Properties of KCo2_2As2_2 and Alloys with Fe and Ru: Density Functional Calculations

Electronic structure calculations are presented for KCo$_2$As$_2$ and alloys with KFe$_2$As$_2$ and KRu$_2$As$_2$. These materials show electronic structures characteristic of coherent alloys, with a similar Fermi surface structure to that of the Fe-based superconductors, when the $d$ electron count is near six per transition metal. However, they are less magnetic than the corresponding Fe compounds. These results are discussed in relation to superconductivity.Comment: 5 page

Raman scattering study of electron-doped Prx_xCa1−x_{1-x}Fe2_2As2_2 superconductors

Temperature-dependent polarized Raman spectra of electron-doped superconducting Pr$_x$Ca$_{1-x}$Fe$_2$As$_2$ ($x \approx 0.12$) single crystals are reported. All four allowed by symmetry even-parity phonons are identified. Phonon mode of B$_{1g}$ symmetry at 222 cm$^{-1}$, which is associated with the c-axis motion of Fe ions, is found to exhibit an anomalous frequency hardening at low temperatures, that signals non-vanishing electron-phonon coupling in the superconducting state and implies that the superconducting gap magnitude $2\Delta_c < 27$meV.Comment: 4 pages, 3 figure

Superconductivity at 22 K in Co-doped BaFe2As2 Crystals

Here we report bulk superconductivity in BaFe1.8Co0.2As2 single crystals below Tc = 22 K, as demonstrated by resistivity, magnetic susceptibility, and specific heat data. Hall data indicate that the dominant carriers are electrons, as expected from simple chemical reasoning. This is the first example of superconductivity induced by electron doping in this family of materials. In contrast to the cuprates, the BaFe2As2 system appears to tolerate considerable disorder in the FeAs planes. First principles calculations for BaFe1.8Co0.2As2 indicate the inter-band scattering due to Co is weak.Comment: 9 pages, 3 figure

Corelaţie între substanţa uscată solubilă şi conţinutul de β-1,3 d-glucan la ciupercile Agaricus Blazei Murrill

Experiments carried out by the researchers,aboutthe extraction of the anti-tumour substances, likeprotein complex polysaccharides, whichhave demonstrated favorable effects of the immunostimulatory preparations and biologically active biomass obtained from certain species of fungi from the Basidiomicetaegroup.Thus, the antitumor activity of the β-1.3-D-glucan polysaccharide fractions extracted from mycelial biomass and fructification bodies of Agaricus blazei Murrill are well known.Mushrooms grown on synthetic substratewith wheat bran addition have a higher content of soluble dry substance (8.80%) and proteins (30.63% of the dm).The content of β-1.3-D-glucan, a specific substance in Agaricus blazei Murrill mushrooms, with a high biological value, is relatively high in the product obtained on the classic compost with the addition of cornflour and wheat bran (3.22-3.41mg100g-1dm).Regression obtained from the correlation of these,shows strong link between the two components beingvery significant in both case

Raman scattering study of (Kx_xSr1−x_{1-x})Fe2_2As2_2 (xx = 0.0, 0.4)

Polarized Raman spectra of non-superconducting SrFe$_2$As$_2$ and superconducting K$_{0.4}$Sr$_{0.6}$Fe$_2$As$_2$ ($T_c = 37$ K) are reported. All four phonon modes (A$_{1g}$ + B$_{1g}$ + 2E$_g$) allowed by symmetry, are found and identified. Shell model gives reasonable description of the spectra. No detectable anomalies are observed near the tetragonal-to-orthorhombic transition in SrFe$_2$As$_2$ or the superconducting transition in K$_{0.4}$Sr$_{0.6}$Fe$_2$As$_2$.Comment: 4 pages, 4 figures, 2 table

Response Mixture Modeling of Intraindividual Differences in Responses and Response Times to the Hungarian WISC-IV Block Design Test

Response times may constitute an important additional source of information about cognitive ability as it enables to distinguishing between different intraindividual response processes. In this paper, we present a method to disentangle interindividual variation from intraindividual variation in the responses and response times of 978 subjects to the 14 items of the Hungarian WISC-IV Block Design test. It is found that faster and slower responses differ in their measurement properties suggesting that there are intraindivual differences in the response processes adopted by the subjects

Interacţiunea dintre conţinutul de azot al substratului de cultură şi conţinutul de proteină al ciupercilor Agaricus Blazei Murrill

Mushrooms provide important sources of protein extracted from materials of very low economic value, such as manure, agricultural waste, forestry, wood industry.Cultivated mushrooms having a saprophyte diet are forced to feed their enzymes from decomposing organic substances.During the composting and pasteurization of the substrate, the proteinnitrogen is transformed into peptides and amino acids that are absorbed by mycelialhippocampal cells.Research has shown that there is a direct correlation between the total nitrogen content of the nutrient substrate (up to 2.7%), the production of mushrooms and the protein content of the mushrooms.In this study, four types of compost and three types of additional protein additions were investigated.The highest values of correlation coefficient (r = 0.88187) were obtained with the addition of3% wheat bran,additional protein supplement in the substrate

Breaking through the Mermin-Wagner limit in 2D van der Waals magnets

The Mermin-Wagner theorem states that long-range magnetic order does not exist in one- or two-dimensional (2D) isotropic magnets with short-ranged interactions. The theorem has been a milestone in magnetism and has been driving the research of recently discovered 2D van der Waals (vdW) magnetic materials from fundamentals up to potential applications. In such systems, the existence of magnetic ordering is typically attributed to the presence of a significant magnetic anisotropy, which is known to introduce a spin-wave gap and circumvent the core assumption of the theorem. Here we show that in finite-size 2D vdW magnets typically found in lab setups (e.g., within millimetres), short-range interactions can be large enough to allow the stabilisation of magnetic order at finite temperatures without any magnetic anisotropy for practical implementations. We demonstrate that magnetic ordering can be created in flakes of 2D materials independent of the lattice symmetry due to the intrinsic nature of the spin exchange interactions and finite-size effects in two-dimensions. Surprisingly we find that the crossover temperature, where the intrinsic magnetisation changes from superparamagnetic to a completely disordered paramagnetic regime, is weakly dependent on the system length, requiring giant sizes (e.g., of the order of the observable universe ~10$^{26}$ m) in order to observe the vanishing of the magnetic order at cryogenic temperatures as expected from the Mermin-Wagner theorem. Our findings indicate exchange interactions as the main driving force behind the stabilisation of short-range order in 2D magnetism and broaden the horizons of possibilities for exploration of compounds with low anisotropy at an atomically thin level

Superconductivity at 38 K in the iron arsenide (Ba1-xKx)Fe2As2

The ternary iron arsenide BaFe2As2 becomes superconducting by hole doping, which was achieved by partial substitution of the barium site with potassium. We have discovered bulk superconductivity up to Tc = 38 K in (Ba1-xKx)Fe2As2 with x = 0.4. The parent compound BaFe2As2 as well as KFe2As2 both crystallize in the tetragonal ThCr2Si2-type structure, which consists of (FeAs)- iron arsenide layers separated by barium or potassium ions. BaFe2As2 is a poor metal and exhibits a SDW anomaly at 140 K. By substituting Ba2+ for K+ ions we have introduced holes in the (FeAs)- layers, which suppress the SDW anomaly and induce superconductivity. This scenario is very similar to the recently discovered arsenide-oxide superconductors. The Tc of 38 K in (Ba1-xKx)Fe2As2 is the highest observed critical temperature in hole doped iron arsenide superconductors so far. Therefore, we were able to expand this class of superconductors by oxygen-free compounds with the ThCr2Si2-type structure. Our results suggest, that superconductivity in these systems essentially evolves from the (FeAs)- layers and may occur in other related compounds.Comment: 4 pages, 5 figures, submitted to Phys. Rev. Let

BaT2As2 Single Crystals (T = Fe, Co, Ni) and Superconductivity upon Co-doping

The crystal structure and physical properties of BaFe2As2, BaCo2As2, and BaNi2As2 single crystals are surveyed. BaFe2As2 gives a magnetic and structural transition at TN = 132(1) K, BaCo2As2 is a paramagnetic metal, while BaNi2As2 has a structural phase transition at T0 = 131 K, followed by superconductivity below Tc = 0.69 K. The bulk superconductivity in Co-doped BaFe2As2 below Tc = 22 K is demonstrated by resistivity, magnetic susceptibility, and specific heat data. In contrast to the cuprates, the Fe-based system appears to tolerate considerable disorder in the transition metal layers. First principles calculations for BaFe1.84Co0.16As2 indicate the inter-band scattering due to Co is weak.Comment: Accepted to Physica