Exchange coupling inversion in a high-spin organic triradical molecule

The magnetic properties of a nanoscale system are inextricably linked to its local environment. In ad-atoms on surfaces and inorganic layered structures the exchange interactions result from the relative lattice positions, layer thicknesses and other environmental parameters. Here, we report on a sample-dependent sign inversion of the magnetic exchange coupling between the three unpaired spins of an organic triradical molecule embedded in a three-terminal device. This ferro-to-antiferromagnetic transition is due to structural distortions and results in a high-to-low spin ground state change in a molecule traditionally considered to be a robust high-spin quartet. Moreover, the flexibility of the molecule yields an in-situ electric tunability of the exchange coupling via the gate electrode. These findings open a route to the controlled reversal of the magnetic states in organic molecule-based nanodevices by mechanical means, electrical gating or chemical tailoring

Obesity prevention strategies: could food or soda taxes improve health?

Evidence shows that one of the main causes for rising obesity rates is excessive consumption of sugar, which is due in large part to the high sugar content of most soda and juice drinks and junk foods. Worryingly, UK and global populations are consuming increasing amounts of sugary drinks and junk foods (high in salt, sugar and saturated fats). However, there is raised public awareness, and parents in particular want something to be done to curb the alarming rise in childhood obesity. Population-wide policies (i.e. taxation, regulation, legislation, reformulation) consistently achieve greater public health gains than interventions and strategies targeted at individuals. Junk food and soda taxes are supported by increasing evidence from empirical and modelling studies. The strongest evidence base is for a tax on sugar sweetened beverages, but in order to effectively reduce consumption, that taxation needs to be at least 20%. Empirical data from a number of countries which have implemented a duty on sugar or sugary drinks shows rapid, substantial benefits. In the UK, increasing evidence from recent scientific reports consistently support substantial reductions in sugar consumption through comprehensive strategies which include a tax. Furthermore, there is increasing public support for such measures. A sugar sweetened beverages tax will happen in the UK so the question is not 'If?' but 'When?' this tax will be implemented. And, crucially, which nation will get there first? England, Ireland, Scotland or Wales

Models of helically symmetric binary systems

Results from helically symmetric scalar field models and first results from a convergent helically symmetric binary neutron star code are reported here; these are models stationary in the rotating frame of a source with constant angular velocity omega. In the scalar field models and the neutron star code, helical symmetry leads to a system of mixed elliptic-hyperbolic character. The scalar field models involve nonlinear terms that mimic nonlinear terms of the Einstein equation. Convergence is strikingly different for different signs of each nonlinear term; it is typically insensitive to the iterative method used; and it improves with an outer boundary in the near zone. In the neutron star code, one has no control on the sign of the source, and convergence has been achieved only for an outer boundary less than approximately 1 wavelength from the source or for a code that imposes helical symmetry only inside a near zone of that size. The inaccuracy of helically symmetric solutions with appropriate boundary conditions should be comparable to the inaccuracy of a waveless formalism that neglects gravitational waves; and the (near zone) solutions we obtain for waveless and helically symmetric BNS codes with the same boundary conditions nearly coincide.Comment: 19 pages, 7 figures. Expanded version of article to be published in Class. Quantum Grav. special issue on Numerical Relativit

A Hybrid N-body--Coagulation Code for Planet Formation

We describe a hybrid algorithm to calculate the formation of planets from an initial ensemble of planetesimals. The algorithm uses a coagulation code to treat the growth of planetesimals into oligarchs and explicit N-body calculations to follow the evolution of oligarchs into planets. To validate the N-body portion of the algorithm, we use a battery of tests in planetary dynamics. Several complete calculations of terrestrial planet formation with the hybrid code yield good agreement with previously published calculations. These results demonstrate that the hybrid code provides an accurate treatment of the evolution of planetesimals into planets.Comment: Astronomical Journal, accepted; 33 pages + 11 figure

Boring bivalve traces in modern reef and deeper-water macroid and rhodolith beds

Macroids and rhodoliths, made by encrusting acervulinid foraminifera and coralline algae, are widely recognized as bioengineers providing relatively stable microhabitats and increasing biodiversity for other species. Macroid and rhodolith beds occur in different depositional settings at various localities and bathymetries worldwide. Six case studies of macroid/rhodolith beds from 0 to 117m water depth in the Pacific Ocean (northern Central Ryukyu Islands, French Polynesia), eastern Australia (Fraser Island, One Tree Reef, Lizard Island), and the Mediterranean Sea (southeastern Spain) show that nodules in the beds are perforated by small-sized boring bivalve traces (Gastrochanolites). On average, boring bivalve shells (gastrochaenids and mytilids) are more slender and smaller than those living inside shallow-water rocky substrates. In the Pacific, Gastrochaena cuneiformis, Gastrochaena sp., Leiosolenus malaccanus, L. mucronatus, L. spp., and Lithophaga/Leiosolenus sp., for the first time identified below 20m water depth, occur as juvenile forms along with rare small-sized adults. In deep-water macroids and rhodoliths the boring bivalves are larger than the shallower counterparts in which growth of juveniles is probably restrained by higher overturn rates of host nodules. In general, most boring bivalves are juveniles that grew faster than the acervulinid foraminiferal and coralline red algal hosts and rarely reached the adult stage. As a consequence of phenotypic plasticity, small-sized adults with slow growth rates coexist with juveniles. Below wave base macroids and rhodoliths had the highest amounts of bioerosion, mainly produced by sponges and polychaete worms. These modern observations provide bases for paleobiological inferences in fossil occurrences.Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT) Japan Society for the Promotion of Science Grants-in-Aid for Scientific Research (KAKENHI) 25247083Erasmus+FAR2012-2017FIR2016FIR2018PRIN "Biotic resilience to global change: biomineralization of planktonic and benthic calcifiers in the past, present and future" 2017RX9XXXYBioMed Central-Prepay Membership at the University of FerraraJunta de Andalucía RNM 190Committee on ResearchMuseum of PaleontologyDepartment of Integrative Biology, UC BerkeleyUC Pacific Rim Projec

Line Emission from an Accretion Disk around a Rotating Black Hole: Toward a Measurement of Frame Dragging

Line emission from an accretion disk and a corotating hot spot about a rotating black hole are considered for possible signatures of the frame-dragging effect. We explicitly compare integrated line profiles from a geometrically thin disk about a Schwarzschild and an extreme Kerr black hole, and show that the line profile differences are small if the inner radius of the disk is near or above the Schwarzschild stable-orbit limit of radius 6GM/c^2. However, if the inner disk radius extends below this limit, as is possible in the extreme Kerr spacetime, then differences can become significant, especially if the disk emissivity is stronger near the inner regions. We demonstrate that the first three moments of a line profile define a three-dimensional space in which the presence of material at small radii becomes quantitatively evident in broad classes of disk models. In the context of the simple, thin disk paradigm, this moment-mapping scheme suggests formally that the iron line detected by the Advanced Satellite for Cosmology and Astrophysics mission from MCG-6-30-15 (Tanaka et al. 1995) is 3 times more likely to originate from a disk about a rotating black hole than from a Schwarzschild system. A statistically significant detection of black hole rotation in this way may be achieved after only modest improvements in the quality of data. We also consider light curves and frequency shifts in line emission as a function of time for corotating hot spots in extreme Kerr and Schwarzschild geometries. Both the frequency-shift profile and the light curve from a hot spot are valuable measures of orbital parameters and might possibly be used to detect frame dragging even at radii approaching 6GM/c^2 if the inclination angle of the orbital plane is large.Comment: 15 pages (LaTex), 7 postscript figures; color plot (Figure 1) available at http://cfata2.harvard.edu/bromley/nu_nofun.html (This version contains a new subsection as well as minor corrections.

3DFeat-Net: Weakly Supervised Local 3D Features for Point Cloud Registration

In this paper, we propose the 3DFeat-Net which learns both 3D feature detector and descriptor for point cloud matching using weak supervision. Unlike many existing works, we do not require manual annotation of matching point clusters. Instead, we leverage on alignment and attention mechanisms to learn feature correspondences from GPS/INS tagged 3D point clouds without explicitly specifying them. We create training and benchmark outdoor Lidar datasets, and experiments show that 3DFeat-Net obtains state-of-the-art performance on these gravity-aligned datasets.Comment: 17 pages, 6 figures. Accepted in ECCV 201

Survey on Vision-based Path Prediction

Path prediction is a fundamental task for estimating how pedestrians or vehicles are going to move in a scene. Because path prediction as a task of computer vision uses video as input, various information used for prediction, such as the environment surrounding the target and the internal state of the target, need to be estimated from the video in addition to predicting paths. Many prediction approaches that include understanding the environment and the internal state have been proposed. In this survey, we systematically summarize methods of path prediction that take video as input and and extract features from the video. Moreover, we introduce datasets used to evaluate path prediction methods quantitatively.Comment: DAPI 201

Line Emission from an Accretion Disk around a Black hole: Effects of Disk Structure

The observed iron K-alpha fluorescence lines in Seyfert-1 galaxies provide strong evidence for an accretion disk near a supermassive black hole as a source of the line emission. These lines serve as powerful probes for examining the structure of inner regions of accretion disks. Previous studies of line emission have considered geometrically thin disks only, where the gas moves along geodesics in the equatorial plane of a black hole. Here we extend this work to consider effects on line profiles from finite disk thickness, radial accretion flow and turbulence. We adopt the Novikov and Thorne (1973) solution, and find that within this framework, turbulent broadening is the dominant new effect. The most prominent change in the skewed, double-horned line profiles is a substantial reduction in the maximum flux at both red and blue peaks. The effect is most pronounced when the inclination angle is large, and when the accretion rate is high. Thus, the effects discussed here may be important for future detailed modeling of high quality observational data.Comment: 21 pages including 8 figures; LaTeX; ApJ format; accepted by ApJ; short results of this paper appeared before as a conference proceedings (astro-ph/9711214