Modifications in aerosol physical, optical and radiative properties during heavy aerosol events over Dushanbe, Central Asia

The location of Central Asia, almost at the center of the global dust belt region, makes it susceptible for dust events. The studies on atmospheric impact of dust over the region are very limited despite the large area occupied by the region and its proximity to the mountain regions (Tianshan, Hindu Kush-Karakoram-Himalayas, and Tibetan Plateau). In this study, we analyse and explain the modification in aerosols’ physical, optical and radiative properties during various levels of aerosol loading observed over Central Asia utilizing the data collected during 2010–2018 at the AERONET station in Dushanbe, Tajikistan. Aerosol episodes were classified as strong anthropogenic, strong dust and extreme dust. The mean aerosol optical depth (AOD) during these three types of events was observed a factor of ~3, 3.5 and 6.6, respectively, higher than the mean AOD for the period 2010–2018. The corresponding mean fine-mode fraction was 0.94, 0.20 and 0.16, respectively, clearly indicating the dominance of fine-mode anthropogenic aerosol during the first type of events, whereas coarse-mode dust aerosol dominated during the other two types of events. This was corroborated by the relationships among various aerosol parameters (AOD vs. AE, and EAE vs. AAE, SSA and RRI). The mean aerosol radiative forcing (ARF) at the top of the atmosphere (ARFTOA), the bottom of the atmosphere (ARFBOA), and in the atmosphere (ARFATM) were −35 ± 7, −73 ± 16, and 38 ± 17 Wm−2 during strong anthropogenic events, −48 ± 12, −85 ± 24, and 37 ± 15 Wm−2 during strong dust event, and −68 ± 19, −117 ± 38, and 49 ± 21 Wm−2 during extreme dust events. Increase in aerosol loading enhanced the aerosol-induced atmospheric heating rate to 0.5–1.6 K day−1 (strong anthropogenic events), 0.4–1.9 K day−1 (strong dust events) and 0.8–2.7 K day−1 (extreme dust events). The source regions of air masses to Dushanbe during the onset of such events are also identified. Our study contributes to the understanding of dust and anthropogenic aerosols, in particular the extreme events and their disproportionally high radiative impacts over Central Asia

Black carbon and organic carbon dataset over the Third Pole

The Tibetan Plateau and its surroundings, also known as the Third Pole, play an important role in the global and regional climate and hydrological cycle. Carbonaceous aerosols (CAs), including black carbon (BC) and organic carbon (OC), can directly or indirectly absorb and scatter solar radiation and change the energy balance on the Earth. CAs, along with the other atmospheric pollutants (e.g., mercury), can be frequently transported over long distances into the inland Tibetan Plateau. During the last decades, a coordinated monitoring network and research program named “Atmospheric Pollution and Cryospheric Changes” (APCC) has been gradually set up and continuously operated within the Third Pole regions to investigate the linkage between atmospheric pollutants and cryospheric changes. This paper presents a systematic dataset of BC, OC, water-soluble organic carbon (WSOC), and water-insoluble organic carbon (WIOC) from aerosols (20 stations), glaciers (17 glaciers, including samples from surface snow and ice, snow pits, and 2 ice cores), snow cover (2 stations continuously observed and 138 locations surveyed once), precipitation (6 stations), and lake sediment cores (7 lakes) collected across the Third Pole, based on the APCC program. These data were created based on online (in situ) and laboratory measurements. High-resolution (daily scale) atmospheric-equivalent BC concentrations were obtained by using an Aethalometer (AE-33) in the Mt. Everest (Qomolangma) region, which can provide new insight into the mechanism of BC transportation over the Himalayas. Spatial distributions of BC, OC, WSOC, and WIOC from aerosols, glaciers, snow cover, and precipitation indicated different features among the different regions of the Third Pole, which were mostly influenced by emission sources, transport pathways, and deposition processes. Historical records of BC from ice cores and lake sediment cores revealed the strength of the impacts of human activity since the Industrial Revolution. BC isotopes from glaciers and aerosols identified the relative contributions of biomass and fossil fuel combustion to BC deposition on the Third Pole. Mass absorption cross sections of BC and WSOC from aerosol, glaciers, snow cover, and precipitation samples were also provided. This updated dataset is released to the scientific communities focusing on atmospheric science, cryospheric science, hydrology, climatology, and environmental science. The related datasets are presented in the form of excel files. BC and OC datasets over the Third Pole are available to download from the National Cryosphere Desert Data Center (10.12072/ncdc.NIEER.db0114.2021; Kang and Zhang, 2021)

Influence of transboundary air pollution on air quality in southwestern China

Air pollution is a grand challenge of our time due to its multitude of adverse impacts on environment and society, with the scale of impacts more severe in developing countries, including China. Thus, China has initiated and implemented strict air pollution control measures over last several years to reduce impacts of air pollution. Monitoring data from Jan 2015 to Dec 2019 on six criteria air pollutants (SO2, NO2, CO, O3, PM2.5, and PM10) at eight sites in southwestern China were investigated to understand the situation and analyze the impacts of transboundary air pollutants in this region. In terms of seasonal variation, the maximum concentrations of air pollutants at these sites were observed in winter or spring season depending on individual site. For diurnal variation, surface ozone peaked in the afternoon while the other pollutants had a bimodal pattern with peaks in the morning and late afternoon. There was limited transport of domestic emissions of air pollutants in China to these sites. Local emissions enhanced the concentrations of air pollutants during some pollution events. Mostly, the transboundary transport of air pollution from South Asia and Southeast Asia was associated with high concentrations of most air pollutants observed in southwestern China. Since air pollutants can be transported to southwestern China over long distances from the source regions, it is necessary to conduct more research to properly attribute and quantify transboundary transport of air pollutants, which will provide more solid scientific guidance for air pollution management in southwestern China

Water-Soluble Ionic Composition of Aerosols at Urban Location in the Foothills of Himalaya, Pokhara Valley, Nepal

The total suspended particulate (TSP) samples were collected from April 2013 to April 2014 at the urban location of Pokhara valley in western Nepal. The major aims were to study, quantify, and understand the concentrations and variations of TSP and major water-soluble inorganic ions (WSIIs) in the valley with limited data. The annual average TSP mass concentration was 135.50 ± 62.91 µg/m3. The average analyzed total WSIIs accounted for 14.4% of total TSP mass. Major anions and cations in TSP samples were SO42− and Ca2+, respectively. Seasonal differences in atmospheric conditions explain the clear seasonal variations of ions, with higher concentrations during pre-monsoon and winter and lower concentrations during the monsoon period. Neutralization factor calculations suggested that Ca2+ in the Pokhara valley mostly neutralizes the acidity in the atmosphere. Principle component analysis, NO3−/SO42− ratio, and non-sea salt fraction calculations suggested that the WSIIs in the valley were mostly derived from anthropogenic activities and crustal mineral dust, which was also supported by the results from precipitation chemistry over the central Himalayas, Nepal. In addition, back trajectories analysis has suggested that the air pollution transported from and through Indo-Gangetic Plains (IGP) during the dry periods, which has resulted in high ionic loadings during this period. Average NO3−/SO42− ratio was found to be 0.69, indicating the dominance of stationary sources of TSP in Pokhara valley. Secondary inorganic aerosols can have an adverse health impact on the human population in the valley. The data set from this one-year study provides new insights into the composition of WSIIs in the foothills of the Himalayas, which can be of great importance for understanding the atmospheric environment in the region

Health risk assessment of atmospheric polycyclic aromatic hydrocarbons over the Central Himalayas

<p>Carcinogenic risk assessments of polycyclic aromatic hydrocarbons (PAHs) in four sites from the Central Himalayas (Bode, Lumbini, Pokhara, and Dhunche) were performed. Lifetime Average Daily Dose (LADD), Lifetime lung cancer risk (LLCR) and Incremental lifetime cancer risk (ILCR) were calculated in order to evaluate the cancer risk. PAHs levels were converted to BaP equivalent concentrations (B[a]Peq), and models of health risk assessment were applied. B[a]Peq concentrations exceeded the standard limited value (1 ng/m³) in all the four sites. The human health risk assessment (HHRA) demonstrated high carcinogenic risk on residents of Bode and Lumbini. Further, LLCR in all sites were over the acceptable range (1.15E-03, 7.90E-04, 1.40E-04 and 9.96E-05, respectively); however, ILCR ranking exhibited acceptable range in Lumbini, Pokhara, and Dhunche (7.10E-06, 1.26E-06, and 8.95E-07). The risk variation among the sites is due to the difference in pollution status. The study shows health risk due to atmospheric PAHs via inhalation prevails all the seasons throughout, differing only seasonally; nevertheless, the concentration and carcinogenic risk decreased remarkably from south-north transect of the central Himalaya. Keeping some uncertainties aside, this study provides noble insights and helps to formulate new advance assessment on the carcinogenic risk of atmospheric PAHs over the Central Himalayas.</p

Spatial distribution and risk assessments of mercury in topsoils of Central Asia

Central Asia is one of the largest arid areas on earth, yet little is known about the concentration levels and risks of mercury (Hg) in the soils of this region. In this study, extensive sampling of topsoils (0–10 cm) from representative landscapes was carried out over Central Asia (i.e., Tajikistan, Uzbekistan, and Kyrgyzstan). The total mercury (THg) concentrations in topsoils varied widely from 1.6 to 908.0 ng/g, with high values observed in samples collected in the capital cities and urban areas. Topsoil THg concentrations among different landscapes showed a decreasing order of urban (79.8±184.0 ng/g) > woodland (27.3±28.9 ng/g) > grassland (20.6±15.9 ng/g) > farmland (18.3±9.5 ng/g) > desert (12.3±8.0 ng/g). High THg concentrations were found in the capital cities/urban clusters, followed by a gradual decrease towards the peripheries. THg concentrations were found to be negatively correlated with the distance from the sampling sites to their nearest cities, indicating that anthropogenic emissions significantly influenced the spatial distribution of topsoil Hg. A significant correlation between THg concentrations and topsoil total organic carbon (TOC) contents was also observed, suggesting that TOC played an essential role in the spatial distribution of topsoil Hg. The assessments of pollution and potential ecological risk suggested that topsoils in highly densely-populated areas were contaminated by Hg and had higher degrees of potential ecological risks. The health risk assessment results showed that the exposure risk of topsoil Hg to children was higher than that to adults. Fortunately, there was no unacceptable human health risk of topsoil Hg. This study clarified the spatial distribution and risks of Hg in the Central Asian topsoils, offering new insight into the risk prevention and control of soil Hg