571 research outputs found
The asymptotics of the moving contact line: cracking an old nut
This article has been published in a revised form in Journal of Fluid Mechanics https://doi.org/10.1017/jfm.2014.702. This version is free to view and download for private research and study only. Not for re-distribution, re-sale or use in derivative works. © Cambridge University Press.For contact line motion where the full Stokes flow equations hold, full matched asymptotic solutions using slip models have been obtained for droplet spreading and more general geometries. These solutions to the singular perturbation problem in the slip length, however, all involve matching through an intermediate region that is taken to be separate from the outer-inner regions. Here, we show that the intermediate region is in fact an overlap region representing extensions of both the outer and the inner region, allowing direct matching to proceed. In particular, we investigate in detail how a previously seen result of the matching of the cubes of the free surface slope is justified in the lubrication setting. We also extend this two-region direct matching to the more general Stokes flow case, offering a new perspective on the asymptotics of the moving contact line problem
Wetting on a spherical wall: influence of liquid-gas interfacial properties
We study the equilibrium of a liquid film on an attractive spherical
substrate for an intermolecular interaction model exhibiting both fluid-fluid
and fluid-wall long-range forces. We first reexamine the wetting properties of
the model in the zero-curvature limit, i.e., for a planar wall, using an
effective interfacial Hamiltonian approach in the framework of the well known
sharp-kink approximation (SKA). We obtain very good agreement with a mean-field
density functional theory (DFT), fully justifying the use of SKA in this limit.
We then turn our attention to substrates of finite curvature and appropriately
modify the so-called soft-interface approximation (SIA) originally formulated
by Napi\'orkowski and Dietrich [Phys. Rev. B 34, 6469 (1986)] for critical
wetting on a planar wall. A detailed asymptotic analysis of SIA confirms the
SKA functional form for the film growth. However, it turns out that the
agreement between SKA and our DFT is only qualitative. We then show that the
quantitative discrepancy between the two is due to the overestimation of the
liquid-gas surface tension within SKA. On the other hand, by relaxing the
assumption of a sharp interface, with, e.g., a simple smoothing of the density
profile there, markedly improves the predictive capability of the theory,
making it quantitative and showing that the liquid-gas surface tension plays a
crucial role when describing wetting on a curved substrate. In addition, we
show that in contrast to SKA, SIA predicts the expected mean-field critical
exponent of the liquid-gas surface tension
Assuring Youth Raising Livestock for Food Produce a Quality Product
The Nebraska 4-H Assuring Quality program was developed to help youth producers understand responsibilities of raising livestock for food, increase technical knowledge of quality assurance practices, and implement those practices. Participants\u27 knowledge, attitudes, and practices were determined by surveying parents using a post-then-pre method. Mean retrospective pre-scores showed that youths significantly increased their knowledge, positively changed their attitudes, and implemented better quality assurance management practices in each of the five subject areas taught: (a) quality assurance concepts, (b) feeding and watering, (c) animal identification, (d) housing and facilities and (e) prevention of problems
Fluid structure in the immediate vicinity of an equilibrium three-phase contact line and assessment of disjoining pressure models using density functional theory
We examine the nanoscale behavior of an equilibrium three-phase contact line
in the presence of long-ranged intermolecular forces by employing a statistical
mechanics of fluids approach, namely density functional theory (DFT) together
with fundamental measure theory (FMT). This enables us to evaluate the
predictive quality of effective Hamiltonian models in the vicinity of the
contact line. In particular, we compare the results for mean field effective
Hamiltonians with disjoining pressures defined through (I) the adsorption
isotherm for a planar liquid film, and (II) the normal force balance at the
contact line. We find that the height profile obtained using (I) shows good
agreement with the adsorption film thickness of the DFT-FMT equilibrium density
profile in terms of maximal curvature and the behavior at large film heights.
In contrast, we observe that while the height profile obtained by using (II)
satisfies basic sum rules, it shows little agreement with the adsorption film
thickness of the DFT results. The results are verified for contact angles of
20, 40 and 60 degrees
Reentrant superconductivity in superconductor/ferromagnetic-alloy bilayers
We studied the Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) like state
establishing due to the proximity effect in superconducting Nb/Cu41Ni59
bilayers. Using a special wedge-type deposition technique, series of 20-35
samples could be fabricated by magnetron sputtering during one run. The layer
thickness of only a few nanometers, the composition of the alloy, and the
quality of interfaces were controlled by Rutherford backscattering
spectrometry, high resolution transmission electron microscopy, and Auger
spectroscopy. The magnetic properties of the ferromagnetic alloy layer were
characterized with superconducting quantum interference device (SQUID)
magnetometry. These studies yield precise information about the thickness, and
demonstrate the homogeneity of the alloy composition and magnetic properties
along the sample series. The dependencies of the critical temperature on the Nb
and Cu41Ni59 layer thickness, Tc(dS) and Tc(dF), were investigated for constant
thickness dF of the magnetic alloy layer and dS of the superconducting layer,
respectively. All types of non-monotonic behaviors of Tc versus dF predicted by
the theory could be realized experimentally: from reentrant superconducting
behavior with a broad extinction region to a slight suppression of
superconductivity with a shallow minimum. Even a double extinction of
superconductivity was observed, giving evidence for the multiple reentrant
behavior predicted by theory. All critical temperature curves were fitted with
suitable sets of parameters. Then, Tc(dF) diagrams of a hypothetical F/S/F
spin-switch core structure were calculated using these parameters. Finally,
superconducting spin-switch fabrication issues are discussed in detail in view
of the achieved results.Comment: 34 pages, 9 figure
Cyanobacterial life at low O 2 : community genomics and function reveal metabolic versatility and extremely low diversity in a Great Lakes sinkhole mat
Cyanobacteria are renowned as the mediators of Earthâs oxygenation. However, little is known about the cyanobacterial communities that flourished under the lowâO 2 conditions that characterized most of their evolutionary history. Microbial mats in the submerged Middle Island Sinkhole of Lake Huron provide opportunities to investigate cyanobacteria under such persistent lowâO 2 conditions. Here, venting groundwater rich in sulfate and low in O 2 supports a unique benthic ecosystem of purpleâcolored cyanobacterial mats. Beneath the mat is a layer of carbonate that is enriched in calcite and to a lesser extent dolomite. In situ benthic metabolism chambers revealed that the mats are net sinks for O 2 , suggesting primary production mechanisms other than oxygenic photosynthesis. Indeed, 14 Câbicarbonate uptake studies of autotrophic production show variable contributions from oxygenic and anoxygenic photosynthesis and chemosynthesis, presumably because of supply of sulfide. These results suggest the presence of either facultatively anoxygenic cyanobacteria or a mix of oxygenic/anoxygenic types of cyanobacteria. Shotgun metagenomic sequencing revealed a remarkably lowâdiversity mat community dominated by just one genotype most closely related to the cyanobacterium Phormidium autumnale , for which an essentially complete genome was reconstructed. Also recovered were partial genomes from a second genotype of Phormidium and several Oscillatoria . Despite the taxonomic simplicity, diverse cyanobacterial genes putatively involved in sulfur oxidation were identified, suggesting a diversity of sulfide physiologies. The dominant Phormidium genome reflects versatile metabolism and physiology that is specialized for a communal lifestyle under fluctuating redox conditions and light availability. Overall, this study provides genomic and physiologic insights into lowâO 2 cyanobacterial mat ecosystems that played crucial geobiological roles over long stretches of Earth history.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/90535/1/j.1472-4669.2012.00322.x.pd
The pressure tensor across a liquid-vapour interface
© 2018, The Authors. Inhomogeneous fluids exhibit physical properties that are neither uniform nor isotropic. The pressure tensor is a case in point, key to the mechanical description of the interfacial region. Kirkwood and Buff and, later, Irving and Kirkwood, obtained a formal treatment based on the analysis of the pressure across a planar surface [J. G. Kirkwood and F. P. Buff, J. Chem. Phys. 17(3), 338 (1949); J. H. Irving and J. G. Kirkwood, J. Chem. Phys. 18, 817 (1950)]. We propose a generalisation of Irving and Kirkwoodâs argument to fluctuating, non-planar surfaces and obtain an expression for the pressure tensor that is not smeared by thermal fluctuations at the molecular scale and corresponding capillary waves [F. P. Buff et al., Phys. Rev. Lett. 15, 621â623 (1965)]. We observe the emergence of surface tension, defined as an excess tangential stress, acting exactly across the dividing surface at the sharpest molecular resolution. The new statistical mechanical expressions extend current treatments to fluctuating inhomogeneous systems far from equilibrium.European Research Council (ERC) Advanced Grant No. 247031; Engineering and Physical Sciences Research Council (EPSRC) Grant No. EP/L020564
Nonequilibrium molecular dynamics simulations of nanoconfined fluids at solidliquid interfaces
We investigate the hydrodynamic properties of a Lennard-Jones fluid confined to a nanochannel using molecular dynamics simulations. For channels of different widths and hydrophilic-hydrophobic surface wetting properties, profiles of the fluid density, stress, and viscosity across the channel are obtained and analysed. In particular, we propose a linear relationship between the density and viscosity in confined and strongly inhomogeneous nanofluidic flows. The range of validity of this relationship is explored in the context of coarse grained models such as dynamic density functional-theory
Risk-based due diligence in supply chains: the case of silver for photovoltaics
Supply concentration and environmental, social, governance (ESG) issues constitute important supply risks. With strategic autonomy and responsible sourcing high on the political agenda these risks are especially relevant for the EU. This paper proposes an approach to conduct risk-based due diligence. Using a trade-linked material flow analysis, ESG and dependency hotspots along supply chains can be identified. Silver supply chains for photovoltaics (PV) are taken as case-study. The model traces silver from mining to PV module manufacturing, from 1995 to 2021. The supply of silver powder, paste, PV cells, and modules is found to be highly concentrated. These supply chains are linked to substantial ESG risks, mostly nested in fabrication and manufacturing, some of which have worsened over time. Over 87% of the silver used in PV transits through at least one country with a very high risk factor. Reshoring the PV industry to the EU can partially de-risk supply.Industrial Ecolog
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