Promoting Territorial Cultural Systems through Urban Planning

Europe is a land of ancient urbanization where nature and culture of places are inextricably intertwined, defining real territorial cultural systems. After the era of a hurried expansion of the cities linked to the industrial revolution, in the height of the digital era, urban planning finds the key to understanding space in cultural heritage. In a European territory that appears increasingly distinct between metropolitan and inner areas, both cultural heritages play an essential role in defining the paradigms of self-sustainable development that urban planning declares to promote. This is the basic assumption that the paper proposes starting from the analysis of the relationship between historic centers and natural landscapes, in search of a different use of the land, reversible, respectful of the environment but still capable of being the physical support for anthropogenic transformations and the productions of economy and life. Starting from a rereading of the relationship between cultural heritage and territorial systems, the paper elaborates a different vision of the historic centers as epicenters of possible economic networks and ecosystem services, based on the analysis of Italian and Eastern Europe experiences

Generalization from correlated sets of patterns in the perceptron

Generalization is a central aspect of learning theory. Here, we propose a framework that explores an auxiliary task-dependent notion of generalization, and attempts to quantitatively answer the following question: given two sets of patterns with a given degree of dissimilarity, how easily will a network be able to "unify" their interpretation? This is quantified by the volume of the configurations of synaptic weights that classify the two sets in a similar manner. To show the applicability of our idea in a concrete setting, we compute this quantity for the perceptron, a simple binary classifier, using the classical statistical physics approach in the replica-symmetric ansatz. In this case, we show how an analytical expression measures the "distance-based capacity", the maximum load of patterns sustainable by the network, at fixed dissimilarity between patterns and fixed allowed number of errors. This curve indicates that generalization is possible at any distance, but with decreasing capacity. We propose that a distance-based definition of generalization may be useful in numerical experiments with real-world neural networks, and to explore computationally sub-dominant sets of synaptic solutions

Environmental Strategy in Business: Green Marketing Communication

Purpose: The aim of the paper is to explore the issues of green marketing and green marketing communication. Design/methodology/approach: The narrative literature review is a method applied to achieve the aim of the paper.Findings: The growth of environmental sensitivity is a driving force for change towards new policy tools and environmental eco-nomics. Businesses have developed various tools for environmen-tal communication including environmental balance sheets, social reports, and certifications. It is not enough for businesses to com-municate generic commitment to environmental protection; they have to integrate the concept of ecology into corporate culture by creating strong environmental policies and environmental ethics that describe the enterprise at all organisational levels. Businesses focusing on the development of green products must not only ‘talk ecologically’ but also ‘be ecological’.Research and practical limitations/implications: The research has an exploratory character since the sample strategy is not probabilistic.Originality/value: The study can stimulate discussion in the field of green marketing and green marketing communication.Paper type: literature review

Tactical Urbanism in Italy: From Grassroots to Institutional Tool—Assessing Value of Public Space Experiments

none3The paper aims to evaluate the value that the experimentation of tactical urban planning activities can assume for the city, through the critical account of some practices in three Italian cities of large (Milan), medium-large (Bari), and medium size (Taranto), which in recent years, in some cases unknowingly, have experienced its effects, also forced by the thrust offered by the need to respond to the consequences of the pandemic. The authors reflect on how short-term interventions started by tactical urbanism movement are inspiring planning institutions to implement short-term place-making initiatives. The contribution moves within the context of new generation urban regeneration in which the transformation of existing spaces is a process of community reconstruction through the redevelopment of public spaces increasingly open to multiple and temporary uses. First through a process of rereading the state of the art of the project of public spaces in Italy and its transformation caused by the pandemic, then through a comparative look between the three case studies, conclusions are drawn on the urban value of the experiments conducted and, on their ability, to identify a new reference point for the sustainable urban regeneration of public spaces.openCariello Alessandro, Ferorelli Rossella, Rotondo, FrancescoCariello, Alessandro; Ferorelli, Rossella; Rotondo, Francesc

catena-Poly[bis­(4-amino­pyridinium) [[tetra­aqua­nickel(II)]-μ-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]

The asymmetric unit of the title compound, {(C5H7N2)2[Ni(C10H2O8)(H2O)4]·2H2O}n, contains an NiII atom, two water mol­ecules of coordination, one half of a benzene-1,2,4,5-tetra­carboxyl­ate (btec) anionic ligand, one 4-amino­pyridinium cation (papy) and an uncoordinated water mol­ecule. The metal center lies on an inversion center and adopts an octa­hedral geometry with the carboxyl­ate groups tilted out of the mean plane formed by the btec. In the crystal, mol­ecules are linked into one-dimensional coordination polymers running along the ac diagonal. The crystal structure is consolidated by N—H⋯O and O—H⋯O hydrogen bonds

Thermodynamic Reverse Bounds for General Open Quantum Processes

Various quantum thermodynamic bounds are shown to stem from a single tighter and more general inequality, consequence of the operator concavity of the logarithmic function. Such an inequality, which we call the "thermodynamic reverse bound", is compactly expressed as a quantum relative entropy, from which it inherits mathematical properties and meaning. As concrete examples, we apply our bound to evaluate the thermodynamic length for open processes, the heat exchange in erasure processes, and the maximal energy outflow in general quantum evolutions.Comment: v2: added six colorful plots for the heat exchanged in erasure processes, accepted in PRA; v1: 6 pages, two-colum

NVC in non-rheumatic disease

Nailfold video-capillaroscopy (NVC) is a useful diagnostic tool, used to early detect abnormalities in micro-circulation, providing a qualitative description of microvascular anomalies in Raynaud’s phenomenon. NVC role in the diagnosis of Systemic Sclerosis is well known. In other rheumatic conditions such as connective tissue diseases, vasculitis, and arthritis, the NVC anomalies are often included in a scleroderma like pattern. The use of NVC in non-rheumatic diseases (NRD), with remarkable microvascular damage, as diabetes, is not standardized yet, although several research studies are carrying on. The aim of this article is to provide a resume of published results in order to lay the groundwork for the employment of NVC both in the diagnosis and follow up of microvascular complication in NRD. Furthermore, we mention NVC findings in pathologies without well recognize microvascular damages in their pathogenesis : micro-vessels abnormalities may suggest a different point of view

Adipokines and Chronic Rheumatic Diseases: from Inflammation to Bone Involvement

AbstractBesides its well-known role as energy storage tissue, adipose tissue is a biologically active tissue that can also be considered as an endocrine organ, as it is able to secrete adipokines. These bioactive factors, similar in structure to cytokines, are involved in several physiological and pathological conditions, such as glucose homeostasis, angiogenesis, blood pressure regulation, control of food intake, and also inflammation and bone homeostasis via endocrine, paracrine, and autocrine mechanisms. Given their pleiotropic functions, the role of adipokines has been evaluated in chronic rheumatic osteoarticular inflammatory diseases, particularly focusing on their effects on inflammatory and immune response and on bone alterations. Indeed, these diseases are characterized by different bone complications, such as local and systemic bone loss and new bone formation. The aim of this review is to summarize the role of adipokines in rheumatoid arthritis, ankylosing spondylitis, psoriatic arthritis, osteoarthritis, and osteoporosis, especially considering their role in the pathogenesis of bone complications typical of these conditions

Sonication of antibiotic-loaded cement spacers in a two-stage revision protocol for infected joint arthroplasty

Background. Culturing of the sonication fluid of removed implants has proven to be more sensitive than conventional periprosthetic tissue culture for the microbiological diagnosis of prosthetic joint infection. Since bacteria surviving on antibiotic-loaded cement spacers used in a two-stage exchange protocol for infected arthroplasties may cause the persistence of infection, in this study we asked whether the sonication also could be used to identify bacteria on antibiotic-loaded cement spacers removed at the second surgical stage during a two-stage exchange procedure to confirm whether or not the prosthetic joint infection had been eradicated. Methods. We cultured the sonication fluid of cement spacers that had been originally implanted in a two-stage exchange protocol in 21 patients (mean age, 66 years) affected by prosthetic joint infection (16 total knee prostheses and 5 hip prostheses). The cement spacers were vortexed for 30 seconds and then subjected to sonication (frequency 35–40 KHz). The resulting sonicate fluid was cultured for aerobic and anaerobic bacteria. Results. The sonication fluid culture of the removed spacer was positive in six patients (29%), with isolation of methicillin-sensible Staphylococcus Aureus (MSSA) in three cases, methicillin-resistant Staphylococcus Aureus (MRSA) in one case and Pseudomonas Aeruginosa in two cases. In three of these positive cases, the traditional culture of periprosthetic tissue was negative. Two patients with positive sonication culture of the spacer were successfully treated by early debridement of the revision prosthesis and systemic antibiotic therapy. In three patients a knee arthrodesis was planned and performed as the second surgical stage. In two of them the infection was caused by highly resistant Pseudomonas Aeruginosa. The other patient with a MSSA infection had been poorly compliant with the systemic antibiotic therapy due to her mental impairment. The patient originally affected by MRSA infection of his primary hip arthroplasty developed recurrent infection of his revision prosthesis and eventually underwent Girdlestone arthroplasty. Conclusions. The sonication culture can be used to discover any bacteria on the antibiotic-loaded cement spacer during a two-stage exchange protocol, thus permitting the adoption of timely treatment options, such as the early prosthetic debridment