 ppm Cl and 830 ppm F. Volatile element concentrations in these samples represent the progress of degassing through the eruption and can be used to estimate the potential amount of the volatiles S, Cl and F released by the magma into the atmosphere, as well as to evaluate the amount liberated by various phases of the eruption. The total amount of volatiles released by the Roza eruption is estimated to have been approximately 12,420 MtSO2, approximately 710 MtHCI and approximately 1780 MtHF. The Roza magma liberated approximately 9620 MtSO, (77% of the total volatile mass released), approximately 400 MtHCI (56%) and approximately 1450 MtHF (81%) at the vents and lofted by the eruption columns to altitudes of 7-13 km. Degassing of the lava is estimated to have released an additional approximately 2810 MtSO2, approximately 310 MtHCI and approximately 330 MtHF. The Roza eruption is likely to have lasted for approximately 10 years, indicating an annual H2SO4-mass loading of approximately 1800 Mt. Thus, the atmospheric perturbations associated with the Roza eruption may have been of the magnitude predicted for a severe "nuclear" or "volcanic" winter, but lasting up to a decade or more

Engineering geology of British rocks and soils : Lias Group

The report begins with an introduction and a detailed modern assessment of the geology of the Lias Group in terms of both stratigraphy and lithology. The modern lithostratigraphy is placed in the context of the old, and sometimes more familiar, usage. The next two chapters deal with the mineralogy of a suite of samples collected for the project, and an assessment of the nature and influence of weathering based on a detailed analysis of the Lias dataset held in the BGS National Geotechnical Properties Database. The following chapters cover geohazards associated with the Lias Group, and a brief overview of the wide variety of industrial applications for which the Lias is well known. The geotechnical database forms the basis of the penultimate chapter, geotechnical properties. The contents of the database are analysed, interpreted, presented in graphical form, and discussed in terms of statistical variation and in the light of likely engineering behaviour. The engineering geology of the Lias Group is discussed in the final chapter, borrowing from the preceding chapters. A comprehensive cited reference list and a bibliography are provided. In addition to the large number of technical data provided to BGS, a small data set has been generated by BGS laboratories, particularly in areas where the main database was deficient, and also in connection with associated BGS studies of the swelling and shrinkage properties of the Lias Group. The individual items of data making up the database are not attributed. However, the contribution of a wide range of consultancies, contractors, authorities, and individuals is acknowledged. It is hoped that this report will provide a source of useful information to a wide range of engineers, planners, scientists, and other interested parties concerned with Lias Group materials. It should be noted that whilst quantitative technical data are included in this report, these should not be used as a substitute for proper site investigation

Calorimetry, activity, and micro-FTIR analysis of CO chemisorption, titration, and oxidation on supported Pt

The value of in situ analysis on CO chemisorption, titration and oxidation over supported Pt catalysts using calorimetry, catalytic and micro-FTIR methods is illustrated using silica- and titania-supported samples. Isothermal CO-O and O2-CO titrations have not been widely used on metal surfaces and may be complicated if some oxide supports are reduced by CO titrant. However, they can illuminate the kinetics of CO oxidation on metal/oxide catalysts since during such titrations all O and CO coverages are scanned as a function of time. There are clear advantages in following the rates of the catalyzed CO oxidation via calorimetry and gc-ms simultaneously. At lower temperatures the evidence they provide is complementary. CO oxidation and its catalysis of CO oxidation have been extensively studied with hysteresis and oscillations apparent, and the present results suggest the benefits of a combined approach. Silica support porosity may be important in defining activity-temperature hysteresis. FTIR microspectroscopy reveals the chemical heterogeneity of the catalytic surfaces used; it is interesting that the evidence with regard to the dominant CO surface species and their reactivities with regard to surface oxygen for present oxide-supported Pt are different from those seen on graphite-supported Pt

Disruption of Tephra Fall Deposits Caused by Lava Flows during Basaltic Eruptions

Observations in the USA, Iceland and Tenerife, Canary Islands reveal how processes occurring during basaltic eruptions can result in complex physical and stratigraphic relationships between lava and proximal tephra fall deposits around vents. Observations illustrate how basaltic lavas can disrupt, dissect (spatially and temporally) and alter sheet-form fall deposits. Complexity arises through synchronous and alternating effusive and explosive activity that results in intercalated lavas and tephra deposits. Tephra deposits can become disrupted into mounds and ridges by lateral and vertical displacement caused by movement (including inflation) of underlying pāhoehoe lavas and clastogenic lavas. Mounds of tephra can be rafted away over distances of 100 s to 1,000 s m from proximal pyroclastic constructs on top of lava flows. Draping of irregular topography by fall deposits and subsequent partial burial of topographic depressions by later lavas can result in apparent complexity of tephra layers. These processes, deduced from field relationships, have resulted in considerable stratigraphic complexity in the studied proximal regions where fallout was synchronous or alternated with inflation of subjacent lava sheets. These mechanisms may lead to diachronous contact relationships between fall deposits and lava flows. Such complexities may remain cryptic due to textural and geochemical quasi-homogeneity within sequences of interbedded basaltic fall deposits and lavas. The net effect of these processes may be to reduce the usefulness of data collected from proximal fall deposits for reconstructing basaltic eruption dynamics

On the design of an energy-efficient low-latency integrated protocol for distributed mobile sensor networks

Self organizing, wireless sensors networks are an emergent and challenging technology that is attracting large attention in the sensing and monitoring community. Impressive progress has been done in recent years even if we need to assume that an optimal protocol for every kind of sensor network applications can not exist. As a result it is necessary to optimize the protocol for certain scenarios. In many applications for instance latency is a crucial factor in addition to energy consumption. MERLIN performs its best in such WSNs where there is the need to reduce the latency while ensuring that energy consumption is kept to a minimum. By means of that, the low latency characteristic of MERLIN can be used as a trade off to extend node lifetimes. The performance in terms of energy consumption and latency is optimized by acting on the slot length. MERLIN is designed specifically to integrate routing, MAC and localization protocols together. Furthermore it can support data queries which is a typical application for WSNs. The MERLIN protocol eliminates the necessity to have any explicit handshake mechanism among nodes. Furthermore, the reliability is improved using multiple path message propagation in combination with an overhearing mechanism. The protocol divides the network into subsets where nodes are grouped in time zones. As a result MERLIN also shows a good scalability by utilizing an appropriate scheduling mechanism in combination with a contention period