Asymptotic solution of a model for bilayer organic diodes and solar cells

The current voltage characteristics of an organic semiconductor diode made by placing together two materials with dissimilar electron affinities and ionisation potentials is analysed using asymptotic methods. An intricate boundary layer structure is examined. We find that there are three regimes for the total current passing through the diode. For reverse bias and moderate forward bias the dependency of the voltage on the current is similar to the behaviour of conventional inorganic semiconductor diodes predicted by the Shockley equation and are governed by recombination at the interface of the materials. There is then a narrow range of currents where the behaviour undergoes a transition. Finally for large forward bias the behaviour is different with the current being linear in voltage and is primarily controlled by drift of charges in the organic layers. The size of the interfacial recombination rate is critical in determining the small range of current where there is rapid transition between the two main regimes. The extension of the theory to organic solar cells is discussed and the analogous current voltage curves derived in the regime of interest

The effect of feedback and information on children's pedometer step counts at school

This study examined whether feedback or feedback plus physical activity information could increase the number of pedometer steps taken during 1 school week. One hundred seventy-seven students (mean age 9.124 ± 1.11 years) in three elementary schools participated. Schools were randomly assigned to control (CON), feedback (FB), or feedback plus information (FB+I) groups. Children wore pedometers during school time for 5 consecutive weekdays. The total steps of the groups were recorded at the end of each school day, with students in the FB and FB+I groups free to view their step counts. In addition, the FB+I group received information and ideas about how they could increase their daily steps. The CON group received no step-count feedback or information. Students in the FB+I group achieved significantly more steps per minute (17.17 ± 4.87) than those in the FB (13.77 ± 4.06, p = 0.003) and CON (12.41 ± 3.12, p = 0.0001) groups. Information, as well as step-count feedback, increased elementary students’ school-based physical activity (number of steps) in the short term. A longer intervention period is necessary to assess the sustained impact of this type of approach

Micro-mechanical analysis of damage growth and fracture in discontinuous fiber reinforced metal matrix composites

The near-crack-tip stresses in any planar coupon of arbitrary geometry subjected to mode 1 loading may be equated to those in an infinite center-cracked panel subjected to the appropriate equivalent remote biaxial stresses (ERBS). Since this process can be done for all such mode 1 coupons, attention may be focused on the behavior of the equivalent infinite cracked panel. To calculate the ERBS, the constant term in the series expansion of the crack-tip stress must be retained. It is proposed that the ERBS may be used quantitatively to explain different fracture phenomena such as crack branching

Interplanetary Trajectory Optimization with Powerlimited Propulsion Systems

A trajectory-optimization process is described in which the optimum thrust equations are derived using the calculus of variations. The magnitude of the thrust is constrained within an upper and a lower bound, but the thrust direction is arbitrary. This formulation allows both the constant-thrust program and the variable-thrust program to be considered. For the constant-thrust program, certain propulsion-system parameters are optimized for maximum final vehicle mass. This theory has been used to study interplanetary missions to Venus and Mars using a power-limited propulsion system. Both one-way and round trip rendezvous trajectories are considered. The analysis employs a two-body inverse-square force-field model of three dimensions. An iterative routine used to solve the two-point boundary-value problem is described in the Appendix

A fast and robust numerical scheme for solving models of charge carrier transport and ion vacancy motion in perovskite solar cells

Drift-diffusion models that account for the motion of both electronic and ionic charges are important tools for explaining the hysteretic behaviour and guiding the development of metal halide perovskite solar cells. Furnishing numerical solutions to such models for realistic operating conditions is challenging owing to the extreme values of some of the parameters. In particular, those characterising (i) the short Debye lengths (giving rise to rapid changes in the solutions across narrow layers), (ii) the relatively large potential differences across devices and (iii) the disparity in timescales between the motion of the electronic and ionic species give rise to significant stiffness. We present a finite difference scheme with an adaptive time step that is posed on a non-uniform staggered grid that provides second order accuracy in the mesh spacing. The method is able to cope with the stiffness of the system for realistic parameters values whilst providing high accuracy and maintaining modest computational costs. For example, a transient sweep of a current-voltage curve can be computed in only a few minutes on a standard desktop computer.Comment: 22 pages, 8 figure

Commercial air transport hazard warning and avoidance system. Volume 1 - Summary Final report

Operational requirements for commercial air transport hazard warning and avoidance syste

Financial Conditions on U.S. Cotton Farms

For the last three years, U.S. cotton producers have been heavily dependent on ad hoc emergency disaster and market loss assistance to cash flow their operations. They have not been alone. Wheat, feed grains, oilseeds and rice producers have also been faced with low commodity prices, adverse weather and the need for substantial government assistance. Price support and direct payments by CCC for fiscal years 1998-2000 averaged $17.5 billion per year (USDA Ag Outlook). Has U.S. program crop agriculture turned the corner or will additional government payments likely be needed to sustain a vulnerable sector? This paper will focus on the outlook for the Agricultural and Food Policy Center’s (AFPC’s) representative cotton farms over the period 2001-2005. The results reported herein are drawn from AFPC Working Paper 00-4 which goes into greater depth on all 82 representative farms and ranches modeled by AFPC.Agribusiness, Agricultural and Food Policy, Crop Production/Industries,

Greenhouse Gas Regulation under the Clean Air Act: A Guide for Economists

Until recently, most attention to U.S. climate policy has focused on legislative efforts to introduce a price on carbon through cap and trade. In the absence of such legislation, the Clean Air Act is a potentially potent alternative. Decisions regarding existing stationary sources will have the greatest effect on emissions reductions. The magnitude is uncertain, but plausibly 10 percent reductions in greenhouse gas emissions from 2005 levels could be achieved at moderate costs by 2020. This is comparable to the reductions that would have been achieved under the Waxman-Markey legislation in the domestic economy. These measures do not include the switching of fuels, which could yield further reductions. The ultimate cost of regulation under the act hinges on the stringency of standards and the flexibility allowed. A broad-based tradable performance standard is legally plausible and would provide incentives comparable to the proposed legislation, at least in the near term.climate policy, efficiency, EPA, Clean Air Act, NAAQS, coal

Tradable Standards for Clean Air Act Carbon Policy

EPA is in the process of regulating U.S. greenhouse gas (GHG) emissions using its powers under the Clean Air Act. The likely next phase of this regulatory program is performance standards under Section 111 of the act for coal plants and petroleum refineries, which the agency has committed to finalize by the end of 2012. Section 111 appears to allow use of flexible, market-based regulatory tools. In this paper, we discuss one such tool, tradable standards. Tradable standards appear to be a legally and politically viable choice for the agency, and evidence suggests they are substantially more cost-effective than traditional performance standards. The paper discusses implementation issues with tradable standards, including categorization, banking, and phased implementation, as well as broader issues with the Section 111 rulemaking process as it relates to state-level GHG regulatory efforts.averaging, flexibility, regulatory design, market-based regulation