Periodic Orbits and Spectral Statistics of Pseudointegrable Billiards

We demonstrate for a generic pseudointegrable billiard that the number of periodic orbit families with length less than $l$ increases as $\pi b_0l^2/\langle a(l) \rangle$, where $b_0$ is a constant and $\langle a(l) \rangle$ is the average area occupied by these families. We also find that $\langle a(l) \rangle$ increases with $l$ before saturating. Finally, we show that periodic orbits provide a good estimate of spectral correlations in the corresponding quantum spectrum and thus conclude that diffraction effects are not as significant in such studies.Comment: 13 pages in RevTex including 5 figure

Semiclassical Inequivalence of Polygonalized Billiards

Polygonalization of any smooth billiard boundary can be carried out in several ways. We show here that the semiclassical description depends on the polygonalization process and the results can be inequivalent. We also establish that generalized tangent-polygons are closest to the corresponding smooth billiard and for de Broglie wavelengths larger than the average length of the edges, the two are semiclassically equivalent.Comment: revtex, 4 ps figure

Periodic Orbits in Polygonal Billiards

We review some properties of periodic orbit families in polygonal billiards and discuss in particular a sum rule that they obey. In addition, we provide algorithms to determine periodic orbit families and present numerical results that shed new light on the proliferation law and its variation with the genus of the invariant surface. Finally, we deal with correlations in the length spectrum and find that long orbits display Poisson fluctuations.Comment: 30 pages (Latex) including 11 figure

Scale Anomaly and Quantum Chaos in the Billiards with Pointlike Scatterers

We argue that the random-matrix like energy spectra found in pseudointegrable billiards with pointlike scatterers are related to the quantum violation of scale invariance of classical analogue system. It is shown that the behavior of the running coupling constant explains the key characteristics of the level statistics of pseudointegrable billiards.Comment: 10 pages, RevTex file, uuencode

Level statistics and eigenfunctions of pseudointegrable systems: dependence on energy and genus number

We study the level statistics (second half moment $I_0$ and rigidity $\Delta_3$) and the eigenfunctions of pseudointegrable systems with rough boundaries of different genus numbers $g$. We find that the levels form energy intervals with a characteristic behavior of the level statistics and the eigenfunctions in each interval. At low enough energies, the boundary roughness is not resolved and accordingly, the eigenfunctions are quite regular functions and the level statistics shows Poisson-like behavior. At higher energies, the level statistics of most systems moves from Poisson-like towards Wigner-like behavior with increasing $g$. Investigating the wavefunctions, we find many chaotic functions that can be described as a random superposition of regular wavefunctions. The amplitude distribution $P(\psi)$ of these chaotic functions was found to be Gaussian with the typical value of the localization volume $V_{\rm{loc}}\approx 0.33$. For systems with periodic boundaries we find several additional energy regimes, where $I_0$ is relatively close to the Poisson-limit. In these regimes, the eigenfunctions are either regular or localized functions, where $P(\psi)$ is close to the distribution of a sine or cosine function in the first case and strongly peaked in the second case. Also an interesting intermediate case between chaotic and localized eigenfunctions appears

Level spacing distribution of pseudointegrable billiard

In this paper, we examine the level spacing distribution $P(S)$ of the rectangular billiard with a single point-like scatterer, which is known as pseudointegrable. It is shown that the observed $P(S)$ is a new type, which is quite different from the previous conclusion. Even in the strong coupling limit, the Poisson-like behavior rather than Wigner-like is seen for $S>1$, although the level repulsion still remains in the small $S$ region. The difference from the previous works is analyzed in detail.Comment: 11 pages, REVTeX file, 3 PostScript Figure

Kinetic detection of osmium(VI) ester intermediates during the OsO4‐mediated aqueous dihydroxylation of chloroethylenes

The kinetics and mechanism of the cis dihydroxylation of cis‐1,2‐ dichloroethylene, trans‐1,2‐dichloroethylene, and trichloroethylene by osmium tetroxide was studied systematically in aqueous solution. The stoichiometry of the process was determined based on the principle of continuous variation of reactant ratios with spectrophotometric detection. The results always showed 1:1 stoichiometry, which is in agreement with dihydroxylation. All three reactions were found to proceed in two distinct steps. The first step occurred on a time scale of seconds and was associated with a minor change in absorbance and was identified as the formation of a 1:1 adduct between the two reagents, which is the osmium(VI) ester that plays a decisive role in catalytic applications. This species is formed in an equilibrium that is very much shifted toward the reactants, so the osmium(VI) complex is a short‐lived intermediate of the process, which is detected kinetically, but its concentration is never high enough for structural characterization. The second reaction is accompanied by major spectral changes; it involves the formation of the final products. Our results clearly show that it is possible to detect the intermediate of the process by careful kinetic studies. It is also possible that the same strategy might be successful in other OsO4‐dependent dihydroxylation processes

Distribution of Husimi Zeroes in Polygonal Billiards

The zeroes of the Husimi function provide a minimal description of individual quantum eigenstates and their distribution is of considerable interest. We provide here a numerical study for pseudo- integrable billiards which suggests that the zeroes tend to diffuse over phase space in a manner reminiscent of chaotic systems but nevertheless contain a subtle signature of pseudo-integrability. We also find that the zeroes depend sensitively on the position and momentum uncertainties with the classical correspondence best when the position and momentum uncertainties are equal. Finally, short range correlations seem to be well described by the Ginibre ensemble of complex matrices.Comment: includes 13 ps figures; Phys. Rev. E (in press

Complex Periodic Orbits and Tunnelling in Chaotic Potentials

We derive a trace formula for the splitting-weighted density of states suitable for chaotic potentials with isolated symmetric wells. This formula is based on complex orbits which tunnel through classically forbidden barriers. The theory is applicable whenever the tunnelling is dominated by isolated orbits, a situation which applies to chaotic systems but also to certain near-integrable ones. It is used to analyse a specific two-dimensional potential with chaotic dynamics. Mean behaviour of the splittings is predicted by an orbit with imaginary action. Oscillations around this mean are obtained from a collection of related orbits whose actions have nonzero real part

Evanescent wave approach to diffractive phenomena in convex billiards with corners

What we are going to call in this paper "diffractive phenomena" in billiards is far from being deeply understood. These are sorts of singularities that, for example, some kind of corners introduce in the energy eigenfunctions. In this paper we use the well-known scaling quantization procedure to study them. We show how the scaling method can be applied to convex billiards with corners, taking into account the strong diffraction at them and the techniques needed to solve their Helmholtz equation. As an example we study a classically pseudointegrable billiard, the truncated triangle. Then we focus our attention on the spectral behavior. A numerical study of the statistical properties of high-lying energy levels is carried out. It is found that all computed statistical quantities are roughly described by the so-called semi-Poisson statistics, but it is not clear whether the semi-Poisson statistics is the correct one in the semiclassical limit.Comment: 7 pages, 8 figure