6,543 research outputs found
A model for orientation effects in electronâtransfer reactions
A method for solving the singleâparticle Schrödinger equation with an oblate spheroidal potential of finite depth is presented. The wave functions are then used to calculate the matrix element T_BA which appears in theories of nonadiabatic electron transfer. The results illustrate the effects of mutual orientation and separation of the two centers on TBA. Trends in these results are discussed in terms of geometrical and nodal structure effects. Analytical expressions related to T_BA for states of spherical wells are presented and used to analyze the nodal structure effects for T_BA for the spheroidal wells
Celestial mechanics of elastic bodies
We construct time independent configurations of two gravitating elastic
bodies. These configurations either correspond to the two bodies moving in a
circular orbit around their center of mass or strictly static configurations.Comment: 16 pages, 2 figures, several typos removed, erratum appeared in
MathZ.263:233,200
Search for variations in circular-polarization spectra of the magnetic white dwarf LP790-29
We present highly time resolved circular-polarization and flux spectra of the
magnetic white dwarf LP790-29 taken with the VLT UT1 in order to test the
hypothesis that LP790-29 is a fast rotator with a period of the order of
seconds to minutes. Due to low time resolution of former observations this
might have been overlooked -- leading to the conclusion that LP790-29 has a
rotational period of over 100 years. The optical spectrum exhibits one
prominent absorption feature with minima at about 4500, 4950, and 5350 A, which
are most likely C2 Swan-bands shifted by about 180 A in a magnetic field
between 50MG and 200MG. At the position of the absorption structures the degree
of circular polarization varies between -1% and +1%, whereas it amounts to +8
to +10% in the blue and red continuum. With this very high degree of
polarization lp790-29 is very well suited to a search for short time
variations, since a variation of several percent in the polarization can be
expected for a magnetic field oblique to the rotational axis. From our analysis
we conclude that variations on time scales from 50 to 2500 seconds must have
amplitudes <0.7% in the continuum and <2% in the strongest absorption feature
at 4950A. While no short-term variations could be found a careful comparison of
our polarization data of LP790-29 with those in the literatures indicates
significant variations on time scales of decades with a possible period of
about 24-28 years.Comment: 5 pages, 4 figures. Astronomy and Astrophysics, in pres
Book Reviews
Book Reviews by Charles S. Desmond, Godfrey P. Schmidt, Robert E. Sullivan, Louis C. Kaplan, and Paul C. Bartholomew
Development and Evaluation of a Pragmatic Measure of Adherence to Dialectical Behavior Therapy: The DBT Adherence Checklist for Individual Therapy
This paper presents two studies conducted to develop and evaluate a new pragmatic measure of therapist adherence to Dialectical Behavior Therapy (DBT): the DBT Adherence Checklist for Individual Therapy (DBT AC-I). Study 1 used item response analysis to select items from the gold standard DBT Adherence Coding Scale (DBT ACS) using archival data from 1271 DBT sessions. Items were then iteratively refined based on feedback from 33 target end-users to ensure relevance, usability, and understandability. Study 2 examined the psychometric properties of the DBT AC-I as a therapist self-report and observer-rated measure in 100 sessions from 50 therapist-client dyads, while also evaluating predictors of therapist accuracy in self-rated adherence. When used as a therapist self-report measure, concordance between therapist and observer ratings was at least moderate (AC1â„0.41) for all DBT AC-I items but overall concordance (ICC=0.09) as well as convergent (r=0.05) and criterion validity (AUC=0.54) with the DBT ACS were poor. Higher therapist accuracy was predicted by greater DBT knowledge and adherence as well as more severe client suicidal ideation. When used by trained observers, the DBT AC-I had excellent interrater reliability (ICC=0.93), convergent validity (r=0.90), and criterion validity (AUC=0.94). While therapistsâ self-rated adherence on the DBT AC-I should not be assumed to reflect their actual adherence, some therapists may self-rate accurately. The DBT AC-I offers an effective and relatively efficient method of evaluating adherence to DBT when used by trained observers
Numerical computations of facetted pattern formation in snow crystal growth
Facetted growth of snow crystals leads to a rich diversity of forms, and
exhibits a remarkable sixfold symmetry. Snow crystal structures result from
diffusion limited crystal growth in the presence of anisotropic surface energy
and anisotropic attachment kinetics. It is by now well understood that the
morphological stability of ice crystals strongly depends on supersaturation,
crystal size and temperature. Until very recently it was very difficult to
perform numerical simulations of this highly anisotropic crystal growth. In
particular, obtaining facet growth in combination with dendritic branching is a
challenging task. We present numerical simulations of snow crystal growth in
two and three space dimensions using a new computational method recently
introduced by the authors. We present both qualitative and quantitative
computations. In particular, a linear relationship between tip velocity and
supersaturation is observed. The computations also suggest that surface energy
effects, although small, have a larger effect on crystal growth than previously
expected. We compute solid plates, solid prisms, hollow columns, needles,
dendrites, capped columns and scrolls on plates. Although all these forms
appear in nature, most of these forms are computed here for the first time in
numerical simulations for a continuum model.Comment: 12 pages, 28 figure
Spectroscopic Discovery of the Broad-Lined Type Ic Supernova 2010bh Associated with the Low-Redshift GRB 100316D
We present the spectroscopic discovery of a broad-lined Type Ic supernova (SN
2010bh) associated with the nearby long-duration gamma-ray burst (GRB) 100316D.
At z = 0.0593, this is the third-nearest GRB-SN. Nightly optical spectra
obtained with the Magellan telescopes during the first week after explosion
reveal the gradual emergence of very broad spectral features superposed on a
blue continuum. The supernova features are typical of broad-lined SNe Ic and
are generally consistent with previous supernovae associated with low-redshift
GRBs. However, the inferred velocities of SN 2010bh at 21 days after explosion
are a factor of ~2 times larger than those of the prototypical SN 1998bw at
similar epochs, with v ~ 26,000 km/s, indicating a larger explosion energy or a
different ejecta structure. A near-infrared spectrum taken 13.8 days after
explosion shows no strong evidence for He I at 1.083 microns, implying that the
progenitor was largely stripped of its helium envelope. The host galaxy is of
low luminosity (M_R ~ -18.5 mag) and low metallicity (Z < 0.4 Z_solar), similar
to the hosts of other low-redshift GRB-SNe.Comment: 6 pages, 4 figures, 1 table, submitted to ApJ Letter
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