1,178 research outputs found
Pressure-induced insulator-to-metal transition in low-dimensional TiOCl
We studied the transmittance and reflectance of the low-dimensional
Mott-Hubbard insulator TiOCl in the infrared and visible frequency range as a
function of pressure. The strong suppression of the transmittance and the
abrupt increase of the near-infrared reflectance above 12 GPa suggest a
pressure-induced insulator-to-metal transition. The pressure-dependent
frequency shifts of the orbital excitations, as well as the pressure
dependences of the charge gap and the spectral weight of the optical
conductivity above the phase transition are presented.Comment: 4 pages, 6 figure
Pressure-induced metallization and structural phase transition of the Mott-Hubbard insulator TiOBr
We investigated the pressure-dependent optical response of the
low-dimensional Mott-Hubbard insulator TiOBr by transmittance and reflectance
measurements in the infrared and visible frequency range. A suppression of the
transmittance above a critical pressure and a concomitant increase of the
reflectance are observed, suggesting a pressure-induced metallization of TiOBr.
The metallic phase of TiOBr at high pressure is confirmed by the presence of
additional excitations extending down to the far-infrared range. The
pressure-induced metallization coincides with a structural phase transition,
according to the results of x-ray powder diffraction experiments under
pressure.Comment: 4 pages, 3 figure
Evolution equations for slowly rotating stars
We present a hyperbolic formulation of the evolution equations describing
non-radial perturbations of slowly rotating relativistic stars in the
Regge--Wheeler gauge. We demonstrate the stability preperties of the new
evolution set of equations and compute the polar w-modes for slowly rotating
stars.Comment: 27 pages, 2 figure
Atomistic Simulations of Nanotube Fracture
The fracture of carbon nanotubes is studied by atomistic simulations. The
fracture behavior is found to be almost independent of the separation energy
and to depend primarily on the inflection point in the interatomic potential.
The rangle of fracture strians compares well with experimental results, but
predicted range of fracture stresses is marketly higher than observed. Various
plausible small-scale defects do not suffice to bring the failure stresses into
agreement with available experimental results. As in the experiments, the
fracture of carbon nanotubes is predicted to be brittle. The results show
moderate dependence of fracture strength on chirality.Comment: 12 pages, PDF, submitted to Phy. Rev.
Myofunctional Therapy to Treat Obstructive Sleep Apnea: A Systematic Review and Meta-analysis.
OBJECTIVE:
To systematically review the literature for articles evaluating myofunctional therapy (MT) as treatment for obstructive sleep apnea (OSA) in children and adults and to perform a meta-analysis on the polysomnographic, snoring, and sleepiness data.
DATA SOURCES:
Web of Science, Scopus, MEDLINE, and The Cochrane Library.
REVIEW METHODS:
The searches were performed through June 18, 2014. The Preferred Reporting Items for Systematic Reviews and Meta-Analysis (PRISMA) statement was followed.
RESULTS:
Nine adult studies (120 patients) reported polysomnography, snoring, and/or sleepiness outcomes. The pre- and post-MT apneahypopnea indices (AHI) decreased from a mean ± standard deviation (M ± SD) of 24.5 ± 14.3/h to 12.3 ± 11.8/h, mean difference (MD) -14.26 [95% confidence interval (CI) -20.98, -7.54], P < 0.0001. Lowest oxygen saturations improved from 83.9 ± 6.0% to 86.6 ± 7.3%, MD 4.19 (95% CI 1.85, 6.54), P = 0.0005. Polysomnography snoring decreased from 14.05 ± 4.89% to 3.87 ± 4.12% of total sleep time, P < 0.001, and snoring decreased in all three studies reporting subjective outcomes. Epworth Sleepiness Scale decreased from 14.8 ± 3.5 to 8.2 ± 4.1. Two pediatric studies (25 patients) reported outcomes. In the first study of 14 children, the AHI decreased from 4.87 ± 3.0/h to 1.84 ± 3.2/h, P = 0.004. The second study evaluated children who were cured of OSA after adenotonsillectomy and palatal expansion, and found that 11 patients who continued MT remained cured (AHI 0.5 ± 0.4/h), whereas 13 controls had recurrent OSA (AHI 5.3 ± 1.5/h) after 4 y.
CONCLUSION:
Current literature demonstrates that myofunctional therapy decreases apnea-hypopnea index by approximately 50% in adults and 62% in children. Lowest oxygen saturations, snoring, and sleepiness outcomes improve in adults. Myofunctional therapy could serve as an adjunct to other obstructive sleep apnea treatments
Dipole Interactions and Electrical Polarity in Nanosystems -- the Clausius-Mossotti and Related Models
Point polarizable molecules at fixed spatial positions have solvable
electrostatic properties in classical approximation, the most familiar being
the Clausius-Mossotti (CM) formula. This paper generalizes the model and
imagines various applications to nanosystems. The behavior is worked out for a
sequence of octahedral fragments of simple cubic crystals, and the crossover to
the bulk CM law is found. Some relations to fixed moment systems are discussed
and exploited. The one-dimensional dipole stack is introduced as an important
model system. The energy of interaction of parallel stacks is worked out, and
clarifies the diverse behavior found in different crystal structures. It also
suggests patterns of self-organization which polar molecules in solution might
adopt. A sum rule on the stack interaction is found and tested. Stability of
polarized states under thermal fluctuations is discussed, using the
one-dimensional domain wall as an example. Possible structures for polar hard
ellipsoids are considered. An idea is formulated for enhancing polarity of
nanosystems by intentionally adding metallic coatings.Comment: 18 pages (includes 6 embedded figures and 3 tables). New references,
and other small improvements. Scheduled for publication by J. Chem. Phys.,
Jan. 200
Nanoscale Weibull Statistics
In this paper a modification of the classical Weibull Statistics is developed
for nanoscale applications. It is called Nanoscale Weibull Statistics. A
comparison between Nanoscale and classical Weibull Statistics applied to
experimental results on fracture strength of carbon nanotubes clearly shows the
effectiveness of the proposed modification. A Weibull's modulus around 3 is,
for the first time, deduced for nanotubes. The approach can treat (also) a
small number of structural defects, as required for nearly defect free
structures (e.g., nanotubes) as well as a quantized crack propagation (e.g., as
a consequence of the discrete nature of matter), allowing to remove the
paradoxes caused by the presence of stress-intensifications
Design concepts for broadband high-efficiency DOEs
Several design-concepts are presented for so-called efficiency achromatized diffractive optical elements (EA-DOEs) possessing diffraction efficiency larger than 97% over a broad spectral range. We start with tracing two different methods for surface relief profiles well known from the literature: common depth and multilayer EA-DOEs. Successively we present the following new approaches together with design parameters and performance properties: 1) gradient-index EA DOEs, 2) sub-wavelength EA-DOEs, and 3) a so-called cut-and-paste strategy. All designs are based on scalar assumptions and certain necessary dispersion relations of two different materials. The scalar assumption is no real limitation as the minimum zone width of our main application, the correction of chromatic aberrations, is 50 -100 times the wavelength. From aforementioned relations, design parameters as profile heights are derived and the resulting diffraction efficiency can be deduced. Additionally it turns out that the necessary dispersion relation concerning the sub-wavelength EA-DOE is the same as for the common depth EA-DOE. Moreover, for the multilayer EA-DOE we were able to show that if the dispersion relations of the materials can be accurately described by a second order Cauchy series, the efficiency becomes generic and will be the same regardless of which materials are chosen. By proper choice of the materials, all types of EA-DOEs yield thicknesses of 10 - 30 µm which is more than ten times larger than for conventional DOEs. Due to the small refractive index difference of GRIN materials, such EA-DOEs exhibit thicknesses of 90 µm and more. Therefore, it is advisable to look for material combinations which yield thicknesses as small as possible
Accurate strain measurements in highly strained Ge microbridges
Ge under high strain is predicted to become a direct bandgap semiconductor.
Very large deformations can be introduced using microbridge devices. However,
at the microscale, strain values are commonly deduced from Raman spectroscopy
using empirical linear models only established up to 1.2% for uniaxial stress.
In this work, we calibrate the Raman-strain relation at higher strain using
synchrotron based microdiffraction. The Ge microbridges show unprecedented high
tensile strain up to 4.9 % corresponding to an unexpected 9.9 cm-1 Raman shift.
We demonstrate experimentally and theoretically that the Raman strain relation
is not linear and we provide a more accurate expression.Comment: 10 pages, 4 figure
- …