160 research outputs found
Excited state hydrogen transfer dynamics in substituted phenols and their complexes with ammonia: π π * -π σ*energy gap propensity and ortho-substitution effect
Lifetimes of the first electronic excited state (S1) of fluorine and methyl (o-, m-, and p-) substituted phenols and their complexes with one ammonia molecule have been measured for the 00 transition and for the intermolecular stretching σ1 levels in complexes using picosecond pump-probe spectroscopy. Excitation energies to the S1 (π π *) and S2 (π σ*) states are obtained by quantum chemical calculations at the MP2 and CC2 level using the aug-cc-pVDZ basis set for the ground-state and the S1 optimized geometries. The observed lifetimes and the energy gaps between the π π * and π σ* states show a good correlation, the lifetime being shorter for a smaller energy gap. This propensity suggests that the major dynamics in the excited state concerns an excited state hydrogen detachment or transfer (ESHD/T) promoted directly by a S1 / S2 conical intersection, rather than via internal conversion to the ground-state. A specific shortening of lifetime is found in the o-fluorophenol-ammonia complex and explained in terms of the vibronic coupling between the π π * and π σ* states occurring through the out-of-plane distortion of the C-F bond.Fil: Pino, Gustavo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Oldani, Andres Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Marceca, Ernesto José. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Fujii, M.. Tokyo Institute of Technology; JapónFil: Ishiuchi, S.-I.. Tokyo Institute of Technology; JapónFil: Miyazaki, M.. Tokyo Institute of Technology; JapónFil: Broquier, M.. Centre National de la Recherche Scientifique; Francia. Universite Paris-Saclay;Fil: Dedonder, C.. Centre National de la Recherche Scientifique; Francia. Universite Paris-Saclay;Fil: Jouvet, C.. Universite Paris-Saclay; . Centre National de la Recherche Scientifique; Franci
Stabilities of nanohydrated thymine radical cations: insights from multiphoton ionization experiments and ab initio calculations
Multi-photon ionization experiments have been carried out on thymine-water clusters in the gas phase. Metastable H2O loss from T+(H2O)n was observed at n ≥ 3 only. Ab initio quantum-chemical calculations of a large range of optimized T+(H2O)n conformers have been performed up to n = 4, enabling binding energies of water to be derived. These decrease smoothly with n, consistent with the general trend of increasing metastable H2O loss in the experimental data. The lowest-energy conformers of T+(H2O)3 and T+(H2O)4 feature intermolecular bonding via charge-dipole interactions, in contrast with the purely hydrogen-bonded neutrals. We found no evidence for a closed hydration shell at n = 4, also contrasting with studies of neutral clusters
Blood glutamate scavengers prolong the survival of rats and mice with brain-implanted gliomas
Isomeric recognition by ion/molecule reactions: The ionized phenol-cyclohexadienone case
Spotting the enemy within: Targeted silencing of foreign DNA in mammalian genomes by the Krüppel-associated box zinc finger protein family
Picosecond time-resolved nonresonant ionization detected IR spectroscopy on 7-azaindole dimer
The picosecond time-resolved IR spectrum of the 7-azaindole dimer has been measured by
picosecond time-resolved nonresonant ionization detected IR spectroscopy. This new time-resolved
technique was developed by combining nonresonant ionization detected IR (NID-IR) spectroscopy with
tunable picosecond IR and UV lasers. The time-resolved NID-IR spectrum from 2 600 cm-1 to 3 800 cm-1
shows a drastic change from 1.5 ps to 11 ps time evolution. A mode-specific vibrational redistribution
has been suggested
Picosecond time-resolved nonresonant ionization detected IR spectroscopy on 7-azaindole dimer
Recovery of full flexion after total knee replacement in rheumatoid arthritis - a follow-up study
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