Rigid polyurethane foams from lignin based polyols

Rigid polyurethane (RPU) foams were synthesized using lignin-based polyols obtained by an oxypropylation process. Alcell, Indulin AT, Curan 27-11P and Sarkanda lignins have been oxypropylated using formulations deduced from an optimization study with Alcell. L/PO/C (ratio between lignin, PO and catalyst content) of 30/70/2 and 20/80/5 were used to obtain the desired polyols. The resulting RPU foams were characterized in terms of density, mechanical properties, conductivity and morphology. All Sarkanda lignin based polyols and the 30/70/2 Curan 27-11P polyol were found inadequate for RPU formulations. Alcell and Indulin AT based polyols and the 20/80/5 Curan 27-11P polyol resulted in RPU foams with properties very similar to those obtained from conventional commercial polyols. RPU foams produced with the 30/70/2 Alcell and the 30/70/2 Indulin AT polyols exhibited improved properties compared with those from 20/80/5 based formulations.Foundation for Science and Technology (grant SFRH/BD/18415/2004) and the French-Portuguese Scientific Cooperation Programme (action F-32/08

Lignin-based polyurethane materials

Four technical lignins (Alcell, Indulin AT, Sarkanda and Curan 27-11P) were used as macromonomers in the synthesis of polyurethane materials following two global approaches. In the first one Alcell and Indulin AT lignins were used directly as co-monomers in combination with a linear polycaprolactone (PCL) in order to produce polyurethane elastomers where lignin content varied between 10 and 25% (w/w) with respect to polyol mixture (PCL+lignin). The thermomechanical properties of the resulting materials were determined by dynamical mechanical analysis (DMA), differential scanning calorimetry (DSC) and swelling tests. In lignin-based elastomers Indulin AT showed to be more efficiently incorporated in the polyurethane network compared with Alcell lignin. Elastomers prepared with Indulin AT lignin exhibited a cross-linking density and storage modulus (rubbery plateau) higher than those of Alcell lignin-based counterpart and a lower soluble fraction. For both Alcell and Indulin AT based elastomers the glass transition temperature increased and extended over a wide temperature range with the increase of lignin content. The second approach consisted of producing rigid polyurethane foams (RPU) using ligninbased polyols obtained after chemical modification by an oxypropylation procedure. Two polyol formulations (20/80 and 30/70, in what concerns the weight ratios between lignin and propylene oxide, PO), were used in RPU formulations and their content varied from 0 to 100% (w/w with respect to a commercial polyol, used as a reference). The resulting RPU foams were characterized in terms of density, mechanical properties, conductivity and morphology. The prepared RPU foams with lignin-based polyols presented properties, very similar to those obtained from conventional commercial polyols. RPU foams prepared with 30/70 polyols exhibited improved properties comparatively to those arising from 20/80 formulations. Exceptions were however detected in RPU foams prepared with all Sarkanda lignin based polyols and Curan 27-11P 30/70 formulation, which were found to be inadequate for RPU formulation.Foundation for Science and Technology (grant SFRH/BD/18415/2004) and French-Portuguese Scientific Cooperation Programme (action F- 32/08)

Análises morfométricas entre apis mellifera da mesorregiao do sertao paraibano

Objetivou-se, com esse trabalho, caracterizar as populações de Apis mellifera da mesorregião do Sertão paraibano, comparando os indivíduos morfometricamente. As medidas tomadas foram: comprimento da asa anterior (CAA) e largura da asa anterior (LAA), ângulos B4, E9, G18, J16, K19, N23, O26 e distância b (Db); comprimento da asa posterior (CAP) e largura da asa posterior (LAP), distância L2 (DL2), L5 (DL5) e ângulo W3, comprimento do fêmur (CF), comprimento da tíbia (CT), comprimento do tarso (CTS) e largura do tarso (LTS) e comprimento da probóscide (CP). Para a comparação das diferentes variáveis estudadas utilizou-se a análise de variância, o teste de Tukey, análise canônica e o teste de Tocher a 5% de significância. Para as medidas realizadas em cada amostra utilizou-se um equipamento de análise de imagens, Programa Image Pro Plus 4.0. As variáveis CTS e LTS, ângulos G18 e K19 e DL2 diferiram significativamente (p<0,05) entre as localidades estudadas de acordo com o teste de Tukey. A análise canônica mostrou a existência de um agrupamento com base nas características morfológicas entre duas das localidades estudadas apesar da distância geográfica. Concluiu-se que existem dois grupos distintos morfometricamente para a microrregião estudada e que há um processo adaptativo das abelhas, quanto às medidas morfométricas, para as diferentes regiões geomorfológicas

Valorisation of kraft lignin by using vanillin and lignin-based polyurethanes: Use of the biorefinery concept

In kraft pulp mills, the capacity of the recovery boiler is very often a limiting factor to the increase of the pulp production. Until several decades ago, an upgrade to boiler system for dealing with higher quantities of black liquor was the only alternative. The possibility of lignin extraction from black liquor seems to be much more attractive, either for energy production or combustion elsewhere, or to serve as feedstock for chemicals production. Since the beginning of the 90’s, associate Laboratory LSRE/LCM has been focused on overcoming expansion limitations in pulp industries and, in this work, we show an alternative to this industry segment for the utilization of lignin and producing high added value chemicals from renewable biomass materials. Based on the biorefinery concepts, an integrated process for producing vanillin from kraft lignin oxidation has been proposed and each of the needed unit operations has been investigated to provide a deeper scientific understanding on this subject.FCT - projects POCTI/EQU/33198/99, POCI/EQU/61738/2004 and Grant SFRH/BD/18415/2004. CYTED IV.17/2002-2006. Luso-French actions F13/06 and F32/08

Evaluation of the almond shell oxypropylation process trough the surface response methodology

The efficiency of an oxypropylation process depends on several variables and operating conditions, which may not be generalized due to the diverse nature of subtracts. In lignocellulosic biomasses, the content of each fraction (lignin, cellulose and hemicellulose) can differ, as well as, the crystalline organization, which may limit reagent’s access to biomass. Also, the hydroxyl content can vary among biomasses; high values demand higher amounts of reactants, namely catalyst content, and more severe reaction conditions. Therefore, owing to biomass variability, selection of the operating conditions for oxypropylation their optimization is a key issue. In this context, one-factor-at-a-time approaches are commonly used to optimize processes; but it is well-known that optimal operating conditions or interactions between variables cannot be predicted by this simplistic method. Both problems may be overcome by employing the response surface methodology (RSM).info:eu-repo/semantics/publishedVersio

Biodegradation study of I lignin-based rigid polyrethane foams

Polyurethanes are considered as one of the most versatile polymeric materials offering a wide range of products with applications in diverse sectors. Rigid polyurethane (RPU) foams belong to this class of products and represent a commercially important class of expanded materials. In the present work RPU foams have been prepared from lignin-based polyols (LP) obtained by oxypropylation of two technical lignins (Alcell and Indulin AT) and biodegradability evaluated using respirometry tests in liquid and solid media. A RPU foam produced from a commercial polyether polyol (CP) based on sorbitol (Lupranol® 3323) was used as reference. Lignin biodegradation by P. chrysogenum, T. harzianum, T. reesei, T. versicolor and P. chrysosporium fungi was tested. Respirometry tests (in liquid and solid media) were performed and foam’s biodegradation evaluated based on the produced CO2.FCT (grant SFRH/BD/18415/2004) and the French-Portuguese Scientific Cooperation (actions F-13/06 and F-32/08)

The First Magnetic Fields

We review current ideas on the origin of galactic and extragalactic magnetic fields. We begin by summarizing observations of magnetic fields at cosmological redshifts and on cosmological scales. These observations translate into constraints on the strength and scale magnetic fields must have during the early stages of galaxy formation in order to seed the galactic dynamo. We examine mechanisms for the generation of magnetic fields that operate prior during inflation and during subsequent phase transitions such as electroweak symmetry breaking and the quark-hadron phase transition. The implications of strong primordial magnetic fields for the reionization epoch as well as the first generation of stars is discussed in detail. The exotic, early-Universe mechanisms are contrasted with astrophysical processes that generate fields after recombination. For example, a Biermann-type battery can operate in a proto-galaxy during the early stages of structure formation. Moreover, magnetic fields in either an early generation of stars or active galactic nuclei can be dispersed into the intergalactic medium.Comment: Accepted for publication in Space Science Reviews. Pdf can be also downloaded from http://canopus.cnu.ac.kr/ryu/cosmic-mag1.pd