Measurement of tropospheric carbonyl sulfide by microwave spectrometry

Microwave rotational spectrometry is used to measure tropospheric carbonyl sulfide. The instrument and techniques for using it are described

Establishing Guidelines For Using Readers Theater With Less-Skilled Readers

The author reviews recent research findings concerning the benefits of readers theater for building oral reading accuracy and fluency and then identifies key guidelines for instructional implementation. Recommendations and conclusions place the focus on guidelines for classroom teachers who might want to experiment with readers theater as they work with children who face reading difficulties

Locomotion grows up: The neuromechanical control of interlimb coordinating mechanisms in crayfish

Locomotion requires many dynamic interactions between organism and environment at several levels. It is not known how the nervous system controls all of these relationships to ultimately produce and guide locomotor behavior. Furthermore, it is not known whether the nervous system needs to recognize and control all of the possible body-environment interactions. In this study the crayfish (Procambarus clarkii) is used as a model system to test how size influences locomotor behavior and how a single, simplified neuromechanical system can accommodate these changes.;A set of behavioral experiments was conducted to characterize kinematics of freely walking juvenile crayfish to compare with adults. The purpose of these studies was to determine how crayfish adapt to a great change in size during their ontogeny. Juvenile and adult crayfish show differences in limb function and coordination. Although crayfish are decapods, the juveniles predominantly use the posterior legs and behave more like four-legged walkers. The difference in locomotor behavior can best be explained by differences in chelae size. Allometric relationships between juveniles and adults show limb and body morphologies scale proportionately. Adult chelae, or claws, are twice as long and contribute ∼20% more to the total body mass in fully mature crayfish. This increase in chelae size shifts the location of the center of mass anterior as crayfish grow. The result is a change in relative load distribution that appears to affect individual limb behavior and interlimb coordination. Shifting the center of mass in adults by amputating the chelae resulted in limb behavior and interlimb coordination more similar to that observed in juveniles. Likewise, applying load to the rostrum of juveniles altered behavior and changed limb function in the posterior legs similar to adults with large chelae. The results of these experiments suggest that crayfish of all sizes adapt to changes in load distribution by adjusting behavior of individual legs.;To test whether developmental influences have an effect on walking behavior, juveniles were induced to walk on a treadmill at various speeds. The animals showed more consistent limb coordination as walking speed increased, similar to adults. Selected legs were then amputated to test how gait was affected. Amputating legs removes sensory feedback from the distal leg to the central nervous system. The behavior of the stump is therefore more representative of the endogenous rhythmicity of the central pattern generator (CPG). Juveniles showed no differences in coordination in individual legs. Coordination between adjacent ipsilateral legs was also the same as that observed in adults following amputation. Furthermore, intact legs acquired new interlimb coordination similar to adults. These results suggested that juvenile and adult crayfish have functionally similar nervous systems controlling walking.;Finally, a 3-D virtual crayfish was built to test whether differences in walking between juveniles and adults could be due to mechanical influences alone. The model crayfish lacked direct connections between legs. The model responded to shifts in the center of mass by showing more consistent limb coordination in those legs nearest the center of mass. This was achieved through indirect mechanical coupling of the legs through the environment and body of the crayfish. This mechanism also produced realistic adaptive behavior when limbs were amputated. This showed that differences between adult and juvenile walking are due solely to mechanical influences associated with the changing center of mass as the animals grow. These results suggest further that organisms do not need high levels of control to produce coordinated behavior. Locomotor behavior arises through interactions between body, limb, and environment that are a function of the spatio-temporal dynamics of body morphology. The results may be applicable to a large number of walking systems

Engineering Functional Quantum Algorithms

Suppose that a quantum circuit with K elementary gates is known for a unitary matrix U, and assume that U^m is a scalar matrix for some positive integer m. We show that a function of U can be realized on a quantum computer with at most O(mK+m^2log m) elementary gates. The functions of U are realized by a generic quantum circuit, which has a particularly simple structure. Among other results, we obtain efficient circuits for the fractional Fourier transform.Comment: 4 pages, 2 figure

Cyclical tests of selected space shuttle TPS metallic materials in a plasma arc tunnel Volume 1: Description of tests and program summary

Work, concerned with cyclical thermal evaluation of selected space shuttle thermal protection system (TPS) metallic materials in a hypervelocity oxidizing atmosphere that approximated an actual entry environment, is presented. A total of 325 sample test hours were conducted on 21 super-alloy metallic samples at temperatures from 1800 to 2200 F (1256 to 1478 K) without any failures. The 4 x 4 in. (10.2 x 10.2 cm) samples were fabricated from five nickel base alloys and one cobalt base alloy. Eighteen of the samples were cycled 100 times each and the other three samples 50 times each in a test stream emanating from an 8 in. (20.3 cm) diam exit, Mach 4.6, conical nozzle. The test cycle consisted of a 10 min heat pulse to a controlled temperature followed by a 10 min cooldown period. The TD-NiCrAl and TD-NiAlY materials showed the least change in weight, thickness, and physical appearance even though they were subjected to the highest temperature environment

Cyclical Tests of Selected Space Shuttle TPS Metallic Materials in a Plasma Arc Tunnel. Volume 2: Appendices - Data Tabulation

Calibration data are presented for heat flux and pressure profiles, model temperature histories, and model weight and thickness changes

Can You Tell a Book by its Cover?

Book fairs are great fun, and they offer students a chance to explore a world of books in a more exciting atmosphere than the school library. Today, many schools have self-selection programs and activities to suit the wide range of student reading abilities and interests. Multilevel materials are used, and students are encouraged to read as much as they can. Teacher advice and guidance is usually available as the need arises. Consequently, numerous schools have book fairs to stimulate reading through self-selection, and equally important, educators hope to promote reading interest and future reading growth. Accordingly, books for the fairs are usually carefully selected by librarians, reading and English teachers on the basis of adolescent interests and tastes

Coordination chemistry in molecular symmetry adapted spin space (mSASS)

Many areas of chemistry are devoted to the challenge of understanding, predicting, and controlling the behavior of strongly localized electrons. Examples include molecular magnetism and luminescence, color centers in crystals, photochemistry and quantum sensing to name but a few. Over the years, an amalgam of powerful quantum chemistry methods, simple intuitive models, and phenomenological parameterizations have been developed, providing increasingly complex and specialized methodologies. Even with increasing specialization, a pervasive challenge remains that is surprisingly universal - the simultaneous description of continuous symmetries (e.g. spin and orbital angular momenta) and discrete symmetries (e.g. crystal field). Modeling behavior in these complex systems is increasingly important for metal ions of unusual or technologically relevant behavior. Additionally, development of broad-scope models with physically-meaningful parameters carries the potential to facilitate interdisciplinary collaboration and large-scale meta analysis. We propose a generalized algorithmic approach, the molecular symmetry adapted spin space (mSASS), to localized electronic structure. We derive the Hamiltonian in symmetry-constrained matrix form with an exact account of free parameters and examples. Although preliminary in its implementation, a fundamental benefit of this approach is the treatment of spatial and spin-orbit symmetries without the need for perturbative approximations. In general, the mSASS Hamiltonian is large but finite and can be diagonalized numerically with high efficiency, providing a basis for conceptual models of electronic structure that naturally incorporates spin while leveraging the intuition and efficiency benefits of crystallographic symmetry. For the generation of the mSASS Hamiltonian, we provide an implementation into the Mathematica Software Package, GTPack.Comment: 10 pages, 4 figure