1,885 research outputs found
Origin of the insulating state in honeycomb iridates and rhodates
A burning question in the emerging field of spin-orbit driven insulating
iridates, such as Na2IrO3 and Li2IrO3 is whether the observed insulating state
should be classified as a Mott-Hubbard insulator derived from a half-filled
relativistic j_eff=1/2 band or as a band insulator where the gap is assisted by
spin-orbit interaction, or Coulomb correlations, or both. The difference
between these two interpretations is that only for the former, strong
spin-orbit coupling (lambda >~ W, where W is the band width) is essential. We
have synthesized the isostructural and isoelectronic Li2RhO3 and report its
electrical resistivity and magnetic susceptibility. Remarkably it shows
insulating behavior together with fluctuating effective S=1/2 moments, similar
to Na2IrO3 and Li2IrO3, although in Rh4+ (4d5) the spin-orbit coupling is
greatly reduced. We show that this behavior has non-relativistic one-electron
origin (although Coulomb correlations assist in opening the gap), and can be
traced down to formation of quasi-molecular orbitals, similar to those in
Na2IrO3.Comment: 7 pages, 7 figure
Маркшейдерське забезпечення робіт при створенні програмного модуля розкритих, підготовлених і готових до видобування балансово-промислових запасів
Розглянуто і досліджено методи визначення і нормування балансово-промислових запасів за ступенем підготовленості до видобування, які призначені для залізорудних корисних копалин і вугілля. Для багатьох видів твердих корисних копалин такі методи не розроблені. Встановлено, що кожний із видів мінеральної сировини має особливості природно-просторового розміщення у надрах, гірничо-технологічні стадії видобутку і переробки, які
враховують при підземному способі видобутку, методи визначення стану і рухомості, обліку і нормування підготовленості балансово-промислових запасів за програмним модулем
Effect of isoelectronic doping on honeycomb lattice iridate A_2IrO_3
We have investigated experimentally and theoretically the series
(NaLi)IrO. Contrary to what has been believed so far,
only for the system forms uniform solid solutions. For larger Li
content, as evidenced by powder X-ray diffraction, scanning electron microscopy
and density functional theory calculations, the system shows a miscibility gap
and a phase separation into an ordered NaLiIrO phase with
alternating Na and LiIrO planes, and a Li-rich phase close to pure
LiIrO. For we observe (1) an increase of with Li
doping up to , despite the fact that in pure LiIrO is
smaller than in NaIrO, and (2) a gradual reduction of the
antiferromagnetic ordering temperature and ordered moment. The
previously proposed magnetic quantum phase transition at may
occur in a multiphase region and its nature needs to be re-evaluated.Comment: 8 pages, 9 figures including supplemental informatio
Determination of effective microscopic models for the frustrated antiferromagnets CsCuCl and CsCuBr by density functional methods
We investigate the electronic and magnetic properties of the frustrated
triangular-lattice antiferromagnets CsCuCl and CsCuBr in the
framework of density functional theory. Analysis of the exchange couplings J
and J' using the available X-ray structural data corroborates the values
obtained from experimental results for CsCuBr but not for
CsCuCl. In order to understand this discrepancy, we perform a detailed
study of the effect of structural optimization on the exchange couplings of
CsCuCl employing different exchange-correlation functionals. We find
that the exchange couplings depend on rather subtle details of the structural
optimization and that only when the insulating state (mediated through spin
polarization) is present in the structural optimization, we do have good
agreement between the calculated and the experimentally determined exchange
couplings. Finally, we discuss the effect of interlayer couplings as well as
longer-ranged couplings in both systems.Comment: Phys. Rev. B in pres
Application of the Socio-Economic Impact Classification for Alien Taxa (SEICAT) to a global assessment of alien bird impacts
We use a recently proposed framework, the Socio-Economic Impact Classification for Alien Taxa (SEICAT) to undertake the first global assessment of the impacts of alien birds on human well-being. A review of the published literature and online resources was undertaken to collate information on the reported socio-economic impacts of 415 bird species with self-sustaining alien populations worldwide. These data were then categorised following the SEICAT guidelines. Impact data were found for 57 (14%) of the 415 alien bird species in this study. All but two of these species were found to have minor impacts on human well-being. The most significant threat to human well-being posed by alien birds may be associated with their impacts on aviation safety. About two-thirds of the impact data found described agricultural impacts. No data were found describing disease transmission impacts on humans. We lack data for developing regions of the world: this is of concern as alien species can threaten livelihoods in developing countries, particularly by affecting agricultural production and hence food security. Most assessments were allocated a ‘Low’ confidence score. This may be because SEICAT is a new framework, requiring data on the way in which alien species affect human well-being, as measured by changes to human activities: even where we do have data describing an alien bird impact, information on how profoundly this impact affects people’s activities is currently rarely available
Electronic structure studies of BaFe2As2 by angle-resolved photoemission spectroscopy
We report high resolution angle-resolved photoemission spectroscopy (ARPES)
studies of the electronic structure of BaFeAs, which is one of the
parent compounds of the Fe-pnictide superconductors. ARPES measurements have
been performed at 20 K and 300 K, corresponding to the orthorhombic
antiferromagnetic phase and the tetragonal paramagnetic phase, respectively.
Photon energies between 30 and 175 eV and polarizations parallel and
perpendicular to the scattering plane have been used. Measurements of the Fermi
surface yield two hole pockets at the -point and an electron pocket at
each of the X-points. The topology of the pockets has been concluded from the
dispersion of the spectral weight as a function of binding energy. Changes in
the spectral weight at the Fermi level upon variation of the polarization of
the incident photons yield important information on the orbital character of
the states near the Fermi level. No differences in the electronic structure
between 20 and 300 K could be resolved. The results are compared with density
functional theory band structure calculations for the tetragonal paramagnetic
phase.Comment: 11 pages, 5 figure
Human amniotic fluid glycoproteins expressing sialyl Lewis carbohydrate antigens stimulate progesterone production in human trophoblasts in vitro
Background: Progesterone is thought to mediate immune modulator effects by regulating uterine responsiveness. The aim of the study was to clarify the effect of transferrin and glycodelin A (former name PP14) as sialyl Lewis X-expressing glycoproteins on the release of progesterone by trophoblast cells in vitro. Methods: Cytotrophoblast cells were prepared from human term placentas by standard dispersion of villous tissue followed by a Percoll gradient centrifugation step. Trophoblasts were incubated with varying concentrations (50-300 mug/ml) of human amniotic fluid- and serum-transferrin as well as with glycodelin A. Culture supernatants were assayed for progesterone, human chorionic gonadotropin (hCG) and cortisol by enzyme immunometric methods. Results: The release of progesterone is increased in amniotic fluid transferrin- and glycodelin A-treated trophoblast cell cultures compared to untreated trophoblast cells. There is no relation between transferrin and the hCG or cortisol production of trophoblast cells. Conclusion: The results suggest that sialyl Lewis carbohydrate antigen-expressing amniotic fluid glycoproteins modulate the endocrine function of trophoblasts in culture by upregulating progesterone production. Copyright (C) 2004 S. Karger AG, Basel
Boom‐bust dynamics in biological invasions: towards an improved application of the concept
Boom‐bust dynamics – the rise of a population to outbreak levels, followed by a dramatic decline – have been associated with biological invasions and offered as a reason not to manage troublesome invaders. However, boom‐bust dynamics rarely have been critically defined, analyzed, or interpreted. Here, we define boom‐bust dynamics and provide specific suggestions for improving the application of the boom‐bust concept. Boom‐bust dynamics can arise from many causes, some closely associated with invasions, but others occurring across a wide range of ecological settings, especially when environmental conditions are changing rapidly. As a result, it is difficult to infer cause or predict future trajectories merely by observing the dynamic. We use tests with simulated data to show that a common metric for detecting and describing boom‐bust dynamics, decline from an observed peak to a subsequent trough, tends to severely overestimate the frequency and severity of busts, and should be used cautiously if at all. We review and test other metrics that are better suited to describe boom‐bust dynamics. Understanding the frequency and importance of boom‐bust dynamics requires empirical studies of large, representative, long‐term data sets that use clear definitions of boom‐bust, appropriate analytical methods, and careful interpretations
The monoclinic crystal structure of -RuCl and the zigzag antiferromagnetic ground state
The layered honeycomb magnet alpha-RuCl3 has been proposed as a candidate to
realize a Kitaev spin model with strongly frustrated, bond-dependent,
anisotropic interactions between spin-orbit entangled jeff=1/2 Ru4+ magnetic
moments. Here we report a detailed study of the three-dimensional crystal
structure using x-ray diffraction on untwinned crystals combined with
structural relaxation calculations. We consider several models for the stacking
of honeycomb layers and find evidence for a crystal structure with a monoclinic
unit cell corresponding to a stacking of layers with a unidirectional in-plane
offset, with occasional in-plane sliding stacking faults, in contrast with the
currently-assumed trigonal 3-layer stacking periodicity. We report electronic
band structure calculations for the monoclinic structure, which find support
for the applicability of the jeff=1/2 picture once spin orbit coupling and
electron correlations are included. We propose that differences in the
magnitude of anisotropic exchange along symmetry inequivalent bonds in the
monoclinic cell could provide a natural mechanism to explain the spin gap
observed in powder inelastic neutron scattering, in contrast to spin models
based on the three-fold symmetric trigonal structure, which predict a gapless
spectrum within linear spin wave theory. Our susceptibility measurements on
both powders and stacked crystals, as well as neutron powder diffraction show a
single magnetic transition at TN ~ 13K. The analysis of the neutron data
provides evidence for zigzag magnetic order in the honeycomb layers with an
antiferromagnetic stacking between layers. Magnetization measurements on
stacked single crystals in pulsed field up to 60T show a single transition
around 8T for in-plane fields followed by a gradual, asymptotic approach to
magnetization saturation, as characteristic of strongly anisotropic exchange
interactions.Comment: 13 pages, 9 figures, published in Physical Review
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