A 10-M⊙M_{\odot} YSO with a Keplerian disk and a nonthermal radio jet

We previously observed the star-forming region G16.59$-$0.05 through interferometric observations of both thermal and maser lines, and identified a high-mass young stellar object (YSO) which is surrounded by an accretion disk and drives a nonthermal radio jet. We performed high-angular-resolution (beam FWHM ~0.15") 1.2-mm continuum and line observations towards G16.59$-$0.05 with the Atacama Large Millimeter Array (ALMA). The main dust clump, with size ~10$^4$ au, is resolved into four relatively compact (diameter ~2000 au) millimeter (mm) sources. The source harboring the high-mass YSO is the most prominent in molecular emission. By fitting the emission profiles of several unblended and optically thin transitions of CH$_3$OCH$_3$ and CH$_3$OH, we derived gas temperatures inside the mm-sources in the range 42--131 K, and calculated masses of 1--5 $M_{\odot}$. A well-defined Local Standard of Rest velocity (Vlsr) gradient is detected in most of the high-density molecular tracers at the position of the high-mass YSO, pinpointed by compact 22-GHz free-free emission. This gradient is oriented along a direction forming a large (~70 degree) angle with the radio jet, traced by elongated 13-GHz continuum emission. The butterfly-like shapes of the P-V plots and the linear pattern of the emission peaks of the molecular lines at high velocity confirm that this Vlsr gradient is due to rotation of the gas in the disk surrounding the high-mass YSO. The disk radius is ~500 au, and the Vlsr distribution along the major axis of the disk is well reproduced by a Keplerian profile around a central mass of 10$\pm$2 $M_{\odot}$. The position of the YSO is offset by >~ 0.1" from the axis of the radio jet and the dust emission peak. To explain this displacement we argue that the high-mass YSO could have moved from the center of the parental mm source owing to dynamical interaction with one or more companions.Comment: 16 pages, 12 figures, accepted by Astronomy & Astrophysics, Main Journa

La caccia al fosforo interstellare, l’elemento pre-biotico dimenticato

Il fosforo è un elemento cruciale per lo sviluppo della vita come la conosciamo, ma a causa della sua bassa abbondanza cosmica, fino a pochi anni fa la sua chimica interstellare era quasi del tutto sconosciuta. Dal 2016, il gruppo di Formazione Stellare di Arcetri ha contribuito in modo fondamentale alla comprensione di alcuni processi astrochimici che coinvolgono questo elemento in regioni della Galassia in cui si formano nuove stelle, aprendo la strada a un numero crescente di studi su questo elemento pre-biotico finora “dimenticato”.Phosphorus is a crucial element for the development of life as we know it, but because of its low cosmic abundance, until recently its interstellar chemistry was almost totally unknown. Since 2016, the star formation group at Arcetri has made a fundamental contribution to our understanding of the astrochemical processes that involve this element in the star-forming regions of the Galaxy, paving the way for a growing number of studies on this pre-biotic element that had been “forgotten” up to now

A sequential acid-base (SAB) mechanism in the interstellar medium: The emergence of cis formic acid in dark molecular clouds

The abundance ratios between isomers of a COM observed in the ISM provides valuable information about the chemistry and physics of the gas and eventually, the history of molecular clouds. In this context, the origin of an abundance of c-HCOOH acid of only 6% the isomer c-HCOOH abundance in cold cores, remains unknown. Herein, we explain the presence of c-HCOOH in dark molecular clouds through the destruction and back formation of c-HCOOH and t-HCOOH in a cyclic process that involves HCOOH and highly abundant molecules such as HCO+ and NH3. We use high-level ab initio methods to compute the potential energy profiles for the cyclic destruction/formation routes of c-HCOOH and t-HCOOH. Global rate constants and branching ratios were calculated based on the transition state theory and the master equation formalism under the typical conditions of the ISM. The destruction of HCOOH by reaction with HCO+ in the gas phase leads to three isomers of the cation HC(OH)2+. The most abundant cation can react in a second step with other abundant molecules of the ISM like NH3 to form back c-HCOOH and t-HCOOH. This mechanism explains the formation of c-HCOOH in dark molecular clouds. Considering this mechanism, the fraction of c-HCOOH with respect t-HCOOH is 25.7%. To explain the 6% reported by the observations we propose that further destruction mechanisms of the cations of HCOOH should be taken into account. The sequential acid-base (SAB) mechanism proposed in this work involves fast processes with very abundant molecules in the ISM. Thus, HCOOH very likely suffers our proposed transformations in the conditions of dark molecular clouds. This is a new approach in the framework of the isomerism of organic molecules in the ISM which has the potential to try to explain the ratio between isomers of organic molecules detected in the ISM

Precursors of fatty alcohols in the ISM: Discovery of n-propanol

Theories on the origins of life propose that early cell membranes were synthesized from amphiphilic molecules simpler than phospholipids such as fatty alcohols. The discovery in the interstellar medium (ISM) of ethanolamine, the simplest phospholipid head group, raises the question whether simple amphiphilic molecules are also synthesized in space. We investigate whether precursors of fatty alcohols are present in the ISM. For this, we have carried out a spectral survey at 7, 3, 2 and 1 mm toward the Giant Molecular Cloud G+0.693-0.027 located in the Galactic Center using the IRAM 30m and Yebes 40m telescopes. Here, we report the detection in the ISM of the primary alcohol n-propanol (in both conformers Ga-n-C3H7OH and Aa-n-C3H7OH), a precursor of fatty alcohols. The derived column densities of n-propanol are (5.5+-0.4)x10^13 cm^-2 for the Ga conformer and (3.4+-0.3)x10^13 cm^-2 for the Aa conformer, which imply molecular abundances of (4.1+-0.3)x10^-10 for Ga-n-C3H7OH and of (2.5+-0.2)x10^-10 for Aa-n-C3H7OH. We also searched for the AGa conformer of n-butanol (AGa-n-C4H9OH) without success yielding an upper limit to its abundance of <4.1x10^-11. The inferred CH3OH:C2H5OH:C3H7OH:C4H9OH abundance ratios go as 1:0.04:0.006:<0.0004 toward G+0.693-0.027, i.e. they decrease roughly by one order of magnitude for increasing complexity. We also report the detection of both syn and anti conformers of vinyl alcohol, with column densities of (1.11+-0.08)x10^14 cm^-2 and (1.3+-0.4)x10^13 cm^-2, and abundances of (8.2+-0.6)x10^-10 and (9.6+-3.0)x10^-11, respectively. The detection of n-propanol, together with the recent discovery of ethanolamine in the ISM, opens the possibility that precursors of lipids according to theories of the origin of life, could have been brought to Earth from outer space.Comment: 15 pages, 10 figures, accepted for A&

Extreme radio flares and associated X-ray variability from young stellar objects in the Orion Nebula Cluster

Jan Forbrich, et al, ‘Extreme Radio Flares and Associated XRay Variability from Young Stellar Objects in the Orion Nebula Cluster’, The Astrophysical Journal, Vol. 844 (2), July 2017. DOI: https://doi.org/10.3847/1538-4357/aa7aa4. © 2017 The American Astronomical Society. All Rights Reserved.Young stellar objects are known to exhibit strong radio variability on timescales of weeks to months, and a few reports have documented extreme radio flares with at least an order of magnitude change in flux density on timescales of hours to days. However, there have been few constraints on the occurrence rate of such radio flares or on the correlation with pre-main sequence X-ray flares, although such correlations are known for the Sun and nearby active stars. Here we report simultaneous deep VLA radio and Chandra X-ray observations of the Orion Nebula Cluster, targeting hundreds of sources to look for the occurrence rate of extreme radio variability and potential correlation with the most extreme X-ray variability. We identify 13 radio sources with extreme radio variability, with some showing an order of magnitude change in flux density in less than 30 minutes. All of these sources show X-ray emission and variability, but we find clear correlations with extreme radio flaring only on timescales <1 hr. Strong X-ray variability does not predict the extreme radio sources and vice versa. Radio flares thus provide us with a new perspective on high-energy processes in YSOs and the irradiation of their protoplanetary disks. Finally, our results highlight implications for interferometric imaging of sources violating the constant-sky assumption.Peer reviewedFinal Published versio

The GUAPOS project – V: The chemical ingredients of a massive stellar protocluster in the making

Most stars, including the Sun, are born in rich stellar clusters containing massive stars. Therefore, the study of the chemical reservoir of massive star-forming regions is crucial to understand the basic chemical ingredients available at the dawn of planetary systems. We present a detailed study of the molecular inventory of the hot molecular core G31.41+0.31 from the project GUAPOS (G31.41+0.31 Unbiased ALMA sPectral Observational Survey). We analyse 34 species for the first time plus 20 species analysed in previous GUAPOS works, including oxygen, nitrogen, sulfur, phosphorus, and chlorine species. We compare the abundances derived in G31.41+0.31 with those observed in other chemically-rich sources that represent the initial and last stages of the formation of stars and planets: the hot corino in the Solar-like protostar IRAS 16293-2422 B, and the comets 67P/Churyumov-Gerasimenko and 46P/Wirtanen. The comparative analysis reveals that the chemical feedstock of the two star-forming regions are similar. The abundances of oxygen- and nitrogen-bearing molecules exhibit a good correlation for all pair of sources, including the two comets, suggesting a chemical heritage of these species during the process of star formation, and hence an early phase formation of the molecules. However, sulfur- and phosphorus-bearing species present worse correlations, being more abundant in comets. This suggests that while sulfur- and phosphorus-bearing species are pre-dominantly trapped on the surface of icy grains in the hot close surroundings of protostars, they could be more easily released into gas phase in comets, allowing their cosmic abundances to be almost recovered.ALG and VMR have received support from the Comunidad de Madrid through the Atracción de Talento Investigador Modalidad 1 (Doctores con experiencia) Grant (COOL: Cosmic Origins Of Life; 2019-T1/TIC-5379), the project RYC2020-029387-I funded by MICIU/AEI/10.13039/501100011033 and by ‘ESF, Investing in your future’, from the the Consejo Superior de Investigaciones Científicas (CSIC) and the Centro de Astrobiología (CAB) through the project 20225AT015 (Proyectos intramurales especiales del CSIC), and from the Spanish Ministry of Science through the project PID2022-136814NB-I00. LC and IJS acknowledge financial support through the Spanish grants PID2019-105552RB-C41 and PID2022-136814NB-I00 from the Spanish Ministry of Science and Innovation/State Agency of Research MICIU/AEI/10.13039/501100011033 and by ‘ERDF A way of making Europe’. CM acknowledges funding from the European Research Council (ERC) under the European Union’s Horizon 2020 program through the ECOGAL Synergy grant (ID 855130). ASM acknowledges support from the RyC2021-032892-I and PID2020-117710GB-I00 grants funded by MICIU/AEI/10.13039/501100011033 and by the European Union ‘Next GenerationEU’/PRTR, as well as the program Unidad de Excelencia María de Maeztu CEX2020-001058-M. SV acknowledges support from the European Research Council (ERC) grant MOPPEX ERC-833460.With funding from the Spanish government through the "Severo Ochoa Centre of Excellence" accreditation (CEX2020-001058-M).Peer reviewe

Volume density structure of the central molecular zone NGC 253 through ALCHEMI excitation analysis

We present a spatially resolved excitation analysis for the central molecular zone (CMZ) of the starburst galaxy NGC 253 using the data from the Atacama Large Millimeter/submillimeter Array Comprehensive High-resolution Extragalactic Molecular Inventory, whereby we explore parameters distinguishing NGC 253 from the quiescent Milky Way’s Galactic center (GC). Non-LTE analyses employing a hierarchical Bayesian framework are applied to Band 3–7 transitions from nine molecular species to delineate the position–position–velocity distributions of column density (NH2), volume density (nH2), and temperature (Tkin) at 27 pc resolution. Two distinct components are detected: a low-density component with ( ) ( ~ ) - n T H kin , 10 cm , 85 K 3.3 3 2 and a high-density component with ( )( ) ~ - n T H kin , 10 cm , 110 K 4.4 3 2 , separated at ~ - nH 10 cm 3.8 3 2 . NGC 253 has ∼10 times the high-density gas mass and ∼3 times the dense-gas mass fraction of the GC. These properties are consistent with their HCN/CO ratio but cannot alone explain the factor of ∼30 difference in their star formation efficiencies (SFEs), contradicting the dense-gas mass to star formation rate scaling law. The nH2 histogram toward NGC 253 exhibits a shallow declining slope up to ~ - nH 10 cm 6 3 2 , while that of the GC steeply drops in - nH2 10 cm 4.5 3 and vanishes at 105 cm−3. Their dense-gas mass fraction ratio becomes consistent with their SFEs when the threshold nH2 for the dense gas is taken at ∼104.2−4.6 cm−3. The rich abundance of gas above this density range in the NGC 253 CMZ, or its scarcity in the GC, is likely to be the critical difference characterizing the contrasting star formation in the centers of the two galaxies.K.T. was supported by the ALMA Japan Research Grant of NAOJ ALMA Project, NAOJ-ALMA-300. S.V., M.B., K.-Y.H., and J.B. acknowledge support from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program MOPPEX 833460. K.S. acknowledges the support from the Ministry of Science and Technology (MOST) of Taiwan through the grant MOST 111-2112-M-001-039. V.M.R. has received support from the project RYC2020-029387-I funded by MCIN/AEI /10.13039/501100011033. H.K. and T.T. were supported by JSPS KAKENHI grant No. 20H00172 and the NAOJ ALMA Scientific Research grant No. 2020-15A. L.C. acknowledges financial support through the Spanish grant PID2019-105552RB-C41 funded by MCIN/AEI/10.13039/501100011033.Peer reviewe