Strongly nonlinear waves in capillary electrophoresis

In capillary electrophoresis, sample ions migrate along a micro-capillary filled with a background electrolyte under the influence of an applied electric field. If the sample concentration is sufficiently high, the electrical conductivity in the sample zone could differ significantly from the background.Under such conditions, the local migration velocity of sample ions becomes concentration dependent resulting in a nonlinear wave that exhibits shock like features. If the nonlinearity is weak, the sample concentration profile, under certain simplifying assumptions, can be shown to obey Burgers' equation (S. Ghosal and Z. Chen Bull. Math. Biol. 2010, 72(8), pg. 2047) which has an exact analytical solution for arbitrary initial condition.In this paper, we use a numerical method to study the problem in the more general case where the sample concentration is not small in comparison to the concentration of background ions. In the case of low concentrations, the numerical results agree with the weakly nonlinear theory presented earlier, but at high concentrations, the wave evolves in a way that is qualitatively different.Comment: 7 pages, 5 figures, 1 Appendix, 2 videos (supplementary material

Reynolds number effect on the velocity increment skewness in isotropic turbulence

Second and third order longitudinal structure functions and wavenumber spectra of isotropic turbulence are computed using the EDQNM model and compared to results of the multifractal formalism. At the highest Reynolds number available in windtunnel experiments, $R_\lambda=2500$, both the multifractal model and EDQNM give power-law corrections to the inertial range scaling of the velocity increment skewness. For EDQNM, this correction is a finite Reynolds number effect, whereas for the multifractal formalism it is an intermittency correction that persists at any high Reynolds number. Furthermore, the two approaches yield realistic behavior of second and third order statistics of the velocity fluctuations in the dissipative and near-dissipative ranges. Similarities and differences are highlighted, in particular the Reynolds number dependence

Binding branched and linear DNA structures: from isolated clusters to fully bonded gels

The proper design of DNA sequences allows for the formation of well defined supramolecular units with controlled interactions via a consecution of self-assembling processes. Here, we benefit from the controlled DNA self-assembly to experimentally realize particles with well defined valence, namely tetravalent nanostars (A) and bivalent chains (B). We specifically focus on the case in which A particles can only bind to B particles, via appropriately designed sticky-end sequences. Hence AA and BB bonds are not allowed. Such a binary mixture system reproduces with DNA-based particles the physics of poly-functional condensation, with an exquisite control over the bonding process, tuned by the ratio, r, between B and A units and by the temperature, T. We report dynamic light scattering experiments in a window of Ts ranging from 10{\deg}C to 55{\deg}C and an interval of r around the percolation transition to quantify the decay of the density correlation for the different cases. At low T, when all possible bonds are formed, the system behaves as a fully bonded network, as a percolating gel and as a cluster fluid depending on the selected r.Comment: 15 pages, 11 figure

Random Time Forward Starting Options

We introduce a natural generalization of the forward-starting options, first discussed by M. Rubinstein. The main feature of the contract presented here is that the strike-determination time is not fixed ex-ante, but allowed to be random, usually related to the occurrence of some event, either of financial nature or not. We will call these options {\bf Random Time Forward Starting (RTFS)}. We show that, under an appropriate "martingale preserving" hypothesis, we can exhibit arbitrage free prices, which can be explicitly computed in many classical market models, at least under independence between the random time and the assets' prices. Practical implementations of the pricing methodologies are also provided. Finally a credit value adjustment formula for these OTC options is computed for the unilateral counterparty credit risk.Comment: 19 pages, 1 figur

Dynamic multilateral markets

We study dynamic multilateral markets, in which players' payoffs result from intra-coalitional bargaining. The latter is modeled as the ultimatum game with exogenous (time-invariant) recognition probabilities and unanimity acceptance rule. Players in agreeing coalitions leave the market and are replaced by their replicas, which keeps the pool of market participants constant over time. In this infinite game, we establish payoff uniqueness of stationary equilibria and the emergence of endogenous cooperation structures when traders experience some degree of (heterogeneous) bargaining frictions. When we focus on market games with different player types, we derive, under mild conditions, an explicit formula for each type's equilibrium payoff as the market frictions vanish

The Mean-Field Limit for Solid Particles in a Navier-Stokes Flow

We propose a mathematical derivation of Brinkman's force for a cloud of particles immersed in an incompressible fluid. Our starting point is the Stokes or steady Navier-Stokes equations set in a bounded domain with the disjoint union of N balls of radius 1/N removed, and with a no-slip boundary condition for the fluid at the surface of each ball. The large N limit of the fluid velocity field is governed by the same (Navier-)Stokes equations in the whole domain, with an additional term (Brinkman's force) that is (minus) the total drag force exerted by the fluid on the particle system. This can be seen as a generalization of Allaire's result in [Arch. Rational Mech. Analysis 113 (1991), 209-259] who treated the case of motionless, periodically distributed balls. Our proof is based on slightly simpler, though similar homogenization techniques, except that we avoid the periodicity assumption and use instead the phase-space empirical measure for the particle system. Similar equations are used for describing the fluid phase in various models for sprays

Investigation of methods to produce a uniform cloud of fuel particles in a flame tube

The combustion of a uniform, quiescent cloud of 30-micron fuel particles in a flame tube was proposed as a space-based, low-gravity experiment. The subject is the normal- and low-gravity testing of several methods to produce such a cloud, including telescoping propeller fans, air pumps, axial and quadrature acoustical speakers, and combinations of these devices. When operated in steady state, none of the methods produced an acceptably uniform cloud (+ or - 5 percent of the mean concentration), and voids in the cloud were clearly visible. In some cases, severe particle agglomeration was observed; however, these clusters could be broken apart by a short acoustic burst from an axially in-line speaker. Analyses and experiments reported elsewhere suggest that transient, acoustic mixing methods can enhance cloud uniformity while minimizing particle agglomeration

Microscopic theory for the glass transition in a system without static correlations

We study the orientational dynamics of infinitely thin hard rods of length L, with the centers-of-mass fixed on a simple cubic lattice with lattice constant a.We approximate the influence of the surrounding rods onto dynamics of a pair of rods by introducing an effective rotational diffusion constant D(l),l=L/a. We get D(l) ~ [1-v(l)], where v(l) is given through an integral of a time-dependent torque-torque correlator of an isolated pair of rods. A glass transition occurs at l_c, if v(l_c)=1. We present a variational and a numerically exact evaluation of v(l).Close to l_c the diffusion constant decreases as D(l) ~ (l_c-l)^\gamma, with \gamma=1. Our approach predicts a glass transition in the absence of any static correlations, in contrast to present form of mode coupling theory.Comment: 6 pages, 3 figure

A correspondence of modular forms and applications to values of L-series

An interpretation of the Rogers–Zudilin approach to the Boyd conjectures is established. This is based on a correspondence of modular forms which is of independent interest. We use the reinterpretation for two applications to values of L-series and values of their derivatives