Simultaneous inversion of source spectra, attenuation parameters and site responses. Application to the data of the French Accelerometric Network.

International audienceDisplacement spectra of earthquakes recorded by the French accelerometric network at regional scale are modeled as the product of source, propagation (including geometric and anelastic attenuation), and site effects. We use an iterative Gauss–Newton inversion to solve the nonlinear problem and retrieve these different terms. This method is easy to implement because the partial derivatives of the amplitude spectrum with respect to the different parameters have simple analytic forms. After convergence, we linearize the problem around the solution to compute the correlation matrix, which allows us to identify the parameters which are poorly resolved. We analyze data from two tectonically active regions: the Alps and the Pyrenees. Eighty-three earthquakes with local magnitudes between 3.0 and 5.3 are analyzed, with epicentral distances in the range 15–200 km. S-wave displacement spectra are computed using a fast Fourier transform and integration in the 0.5–15-Hz frequency domain. We assume a Brune-type source, with a geometric attenuation of the form R-{gamma}, {gamma} being constant, and a frequency-dependent quality factor of the form Q=Q0xf{alpha}. The results reveal that the attenuation parameters are correlated to each other and to the seismic moments. The two regions have different attenuation patterns. The geometrical spreading factor is equal to 1 for the Alps and 1.2 for the Pyrenees. The anelastic attenuation exhibits low Q0 values (322 and 376 for the Alps and the Pyrenees, respectively) with regional variations for {alpha} (0.21 in the Alps and 0.46 in the Pyrenees). Computed moment magnitudes are generally 0.5 unit smaller than local magnitudes, and the logarithms of the corner frequencies decrease linearly with magnitude according to log10(fc)=1.72-0.32xMw. Stress drops range from 105 to 107 Pa (i.e., 1–100 bars), with a slight dependence to magnitude (large stress drops for large magnitudes). Finally, robust site responses relative to an average rock-site response are derived, allowing us to identify good reference rock sites

Electron transport through rectifying self-assembled monolayer diodes on silicon: Fermi level pinning at the molecule-metal interface

We report the synthesis and characterization of molecular rectifying diodes on silicon using sequential grafting of self-assembled monolayers of alkyl chains bearing a pi group at their outer end (Si/sigma-pi/metal junctions). We investigate the structure-performance relationships of these molecular devices and we examine to what extent the nature of the pi end-group (change in the energy position of their molecular orbitals) drives the properties of these molecular diodes. For all the pi-groups investigated here, we observe rectification behavior. These results extend our preliminary work using phenyl and thiophene groups (S. Lenfant et al., Nano Letters 3, 741 (2003)).The experimental current-voltage curves are analyzed with a simple analytical model, from which we extract the energy position of the molecular orbital of the pi-group in resonance with the Fermi energy of the electrodes. We report the experimental studies of the band lineup in these silicon/alkyl-pi conjugated molecule/metal junctions. We conclude that Fermi level pinning at the pi-group/metal interface is mainly responsible for the observed absence of dependence of the rectification effect on the nature of the pi-groups, even though they were chosen to have significant variations in their electronic molecular orbitalsComment: To be published in J. Phys. Chem.

Global P- and S-wave tomography from finite-frequency traveltime residual measurements

There are two main ways to improve the resolution of tomographic images: building larger and higher quality datasets, and using better imaging theories, such as finite frequency theory or waveform inversion, instead of the more commonly used ray theory. A first step toward improving the resolution of global tomographic models is thus to construct a seismological database adapted to finite-frequency tomography or waveform inversion. We present a global dataset of finite frequency travel time residuals. These measurements were obtained by cross-correlating observed and synthetic waveforms in several frequency bands. We exploit seismograms at significantly shorter periods than in other recent comparable works. We compute Green's functions with the GEMINI method and convolve them with high-frequency source-time functions. These source-time functions are inverted, along with focal depths, with a simulated annealing approach. We measure travel time residuals on different P and S phases. We check the quality of our global database by performing preliminary tomographic inversions using ray theory. We use the subset of measurements performed in the 0.0725-Hz frequency range, combined to ISC travel times, to build tomographic models for both P and S velocity anomalies. Resulting models are presented and compared to recently published global tomographic models, and some implications for finite frequency effects and physical properties of the deep Earth are discussed

Polypyrrole-Fe2O3 nanohybrid materials for electrochemical storage

We report on the synthesis and electrochemical characterization of nanohybrid polypyrrole (PPy) (PPy/Fe2O3) materials for electrochemical storage applications. We have shown that the incorporation of nanoparticles inside the PPy notably increases the charge storage capability in comparison to the “pure” conducting polymer. Incorporation of large anions, i.e., paratoluenesulfonate, allows a further improvement in the capacity. These charge storage modifications have been attributed to the morphology of the composite in which the particle sizes and the specific surface area are modified with the incorporation of nanoparticles. High capacity and stability have been obtained in PC/NEt4BF4 (at 20 mV/s), i.e., 47 mAh/g, with only a 3% charge loss after one thousand cyles. The kinetics of charge–discharge is also improved by the hybrid nanocomposite morphology modifications, which increase the rate of insertion–expulsion of counter anions in the bulk of the film. A room temperature ionic liquid such as imidazolium trifluoromethanesulfonimide seems to be a promising electrolyte because it further increases the capacity up to 53 mAh/g with a high stability during charge–discharge processes

The dependence of the anomalous J/psi suppression on the number of participant nucleons

The observation of an anomalous J/psi suppression in Pb-Pb collisions by the NA50 Collaboration can be considered as the most striking indication for the deconfinement of quarks and gluons at SPS energies. In this Letter, we determine the J/psi suppression pattern as a function of the forward hadronic energy E-ZDC measured in a Zero Degree Calorimeter (ZDC). The direct connection between EZDC and the geometry of the collision allows us to calculate, within a Glauber approach, the precise relation between the number of participant nucleons N-part and E-ZDC. Then, we check if the experimental data can be better explained by a sudden or a smooth onset of the anomalous J/psi suppression as a function of the number of participants. (C) 2001 Elsevier Science B.V. All rights reserved.info:eu-repo/semantics/publishedVersio

Centrality Behaviour of J/ψ\psi Production in Na50

The J/$\psi$ production in 158 A GeV Pb-Pb interactions is studied, in the dimuon decay channel, as a function of centrality, as measured with the electromagnetic or with the very forward calorimeters. After a first sharp variation at mid centrality, both patterns continue to fall down and exhibit a curvature change at high centrality values. This trend excludes any conventional hadronic model and is in agreement with a deconfined quark-gluon phase scenario. We report also preliminary results on the measured charged multiplicity, as given by a dedicated detector.Comment: 5 pages, 7 figures (in eps) talk given at XXXI International Symposium on Multiparticle Dynamics, Sep. 1-7, 2001, Datong China URL http://ismd31.ccnu.edu.cn

Do patients have to choose between ejaculation and miction? A systematic review about ejaculation preservation technics for benign prostatic obstruction surgical treatment

PURPOSE: Ejaculatory dysfunction is the most common side effect related to surgical treatment of benign prostatic obstruction (BPO). Nowadays, modified surgical techniques and non-ablative techniques have emerged with the aim of preserving antegrade ejaculation. Our objective was to conduce a systematic review of the literature regarding efficacy on ejaculatory preservation of modified endoscopic surgical techniques, and mini-invasive non-ablatives techniques for BPO management. METHODS: A systematic review of the literature was carried out on the PubMed database using the following MESH terms: "Prostatic Hyperplasia/surgery" and "Ejaculation", in combination with the following keywords: "ejaculation preservation", "photoselective vaporization of the prostate", "photoselective vapo-enucleation of the prostate", "holmium laser enucleation of the prostate", "thulium laser", "prostatic artery embolization", "urolift", "rezum", and "aquablation". RESULTS: The ejaculation preservation rate of modified-TURP ranged from 66 to 91%. The ejaculation preservation rate of modified-prostate photo-vaporization ranged from 87 to 96%. The only high level of evidence studies available compared prostatic urethral lift (PUL) and aquablation versus regular TURP in prospective randomized-controlled trials. The ejaculation preservation rate of either PUL or aquablation compared to regular TURP was 100 and 90 versus 34%, respectively. CONCLUSIONS: Non-ablative therapies and modified endoscopic surgical techniques seemed to be reasonable options for patients eager to preserve their ejaculatory functions

Relative effects of sensory modalities and importance of fatty acid sensitivity on fat perception in a real food model

Fat can be perceived through mouthfeel, odour and taste, but the influence of these modalities on fat perception remains undefined. Fatty acids are stimuli. Individual’s sensitivity to fatty acids varies. Studies show association between fatty acid sensitivity, dietary intake and BMI, but results are conflicting. Therefore, this study examined this association, and the effects of modalities on fat perception. Two sub-studies conducted. In Study 1 (n=46), fat intensity was assessed by milk/cream mixtures varying by five fat levels. Fat intensity was rated under four conditions: mouthfeel-odour masked, mouthfeel masked, odour masking and no masking. Mouthfeel masking was achieved using thickener and paraffin, odour masking using nose-clips. Fatty acid sensitivity was measured by 3-AFC-staircase method using milk containing oleic acid (0.31-31.4mM). In Study 2 (n=51), more fat levels were added in fat intensity rating. A 2-AFC discrimination test was used to confirm whether fat levels could be distinguished. In the sensitivity test, a wider range of oleic acid was included. Fat intensity was rated higher without nose-clips (p<0.0001), implying that odour increased fat perception. Samples with mouthfeel-masked were rated higher, showing that increased viscosity and lubricity enhanced fat perception (p<0.0001). Participants could distinguish fat levels based on “taste” in rating tests and 2-AFC-tests. Participants were divided into high/medium/low-sensitivity groups. No significant difference found in fat intensity between groups, however, high-sensitivity group discriminated more fat levels. No association between sensitivity groups, nutrient intake or BMI found