1,148 research outputs found

    Conservatism of mineral magnetic signatures in farm dam sediments in the South African Karoo: the potential effects of particle size and post-depositional diagenesis

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    Purpose: A methodology was developed to evaluate and mitigate the impacts of particle size and post-depositional diagenesis when using mineral magnetic signatures to trace the sources of historically deposited sediment in farm dams in the South African Karoo. Materials and methods: Samples from a range of potential sediment sources were sieved to different particle size fractions, and the relationships between pairs of tracer signatures were established for each fraction. Non-conservatism of the magnetic signatures was determined by identifying whether the magnetic signatures of the farm dam sediments were within the range of those of the fractionated source samples. By fractionating the sediment source samples, the core samples were able to be traced using appropriately sized sources. Results and discussion: It was found that strong relationships existed between the pairs of tracer signatures at all particle size fractions. Relationships in the <32 ÎŒm fraction were significantly different to that of coarser fractions. It was also found that particle size had a large effect on all magnetic signatures and would prove to be a large source of uncertainty if not accounted for within any methodology developed for quantitative source discrimination and source apportionment. There was very little non-conservatism caused by diagenetic or biogenic processes in six of the seven dams sampled. In one dam, there was evidence to suggest that dissolution had probably caused the loss of almost all small superparamagnetic and stable single-domain grains. The other signatures associated with coarser magnetic grains in this dam were generally unaffected by the dissolution processes. Conclusions: The good preservation of magnetic signatures suggests that they can make reliable tracers over historical timescales (up to 164 years) in the Karoo and similar semi- arid catchments. However, the mitigation of particle size effects and screening for post-depositional alteration is an essential part of their use. The methodology presented in this paper is a potential way of recognising tracer non-conservatism and limiting its effects in future studies

    Use of sediment source fingerprinting to assess the role of subsurface erosion in the supply of fine sediment in a degraded catchment in the Eastern Cape, South Africa

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    Sediment source fingerprinting has been successfully deployed to provide information on the surface and subsurface sources of sediment in many catchments around the world. However, there is still scope to reexamine some of the major assumptions of the technique with reference to the number of fingerprint properties used in the model, the number of model iterations and the potential uncertainties of using more than one sediment core collected from the same floodplain sink. We investigated the role of subsurface erosion in the supply of fine sediment to two sediment cores collected from a floodplain in a small degraded catchment in the Eastern Cape, South Africa. The results showed that increasing the number of individual fingerprint properties in the composite signature did not improve the model goodness-of-fit. This is still a much debated issue in sediment source fingerprinting. To test the goodness-of-fit further, the number of model repeat iterations was increased from 5000 to 30,000. However, this did not reduce uncertainty ranges in modelled source proportions nor improve the model goodness-of-fit. The estimated sediment source contributions were not consistent with the available published data on erosion processes in the study catchment. The temporal pattern of sediment source contributions predicted for the two sediment cores was very different despite the cores being collected in close proximity from the same floodplain. This highlights some of the potential limitations associated with using floodplain cores to reconstruct catchment erosion processes and associated sediment source contributions. For the source tracing approach in general, the findings here suggest the need for further investigations into uncertainties related to the number of fingerprint properties included in un-mixing models. The findings support the current widespread use of <5000 model repeat iterations for estimating the key sources of sediment samples

    'White knuckle care work' : violence, gender and new public management in the voluntary sector

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    Drawing on comparative data from Canada and Scotland, this article explores reasons why violence is tolerated in non-profit care settings. This article will provide insights into how workers' orientations to work, the desire to care and the intrinsic rewards from working in a non-profit context interact with the organization of work and managerially constructed workplace norms and cultures (Burawoy, 1979) to offset the tensions in an environment characterized by scarce resources and poor working conditions. This article will also outline how the same environment of scarce resources causes strains in management's efforts to establish such cultures. Working with highly excluded service users with problems that do not respond to easy interventions, workers find themselves working at the edge of their endurance, hanging on by their fingernails, and beginning to participate in various forms of resistance; suggesting that even among the most highly committed, 'white knuckle care' may be unsustainable

    Assessment and Student Learning – a fundamental relationship and the role of information and communication technologies

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    This paper reviews the role of assessment in student learning and its relationship with the use of information and communication technologies (ICT). There is ample evidence of technology-led innovations failing to achieve the transformations expected by educators. We draw upon existing research to illustrate the links between aspects of student learning, assessment practices and the use of ICT. Assessment influences not only what parts of a course get studied, but also how those parts are studied. While the adoption of ICT does not, in itself, change student behaviours, appropriately designed assessment that exploits the potential of ICT can change students’ approaches to learning. We argue that ICT can enable important learning outcomes to be achieved, but these must be underpinned by an assessment strategy that cues students to adopt a suitable approach to learning

    Stroke surfaces: A spatio-temporal framework for temporally coherent nonphotorealistic animations

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    Nitrogen addition alters composition, diversity, and functioning of microbial communities in mangrove soils : an incubation experiment

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    Mangrove ecosystems are important for carbon storage due to their high productivity and low decomposition rates. Waterways have experienced increased nutrient loads as a result of anthropogenic activities and it is unclear how this may affect carbon and nutrient cycles in downstream mangroves that receive these nutrient-rich waters. Using a laboratory-based incubation experiment, this study aimed to assess the effects of nutrient addition on the diversity and structure of mangrove soil bacterial communities, as well as biomass and activity of the soil microbial community, under different oxygen conditions. Bacterial community diversity and composition was characterised using 16S rRNA gene sequencing and microbial activity was examined through the measurement of microbial respiration and the activities of enzymes associated with organic matter decomposition. Nitrogen addition caused clear shifts in bacterial community composition, with decreases in bacterial diversity and the abundance of sulfate-reducing bacteria. Microbial biomass also decreased with nitrogen addition under reduced oxygen incubations. Changes in bacterial community structure were accompanied by changes in the activity of some enzymes involved in carbon, nitrogen and phosphorus cycling. Under reduced oxygen conditions, nitrogen addition resulted in a significant increase in the microbial metabolic quotient but no accompanying change in microbial respiration, which was explained by a decrease in microbial biomass. The findings of this study indicate that nitrogen loading has potential implications for microbial communities and carbon and nutrient cycling in mangrove environments that warrant further investigation under field conditions

    Tracking the reflexivity of the (dis)engaged citizen: some methodological reflections

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    The relationship between governments and citizens in many contemporary democracies is haunted by uncertainty and sociologists face the task of listening effectively to citizens’ own reflections on this uncertain relationship. This article reflects on the qualitative methodology of a recently completed UK project which used a combination of diary and multiple interviews/ focus groups to track over a fieldwork period of up to a year citizens’ reflections on their relationship to a public world and the contribution to this of their media consumption. In particular, the article considers how the project’s multiple methods enabled multiple angles on the inevitable artificiality and performative dimension of the diary process, resulting in rich data on people’s complex reflections on the uncertain position of the contemporary citizen
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