The Role of Plastic Flow in Processes of High-speed Sintering of Ceramic Materials under Pressure

A model to describe the kinetics of the compaction of conductive nitride ceramics using electropulse technologies is developed. The relationship between density and pressure is established on the basis of three components of the geometric, plastic and stressed state, which is affects the contact area between the particles. The model takes into account the change in the relative area of the interpartial contacts under the action oftwo mechanisms of mass transfer-diffusion and plastic flow. It is shown that a decrease in the particle size of the powder leads to an in-crease in the diffusion contribution and a decrease in the plastic flow, at all other conditions being equal. And for the case of nano-sized particles, diffusion mass transfer is predominant.Increasing in the heating rate leads to a decrease in the contribution of dif-fusion mass transfer at equal temperatures, as well as to an increase in the temperature of the beginning of shrinkage.The processes of plasma-plasma sintering, high-voltage electro-pulsed consolidation and hot pressing control the same mechanisms, plastic flow and diffusion mass transfer, which do not require, in the first approximation, the influence of the electric current on the properties of materials. Keywords: spark-plasma sintering, high-voltage electrodischarge consolidation, sintering kinetic

Search for β+\beta^+EC and ECEC processes in 112^{112}Sn

Limits on $\beta^+$EC (here EC denotes electron capture) and ECEC processes in $^{112}$Sn have been obtained using a 380 cm$^3$ HPGe detector and an external source consisting of 53.355 g enriched tin (94.32% of $^{112}$Sn). A limit with 90% C.L. on the $^{112}$Sn half-life of $4.7\times 10^{20}$ y for the ECEC(0$\nu$) transition to the $0^+_3$ excited state in $^{112}$Cd (1871.0 keV) has been established. This transition is discussed in the context of a possible enhancement of the decay rate by several orders of magnitude given that the ECEC$(0\nu)$ process is nearly degenerate with an excited state in the daughter nuclide. Prospects for investigating such a process in future experiments are discussed. The limits on other $\beta^+$EC and ECEC processes in $^{112}$Sn were obtained on the level of $(0.6-8.7)\times 10^{20}$ y at the 90% C.L.Comment: 14 pages, 4 figure

Deformations of the Retaining Structures Upon Deep Excavations in Moscow

Foundation trenches for the buildings having underground floors and vehicular traffic tunnels are excavated in Moscow in congested urban housing environment. A retaining structure is a “slurry wall” made of cast-in-place reinforced concrete), and “soil-mixed-wall”. Retaining structures of trenches are fastened with the help of anchors, metal tie-beams, struts or floor structures. During the monitoring performed at major Moscow construction sites with deep trenches the (NIIOSP) named after Gersevanov created a database on retaining structures deformations

First test of an enriched 116^{116}CdWO4_4 scintillating bolometer for neutrinoless double-beta-decay searches

For the first time, a cadmium tungstate crystal scintillator enriched in $^{116}$Cd has been succesfully tested as a scintillating bolometer. The measurement was performed above ground at a temperature of 18 mK. The crystal mass was 34.5 g and the enrichment level ~82 %. Despite a substantial pile-up effect due to above-ground operation, the detector demonstrated a high energy resolution (2-7 keV FWHM in 0.2-2.6 MeV $\gamma$ energy range), a powerful particle identification capability and a high level of internal radiopurity. These results prove that cadmium tungstate is an extremely promising detector material for a next-generation neutrinoless double-beta decay bolometric experiment, like that proposed in the CUPID project (CUORE Upgrade with Particle IDentification)

Short-term Mechanical Properties of Fe-Cr-Al-Si Alloys

The purpose of this work is to study the short-term mechanical properties of Fe-Cr-AlSi-based alloys. Within the framework of this work, alloys with a chromium content of 5 to 14 wt%, aluminum from 0 to 4 wt%, and silicon from 0 to 4 wt% are considered. The samples were tested in three different states - in the deformed state (cold rolling by 80%), and also after annealing at a temperature of 450 and 650 ∘C with a duration of 1000 h.As a result, the characteristics of the strength and plasticity of alloys in the deformed state, as well as after provoking annealing, were obtained. It is shown that embrittlement isn’t observed in the investigated composition region and annealing conditions, and the strength of the alloys is directly proportional to the sum of the alloying elements Al + Si. Keywords: cladding; VVER; tolerant fuel, ferrite steel; Corrosion-resistant steel, tensile strength, yield strengt

Membrane extraction of organic compounds 2. * transport of glycolic acid induced by α-aminophosphonates: Kinetic study

New lipophilic α-aminophosphonates containing cyclic or acyclic alkyl substituents at the carbon atom in the a position were synthesized by the Kabachnik-Fields reaction. Studies of the obtained compounds as carriers for transport of glycolic acid through polymer-supported liquid membranes demonstrated that the flux of glycolic acid through the membrane depends on the lipophilicity and the presence of substituents at the α-C atom of aminophosphonate. The structures of a number of α-aminophosphonate - glycolic acid complexes were calculated by the semiempirical PM3 method

Lipophilic aminophosphonates and their calix[4]arene derivatives: synthesis and membrane transport of biorelevant species

Many new lipophilic α-aminophosphonates including macrocylic (on calix[4]arene platform) and chiral ones were synthesized by the Kabachnik-Fields reaction. Some of them were examined as carriers for membrane transport of biorelevant species such as hydroxy, amino acids, and amino alcohols. Transport measurements showed that these compounds exhibited remarkable efficiency and selectivity of the transport of very hydrophilic substances across lipophilic membranes. The structures of α-amino-phosphonate-substrate complexes were investigated by spectral and theoretical methods

Selecting efficient parameters for the coke charge of shaft-type melting furnaces

It is shown based on studies of the changes in the composition of the gases and temperature in the preliminary charge that the performance indices of coke-fired shaft furnaces are determined by the conditions under which the oxidizing zone is formed so as to produce the greatest possible amount of heat. It is shown that the size of this zone increases with an increase in the rate of filtration of the air blast, enrichment of the blast with oxygen, and the use of low-activity coke in the form of lumps of limited size. To maximize the reheating of the melt, it is necessary to increase the average size of the lumps and the flow rate of the air blast in order to increase the height of the preliminary charge. © 2013 Springer Science+Business Media New York