Stability assessment of sulphur (II) compounds in medicinal water from B-8b Michał intake in Busko-Zdrój

In this paper, the stability of sulphur (II) compounds determined as the sum of hydrogen sulphide, hydrosulphides and sulphides was evaluated in groundwater sourced from the B-8b Michał intake. Sulphide waters are a valuable raw material used as a basis for spa treatment in Busko-Zdrój. Based on the chemical composition analyses conducted in the years 1946–2018, a general analysis of random variability and statistical analysis of data was performed using PS IMAGO 5.0.1 software. Stability assessment was carried out on the data set for the 2009–2018 period on the basis of individual measurement control charts. Trend analysis was also performed using the GWSDAT software

A probabilistic approach to assessment of the quality of drinking water

Knowledge of uncertainty in analytical results is of prime importance in assessments of compliance with requirements set out for the quality of water intended for human consumption. Assessments of drinking water quality can be performed using either a deterministic or a probabilistic method. In the former approach, every single result is referred directly to the parametric value, while in the probabilistic method uncertainty related to analytical results is taken into account during the decision-making process. In the present research, laboratory uncertainty and uncertainty determined on the basis of results of analyses of duplicate samples collected in two Polish cities were compared and used in the probabilistic approach of water quality assessment. Using the probabilistic method, more results were considered to be “above the parametric value”. Most excesses were observed when the maximum allowable uncertainty as set out in the Regulation of the Minister of Health of 7 December 2017 was used, which is due to the highest values of these uncertainties. The lowest values above parametric values in the probabilistic approach were observed when measurement uncertainty was considered

Methodological aspects concerning sampling and determination of total selenium and selenium species in geothermal waters

The work presents the results of geothermal water sample analysis with respect to the determination of total selenium concentration. For this purpose, geothermal water (GT) samples were collected from three different intakes (GT-1, GT-2, GT-3) with similar temperatures of about 85ºC. Tests were carried out to see if the methodology of sample preparation influenced total selenium concentration during analysis by inductively coupled plasma mass spectrometry (ICP-MS). Samples (raw and filtered) were preserved with nitric acid (HNO3) and mineralised in the laboratory. From the data obtained it was found that there is no significant difference between total selenium concentration in raw and filtered samples. Following mineralisation, the concentrations in the samples were below the limit of detection or limit of quantification. While different analytical steps or procedures are applied, the results of total selenium concentration can vary. Furthermore, high-performance liquid chromatography coupled with ICP-MS was used for the identification of selenium species. The results revealed that hexavalent selenium – Se(VI) – in the geothermal water was found only in samples collected from the GT-2 and GT-3 intakes

Deterministic and probabilistic approaches to the denomination of the hydrochemical type of potentially medicinal groundwater from the “Zdrój Główny” intake (Krzeszowice, Poland)

The analysis and quality control of potentially curative water in Krzeszowice (Lesser Poland Region, Poland) has been carried out since 2002. The analyses are performed in the certified Hydrogeochemical Laboratory of the AGH University of Science and Technology and the laboratory of Provincial Environmental Protection Inspectorate in Krakow. The main purpose of this paper was to confirm the denomination of the hydrochemical type of water taken from “Zdroj Głowny” both for major ions and sulphur(II) compounds concentration which are specific components and assign curative properties to the examined water. On the basis of statistical analysis, it was stated that the concentrations of SO4, Ca, Mg, HCO3 and sulphur(II) compounds can be regarded as stable. Different methods of hydrochemical type determination lead to various classifications of groundwater. In the deterministic method and the probabilistic method with use of expanded uncertainty, the hydrochemical type of the examined water is SO4-Ca-Mg, S. In the probabilistic method where the standard deviation was taken into account, fewer components were in the hydrochemical type (SO4-Ca)-sulphur(II) compounds did not exceed the threshold value of 1 mg/L and, in this situation, the water cannot be regarded as potentially curative

Human Health Risk Assessment of Trace Elements in Tap Waterand the Factors Influencing Its Value

(1) Background: The influence of tap water fittings construction and internal pipe-work on the release of heavy metals was investigated. (2) Methods: A statistical approach was applied for the examination of the chemistry of tap water in five different cities in southern Poland. In total, 500 samples were collected (from 100 to 101 samples in each city). The sampling protocol included information on the construction of the water supply network and the physicochemical parameters of measured tap water. (3) Results: The statistical analysis allowed to extract the crucial factors that affect the concentrations of trace elements in tap water. Age of connection, age of tap, age of pipe-work as well as material of connection, material of pipe-work and material of appliance reveal the most significant variability of concentrations observed for As, Al, Cd, Cu, Fe, Mn, Pb, and Zn. Calculated cancer risks (CRs) decrease with the following order of analysed elements Ni > Cd > Cr > As = Pb and can be associated with the factors that affect the appearance of such elements in tap water. The hazard index (HI) was evaluated as negligible in 59.1% of the sampling points and low in 40.1% for adults. For children, a high risk was observed in 0.2%, medium in 9.0%, negligible in 0.4%, and low for the rest of the analysed samples

Inorganic Chromium Speciation in Geothermal Water of the Podhale Trough (Southern Poland) Used for Recreational Purposes

The results of total chromium determination (by ICP-OES method) in samples collected from nine working wells named GW1–GW9, exploiting geothermal water from the Podhale Trough (southern part of Poland, near the Tatra Mountains), which is used for recreational purposes, were implemented for hydrogeochemical modeling to indicate dominating chromium speciation. The reliability of the results was determined by the application of a quality assurance/quality control program, both in the laboratory and during field work. Based on chromium speciation, the risk associated with the utilization of geothermal water was calculated. The outcome showed that the concentration of Cr(III) is almost equal to the total chromium concentration (1–2 µg·L−1). Crtot concentrations were also used in a health risk assessment in the case of epidermal absorption (EDIderm) during bathing in thermal pools and four assumed scenarios in relation to the handling of geothermal water. The effect of the very low Crtot concentration in the analyzed water on health risk calculation was estimated as low (hazard quotient value <10−7). In the case of risk matrix analysis, the environmental risks were estimated as moderate, major and very severe, dependent on the assumed scenario

A probabilistic approach to assessment of the quality of drinking water

Knowledge of uncertainty in analytical results is of prime importance in assessments of compliance with requirements set out for the quality of water intended for human consumption. Assessments of drinking water quality can be performed using either a deterministic or a probabilistic method. In the former approach, every single result is referred directly to the parametric value, while in the probabilistic method uncertainty related to analytical results is taken into account during the decision-making process. In the present research, laboratory uncertainty and uncertainty determined on the basis of results of analyses of duplicate samples collected in two Polish cities were compared and used in the probabilistic approach of water quality assessment. Using the probabilistic method, more results were considered to be “above the parametric value”. Most excesses were observed when the maximum allowable uncertainty as set out in the Regulation of the Minister of Health of 7 December 2017 was used, which is due to the highest values of these uncertainties. The lowest values above parametric values in the probabilistic approach were observed when measurement uncertainty was considered

Dataset for "Magnetic field generation using single-plate targets driven by kJ-ns class laser"

Dataset underpinning the results presented in the article titled, "Magnetic field generation using single-plate targets driven by kJ-ns class laser" published in Plasma Physics Controlled Fusion (2020) Abstract of the paper: Strong magnetic fields of upto 20 T, corresponding to a current of tens of kA were produced in a coil connected to a single-plate of cm2 area irradiated by a kJ-ns laser pulse. The use of such macroscopic plates protects the coil from plasma debris, while maintaining a strong magnetic field for a time-scale much longer than the laser pulse duration. By correlating the measured magnetic field in the coil to the number of electrons emitted from the interaction zone, we deduce that the target capacitance is enhanced by two orders of magnitude because of the plasma sheath in the proximity of the focal spot. Particle-in-cell simulations illustrate the dynamics of sheath potential and current flow through the coil to ground, thus closing the circuit due to the escape of laser-produced hot electrons from the target