1,438 research outputs found
Sterically Congested 2,6-Disubstituted Anilines from Direct CâN Bond Formation at an Iodine(III) Center
2,6-Disubstituted anilines are readily prepared from the direct reaction between amides and diaryliodonium salts. As demonstrated for 24 different examples, the reaction is of unusually broad scope with respect to the sterically congested arene and the nitrogen source, occurs without the requirement for any additional promoter, and proceeds through a direct reductive elimination at the iodine(III) center. The efficiency of the coupling procedure is further demonstrated within the short synthesis of a chemerin binding inhibitor
Simultaneous dynamic electrical and structural measurements of functional materials
A new materials characterization system developed at the XMaS beamline, located at the European Synchrotron Radiation Facility in France, is presented. We show that this new capability allows to measure the atomic structural evolution (crystallography) of piezoelectric materials whilst simultaneously measuring the overall strain characteristics and electrical response to dynamically (ac) applied external stimuli
Energy and Flux Measurements of Ultra-High Energy Cosmic Rays Observed During the First ANITA Flight
The first flight of the Antarctic Impulsive Transient Antenna (ANITA)
experiment recorded 16 radio signals that were emitted by cosmic-ray induced
air showers. For 14 of these events, this radiation was reflected from the ice.
The dominant contribution to the radiation from the deflection of positrons and
electrons in the geomagnetic field, which is beamed in the direction of motion
of the air shower. This radiation is reflected from the ice and subsequently
detected by the ANITA experiment at a flight altitude of 36km. In this paper,
we estimate the energy of the 14 individual events and find that the mean
energy of the cosmic-ray sample is 2.9 EeV. By simulating the ANITA flight, we
calculate its exposure for ultra-high energy cosmic rays. We estimate for the
first time the cosmic-ray flux derived only from radio observations. In
addition, we find that the Monte Carlo simulation of the ANITA data set is in
agreement with the total number of observed events and with the properties of
those events.Comment: Added more explanation of the experimental setup and textual
improvement
Angular Dependence of Neutrino Flux in KM3 Detectors in Low Scale Gravity Models
Cubic kilometer neutrino telescopes are capable of probing fundamental
questions of ultra-high energy neutrino interactions. There is currently great
interest in neutrino interactions caused by low-scale, extra dimension models.
Above 1 PeV the cross section in low scale gravity models rises well above the
total Standard Model cross section. We assess the observability of this effect
in the 1 PeV - 100 PeV energy range of kilometer-scale detectors with several
new points of emphasis that hinge on enhanced neutral current cross sections. A
major point is the importance of ``feed-down'' regeneration of upward neutrino
flux, driven by new-physics neutral current interactions in the flux evolution
equations. Feed-down is far from negligible, and it is essential to include its
effect. We then find that the angular distribution of events has high
discriminating value in separating models. In particular the ``up-to-down''
ratio between upward and downward-moving neutrino fluxes is a practical
diagnostic tool which can discriminate between models in the near future. The
slope of the angular distribution, in the region of maximum detected flux, is
also substantially different in low-scale gravity and the Standard Model. These
observables are only weakly dependent on astrophysical flux uncertainties. We
conclude that angular distributions can reveal a breakdown of the Standard
Model and probe the new physics beyond, as soon as data become available.Comment: 25 pages, 6 figures, discussion of calculations expanded, references
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Influence of the LPM effect and dielectric suppression on particle air showers
An analysis of the influence of the Landau-Migdal-Pomeranchuk (LPM) effect on
the development of air showers initiated by astroparticles is presented. The
theory of Migdal is studied and compared with other theoretical methods,
particularly the Blankenbecler and Drell approach. By means of realistic
computer simulations and using algorithms that emulate Migdal's theory,
including also the so-called dielectric suppression, we study the behavior of
the relevant observables in the case of ultra-high energy primaries. We find
that the LPM effect can significantly modify the development of high energy
electromagnetic showers in certain cases.Comment: 18 pages, 13 figures, 1 table. To appear in Phys. Rev.
Rice straw-based activated carbons doped with SiC for enhanced hydrogen adsorption
Activated carbons (ACs) based on rice straw (RS) were synthesised using potassium carbonate as activating agent at three different K2CO3/RS weight ratios. Morphological, chemical, structural as well as textural characterisations were carried out in order to establish relationships between the physicochemical properties of the materials and their hydrogen adsorption capacities. The ACs contained potassium and silicon as the main impurities. Si was identified by XRD in both phases of silicon dioxide and silicon carbide. The presence of SiC was particularly surprising due to the rather low activation temperature, much lower than what is usually required for SiC synthesis. ACs exhibited well-developed surface areas (approximatively 2000â2100Â m2Â g-1) and high micropore volumes, making them suitable for hydrogen storage applications. RS-based ACs showed higher hydrogen storage capacities than those previously obtained with KOH-activated sucrose. The latter exhibited hydrogen uptakes (excess, 10Â MPa, 298Â K) up to 0.55Â wt. %, whereas 0.65Â wt. % was measured for RS-based ACs in the same conditions. The higher hydrogen capacities and isosteric heats of adsorption found here were attributed to the presence of SiC
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