Late-Variscan multistage hydrothermal processes unveiled by chemical ages coupled with compositional and textural uraninite variations in W-Au deposits in the western Spanish Central System Batholith

The scheelite skarn from Los Santos and the W-Au veins from El Cabaco district, located in the Spanish Central System Batholith (SCSB), are some of the best-known tungsten ore deposits in Spain. Uraninite is an accessory mineral in both deposits, which underwent several hydrothermal flow events. Chemical and textural characteristics, as well as electron microprobe U-Th-Pb uraninite chemical data from the different stages of the skarn and the vein-type mineralizations, are presented here. Based on these data the uraninite was able to be classified into two groups. Group I uraninite has an octahedral habit and occurs as inclusions in K-feldspar relicts of the leucogranite related to Los Santos skarn formation. It shows high Th (6.95 to 8.51wt.% ThO2) and high Rare Earth Elements (REEs) contents (0.55 to 1.38wt.% ∑REE2O3). Group II uraninite occurs i) associated to El Cabaco granite, in a greenish selvage-style greisen and its reddish envelope and in the mineralized rimming quartz veins and ii) in Los Santos high-temperature endoskarn and anorthite skarn, where it is associated with U-rich mica. This uraninite type has lower Th and ∑REE2O3contents than Group-I uraninite. The mineral chemistry and the assemblage and textural relationships suggest that Group-I uraninite is magmatic and the attained U-Th-Pb chemical age of 300±4Ma is interpreted as the magmatic age of the skarn-forming aplite granites in the western part of the SCSB. Group-II uraninite includes two events: i) hydrothermal uraninite, which yields an age of 295±2Ma, dates a strong alkali mobilization and early tungsten deposition and ii) a later hydrothermal process, around 287±4Ma, that resulted in sulfides and late scheelite precipitation and widespread silicification. Finally, the gold deposition is younger than this silicification according to textural criteria. Therefore, W-Au deposits in the western part of the SCSB were formed by superposition of several processes that took place some 15Ma after the skarn-forming granite crystallized. Comparable W, W-Au and U deposits in the Variscan orogenic belt show a similar timing of hydrothermal events, suggesting that the hydrothermal history was controlled by large-scale Late-Variscan tectonic processes

The electromagnetic counterpart of the binary neutron star merger LIGO/Virgo GW170817. I. Discovery of the optical counterpart using the Dark Energy Camera

We present the Dark Energy Camera (DECam) discovery of the optical counterpart of the first binary neutron star merger detected through gravitational wave emission, GW170817. Our observations commenced 10.5 hours post-merger, as soon as the localization region became accessible from Chile. We imaged 70 deg2 in the i and z bands, covering 93% of the initial integrated localization probability, to a depth necessary to identify likely optical counterparts (e.g., a kilonova). At 11.4 hours post-merger we detected a bright optical transient located 10:600 from the nucleus of NGC4993 at redshift z = 0:0098, consistent (for H0 = 70 km s-1 Mpc-1) with the distance of 40±8 Mpc reported by the LIGO Scientific Collaboration and the Virgo Collaboration (LVC). At detection the transient had magnitudes i=17.3 and z=17.4, and thus an absolute magnitude of Mi = -15.7, in the luminosity range expected for a kilonova. We identified 1,500 potential transient candidates. Applying simple selection criteria aimed at rejecting background events such as supernovae, we find the transient associated with NGC4993 as the only remaining plausible counterpart, and reject chance coincidence at the 99.5% confidence level. We therefore conclude that the optical counterpart we have identified near NGC4993 is associated with GW170817. This discovery ushers in the era of multi-messenger astronomy with gravitational waves, and demonstrates the power of DECam to identify the optical counterparts of gravitational-wave sources

Late Cretaceous ultramafic lamprophyres and carbonatites from the Delitzsch Complex, Germany

The Delitzsch Complex consists of late Cretaceous ultramafic lamprophyres and carbonatitic rocks. They form dikes and diatremes, emplaced into Palaeozoic to lower Permian volcanic and sedimentary rocks, and are covered by up to 120 m thick sequences of Tertiary sedimentary rocks. The complex includes a diversity of magmatic and subvolcanic rocks. The lithologies range from monchiquites and alkali picrites to dolomite– and calcite–carbonatites (rauhaugites, beforsites, and alvikites), and ultramafic lamprophyres (alnöites, aillikites). Contact relationships and the distribution of xenolithic material indicate that phases of carbonatitic and ultramafic lamprophyre magmatism overlapped. New U–Pb ages (72 ± 1 Ma on baddeleyite) from a dolomite–carbonatite (beforsite), Rb–Sr ages (73 ± 2 Ma on phlogopite) from an ultramafic lamprophyre (alnöite) in combination with modeling of the effect of the initial 87Sr/86Sr of phlogopite on the isochron ages of dolomite– and calcite–carbonatites demonstrate: (1) a short duration of magmatic activity for the main phases of the subvolcanic emplacement of the Delitzsch Complex; (2) phlogopite crystals in carbonatites of the Delitzsch Complex are xenocrysts; (3) the calculated initial 87Sr/86Sr composition of xenocrystic phlogopite equals the initial Sr composition of phlogopite from the alnöite

Alpine and pre-Alpine magmatism in the root-zone of the western Central Alps

The highest grade of metamorphism and associated structural elements in orogenic belts may be inherited from earlier orogenic events. We illustrate this point using magmatic and metamorphic rocks from the southern steep belt of the Lepontine Gneiss Dome (Central Alps). The U-Pb zircon ages from an anatectic granite at Verampio and migmatites at Corcapolo and Lavertezzo yield 280-290 Ma, i.e., Hercynian ages. These ages indicate that the highest grade of metamorphism in several crystalline nappes of the Lepontine Gneiss Dome is pre-Alpine. Alpine metamorphism reached sufficiently high grade to reset the Rb-Sr and K-Ar systematics of mica and amphibole, but generally did not result in crustal melting, except in the steep belt to the north of the Insubric Line, where numerous 29 to 26 Ma old pegmatites and aplites had intruded syn- and post-kinematically into gneisses of the ductile Simplon Shear Zone. The emplacement age of these pegmatites gives a minimum estimate for the age of the Alpine metamorphic peak in the Monte Rosa nappe. The U-Pb titanite ages of 33 to 31 Ma from felsic porphyritic veins represent a minimum-age estimate for Alpine metamorphism in the Sesia Zone. A porphyric vein emplaced at 448 +/- 5 Ma (U-Pb monazite) demonstrates that there existed a consolidated Caledonian basement in the Sesia Zone

Zircon and allanite U-Pb ID-TIMS ages of vaugnerites from the Calzadilla pluton, Salamanca (Spain): dating mantle-derived magmatism and post-magmatic subsolidus overprint.

Basic to intermediate high-K, high-Mg mantle-derived rocks occur throughout the Iberian Massif and are particularly important in the Tormes Dome, where vaugnerites form several stocks and small plutons. One of the largest and geochemically most variable among these plutons is the Calzadilla pluton in the Tormes Dome that crystallized at 318 ± 1.4Ma (Bashkirian; U-Pb TIMS zircon). This age reveals that the vaugnerite pluton was emplaced during the transition from late D2 extensional deformation to early D3 contractional deformation (319 to 317Ma). Large-scale extension in the area resulted, on one hand, in extensive anatexis in the crust due to quasiisothermal decompression and mica-dehydration melting and, on the other hand, in the upwelling of the mantle, which induced partial melting of the enriched domains in the lithospheric mantle. The driving reason why crustal and mantle melts were coeval is extension. The U-Pb ID-TIMS age of allanite is not related to the emplacement nor cooling of the Calzadilla vaugnerite, but it seems to be related to a younger subsolidus overprint ca. 275Ma that, in the scale of the Central Iberian Zone, corresponds to a period of hydrothermal alteration, including episyenite formation and tungsten mineralization