3,769 research outputs found
Alcohol-Based Adsorption Heat Pumps using Hydrophobic Metal-Organic Frameworks
The building climate industry and its influence on energy consumption have
consequences on the environment due to the emission of greenhouse gasses.
Improving the efficiency of this sector is essential to reduce the effect on
climate change. In recent years, the interest in porous materials in
applications such as heat pumps has increased for their promising potential. To
assess the performance of adsorption heat pumps and cooling systems, here we
discuss a multistep approach based on the processing of adsorption data
combined with a thermodynamic model. The process provides properties of
interest, such as the coefficient of performance, the working capacity, the
specific heat or cooling effect, or the released heat upon adsorption and
desorption cycles, and it also has the advantage of identifying the optimal
conditions for each adsorbent-fluid pair. To test this method, we select
several metal-organic frameworks that differ in topology, chemical composition,
and pore size, which we validate with available experiments. Adsorption
equilibrium curves were calculated using molecular simulations to describe the
adsorption mechanisms of methanol and ethanol as working fluids in the selected
adsorbents. Then, using a thermodynamic model we calculate the energetic
properties combined with iterative algorithms that simultaneously vary all the
required working conditions. We discuss the strong influence of operating
temperatures on the performance of heat pump devices. Our findings point to the
highly hydrophobic metal azolate framework MAF-6 as a very good candidate for
heating and cooling applications for its high working capacity and excellent
energy efficiency
Understanding the Role of Open Metal Sites in MOFs for the Efficient Separation of Benzene/Cyclohexane Mixtures
Separating C6 cyclic hydrocarbons, specifically benzene and cyclohexane,
presents a significant industrial challenge due to their similar
physicochemical properties. We conducted Monte Carlo simulations in the
Grand-Canonical ensemble to acquire adsorption properties and separation
performance data for benzene and cyclohexane in three metal-organic frameworks
featuring coordinatively unsaturated metal sites (Ni-MOF-74, Ni-ClBBTA, and
Ni-ClBTDD). The separation performance of these MOFs was analyzed and compared
with literature data for adsorbents of different natures, demonstrating
superior performance. Additionally, we explored the molecular origins of this
effective separation, examining the pore-filling mechanism, interaction of
guest molecules with metal centers, and mutual interactions of each adsorbate.
Our results highlight that the selected adsorbents, with remarkable loading
capacity, can efficiently separate both compounds in a mixture with exceptional
effectiveness
Synthesis, Characterization and Electrocatalytic Activity of Bi- and Tri-metallic Pt-Based Anode Catalysts for Direct Ethanol Fuel Cells
Three Pt-based anode catalysts supported on Vulcan XC-72R (VC) were prepared by using a modified polyol process. These materials were characterized and tested by X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF) and Transmission Electron Microscopy (TEM). XRD and TEM analysis indicated that especially the ternary anode catalysts consisted of uniform nanosized particles with sharp distribution. The Pt lattice parameter was smaller, in the ternary PtSnIr catalyst whereas it increased with the addition of Sn and Rh, in the corresponding binary and ternary catalysts. Cyclic voltammetry (CV) measurements showed that Sn, Ir and Rh may act as promoter of Pt enhancing ethanol electro-oxidation activity. It was found that the direct ethanol fuel cell (DEFC) performances were significantly improved with these modified anode catalysts. This effect on the DEFC performance is attributed to the so-called bi-tri-functional mechanism and to the electronic interaction between Pt and additives. The performance increased significantly with the temperature. However, it was also possible to observe some decay with time for all catalysts due to the formation of surface poisons, probably consisting in CO-like species. At 60 °C, the PtSnIr catalyst showed the best performance, as a result of a proper morphology and promoting effectFil: D'Urso, C.. Centro Nazionale della Ricerca. ITAE; ItaliaFil: Bonesi, Alejandro Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Triaca, Walter Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Castro Luna Berenguer, Ana Maria del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Baglio, V.. Centro Nazionale della Ricerca. ITAE; Italia; ItaliaFil: Aricò, A. S.. Centro Nazionale della Ricerca. ITAE; Italia; Itali
Synthesis, Characterization and Electrocatalytic Activity of Bi- and Tri-metallic Pt-Based Anode Catalysts for Direct Ethanol Fuel Cells
Three Pt-based anode catalysts supported on Vulcan XC-72R (VC) were prepared by using a modified polyol process. These materials were characterized and tested by X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF) and Transmission Electron Microscopy (TEM). XRD and TEM analysis indicated that especially the ternary anode catalysts consisted of uniform nanosized particles with sharp distribution. The Pt lattice parameter was smaller, in the ternary PtSnIr catalyst whereas it increased with the addition of Sn and Rh, in the corresponding binary and ternary catalysts. Cyclic voltammetry (CV) measurements showed that Sn, Ir and Rh may act as promoter of Pt enhancing ethanol electro-oxidation activity. It was found that the direct ethanol fuel cell (DEFC) performances were significantly improved with these modified anode catalysts. This effect on the DEFC performance is attributed to the so-called bi-tri-functional mechanism and to the electronic interaction between Pt and additives. The performance increased significantly with the temperature. However, it was also possible to observe some decay with time for all catalysts due to the formation of surface poisons, probably consisting in CO-like species. At 60 °C, the PtSnIr catalyst showed the best performance, as a result of a proper morphology and promoting effectFacultad de Ciencias ExactasInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicada
Synthesis, Characterization and Electrocatalytic Activity of Bi- and Tri-metallic Pt-Based Anode Catalysts for Direct Ethanol Fuel Cells
Three Pt-based anode catalysts supported on Vulcan XC-72R (VC) were prepared by using a modified polyol process. These materials were characterized and tested by X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF) and Transmission Electron Microscopy (TEM). XRD and TEM analysis indicated that especially the ternary anode catalysts consisted of uniform nanosized particles with sharp distribution. The Pt lattice parameter was smaller, in the ternary PtSnIr catalyst whereas it increased with the addition of Sn and Rh, in the corresponding binary and ternary catalysts. Cyclic voltammetry (CV) measurements showed that Sn, Ir and Rh may act as promoter of Pt enhancing ethanol electro-oxidation activity. It was found that the direct ethanol fuel cell (DEFC) performances were significantly improved with these modified anode catalysts. This effect on the DEFC performance is attributed to the so-called bi-tri-functional mechanism and to the electronic interaction between Pt and additives. The performance increased significantly with the temperature. However, it was also possible to observe some decay with time for all catalysts due to the formation of surface poisons, probably consisting in CO-like species. At 60 °C, the PtSnIr catalyst showed the best performance, as a result of a proper morphology and promoting effectFacultad de Ciencias ExactasInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicada
Formation of a disk-structure and jets in the symbiotic prototype Z And during its 2006-2010 active phase
We present an analysis of spectrophotometric observations of the latest cycle
of activity of the symbiotic binary Z And from 2006 to 2010. We estimate the
temperature of the hot component of Z And to be \approx 150000 - 170000 K at
minimum brightness, decreasing to \approx 90000 K at the brightness maximum.
Our estimate of the electron density in the gaseous nebula is
N_{e}=10^{10}-10^{12} cm^{-3} in the region of formation of lines of neutral
helium and 10^6-10^7 cm^{-3} in the region of formation of the [OIII] and
[NeIII] nebular lines. A trend for the gas density derived from helium lines to
increase and the gas density derived from [OIII] and [NeIII] lines to
simultaneously decrease with increasing brightness of the system was observed.
Our estimates show that the ratios of the theoretical and observed fluxes in
the [OIII] and [NeIII] lines agree best when the O/Ne ratio is similar to its
value for planetary nebulae. The model spectral energy distribution showed
that, in addition to a cool component and gaseous nebula, a relatively cool
pseudophotosphere (5250-11 500 K) is present in the system. The simultaneous
presence of a relatively cool pseudophotosphere and high-ionization spectral
lines is probably related to a disk-like structure of the pseudophotosphere.
The pseudophotosphere formed very rapidly, over several weeks, during a period
of increasing brightness of Z And. We infer that in 2009, as in 2006, the
activity of the system was accompanied by a collimated bipolar ejection of
matter. In contrast to the situation in 2006, the jets were detected even
before the system reached its maximum brightness. Moreover, components with
velocities close to 1200 km/s disappeared at the maximum, while those with
velocities close to 1800 km/s appeared.Comment: 18 pages, 19 figures, Accepted for publication in Astronomy Report
The burden of 14 hr-HPV genotypes in women attending routine cervical cancer screening in 20 states of Mexico: a cross-sectional study
In Mexico, HPV vaccines available immunize against genotypes 16/18 and 16/18/6/11; however, there is limited surveillance about carcinogenic subtypes in different states of the country that allow evaluating the effectiveness of vaccination and cervical cancer screening programs. Here, we report the regional and age-specific prevalence of 14 hr-HPV genotypes as well as their prevalence in abnormal cytology (from ASCUS to cervical cancer) among Mexican women which were undergoing from cervical cancer screening in the Salud Digna clinics in 20 states of the country. This study includes women with social security from the majority of public health institutions (IMSS, ISSSTE, SEMAR, and PEMEX), and women without social security. For cervical cancer screening, we used the SurePath liquid-based cytology and the BD Onclarity HPV Assay. From December 1, 2016, to August 2, 2018, the hr-HPV prevalence among 60,135 women was 24.78%, the most prevalent types were HPV 16 (4.13%), HPV 31 (4.12%) and HPV 51 (3.39%), while HPV 18 (1.70%) was less prevalent among infected women. Interestingly, the genotypes not covered by current vaccines in Mexico were commonly found in precancerous lesions, evidencing their carcinogenic potential, so it is necessary to increase their surveillance and inclusion in cervical cancer screening triage.We gratefully acknowledge to Iromy Meza, Jessica Avitia, and Oswaldo Carrillo for their technical support in obtaining databases during this project. Also, we want to thanks the staff of the Salud Digna clinics and the National Reference Center of Salud Digna for their support during this work. This work was funding by Salud Digna
Investigating hyper-vigilance for social threat of lonely children
The hypothesis that lonely children show hypervigilance for social threat was examined in a series of three studies that employed different methods including advanced eye-tracking technology. Hypervigilance for social threat was operationalized as hostility to ambiguously motivated social exclusion in a variation of the hostile attribution paradigm (Study 1), scores on the Children’s Rejection-Sensitivity Questionnaire (Study 2), and visual attention to socially rejecting stimuli (Study 3). The participants were 185 children (11 years-7 months to 12 years-6 months), 248 children (9 years-4 months to 11 years-8 months) and 140 children (8 years-10 months to 12 years-10 months) in the three studies, respectively. Regression analyses showed that, with depressive symptoms covaried, there were quadratic relations between loneliness and these different measures of hypervigilance to social threat. As hypothesized, only children in the upper range of loneliness demonstrated elevated hostility to ambiguously motivated social exclusion, higher scores on the rejection sensitivity questionnaire, and disengagement difficulties when viewing socially rejecting stimuli. We found that very lonely children are hypersensitive to social threat
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