Observations of water mass transformation and eddies in the Lofoten basin of the Nordic Seas

Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 1735–1756, doi:10.1175/JPO-D-14-0238.1.The Lofoten basin of the Nordic Seas is recognized as a crucial component of the meridional overturning circulation in the North Atlantic because of the large horizontal extent of Atlantic Water and winter surface buoyancy loss. In this study, hydrographic and current measurements collected from a mooring deployed in the Lofoten basin from July 2010 to September 2012 are used to describe water mass transformation and the mesoscale eddy field. Winter mixed layer depths (MLDs) are observed to reach approximately 400 m, with larger MLDs and denser properties resulting from the colder 2010 winter. A heat budget of the upper water column requires lateral input, which balances the net annual heat loss of ~80 W m−2. The lateral flux is a result of mesoscale eddies, which dominate the velocity variability. Eddy velocities are enhanced in the upper 1000 m, with a barotropic component that reaches the bottom. Detailed examination of two eddies, from April and August 2012, highlights the variability of the eddy field and eddy properties. Temperature and salinity properties of the April eddy suggest that it originated from the slope current but was ventilated by surface fluxes. The properties within the eddy were similar to those of the mode water, indicating that convection within the eddies may make an important contribution to water mass transformation. A rough estimate of eddy flux per unit boundary current length suggests that fluxes in the Lofoten basin are larger than in the Labrador Sea because of the enhanced boundary current–interior density difference.The work was supported by NSF OCE 0850416.2015-12-0

Sediment resuspension and nepheloid layers induced by long internal solitary waves shoaling orthogonally on uniform slopes

Author Posting. © The Author(s), 2013. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Continental Shelf Research 72 (2014): 21-33, doi:10.1016/j.csr.2013.10.019.Two-dimensional, nonlinear and nonhydrostatic field-scale numerical simulations are used to examine the resuspension, dispersal and transport of mud-like sediment caused by the shoaling and breaking of long internal solitary waves on uniform slopes. The patterns of erosion and transport are both examined, in a series of test cases with varying conditions. Shoreward sediment movement is mainly within boluses, while seaward movement is within intermediate nepheloid layers. Several relationships between properties of the suspended sediment and control parameters are determined such as the horizontal extent of the nehpeloid layers, the total mass of resuspended sediment and the point of maximum bed erosion. The numerical results provide a plausible explanation for acoustic backscatter patterns observed during and after the shoaling of internal solitary wavetrains in a natural coastal environment. The results may further help interpret sedimentary structures that may have been shaped by internal waves and add an another e ective mechanism for o shore dispersal of muddy sediments.This research was funded by the Natural Sciences and Engineering Research Council of Canada (D. Bourgault) and by the Spanish Research Project CGL2009-13254 (M. Morsilli)

Measurements of shoaling internal waves and turbulence in an estuary

Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 118 (2013): 273–286, doi:10.1029/2012JC008154.The shoaling of horizontally propagating internal waves may represent an important source of mixing and transport in estuaries and coastal seas. Including such effects in numerical models demands improvements in the understanding of several aspects of the energetics, especially those relating to turbulence generation, and observations are needed to build this understanding. To address some of these issues in the estuarine context, we undertook an intensive field program for 10 days in the summer of 2008 in the St. Lawrence Estuary. The sampling involved shore-based photogrammetry, ship-based surveys, and an array of moorings in the shoaling region that held both conventional and turbulence-resolving sensors. The measurements shed light on many aspects of the wave shoaling process. Wave arrivals were generally phase-locked with the M2 tide, providing hints about far-field forcing. In the deeper part of the study domain, the waves propagated according to the predictions of linear theory. In intermediate-depth waters, the waves traversed the field site perpendicularly to isobaths, a pattern that continued as the waves transformed nonlinearly. Acoustic Doppler velocimeters permitted inference of the turbulent energetics, and two main features were studied. First, during a period of shoaling internal waves, turbulence dissipation rates exceeded values associated with tidal shear by an order of magnitude. Second, the evolving spectral signatures associated with a particular wave-shoaling event suggest that the turbulence is at least partly locally generated. Overall, the results of this study suggest that parameterizations of wave-induced mixing could employ relatively simple dynamics in deep water, but may have to handle a wide suite of turbulence generation and transport mechanisms in inshore regions.The work was supported by the Killam Foundation, the Natural Sciences and Engineering Research Council of Canada, the Canadian Foundation for Innovation, the Canadian Foundation for Climate and Atmospheric Sciences, and the Canadian Department of Fisheries and Oceans.2013-07-3

Facile C_sp²-C_sp² bond cleavage in oxalic acid-derived radicals

Oxalate decarboxylase (OxDC) catalyzes the Mn-dependent conversion of the oxalate monoanion into CO2 and formate. Many questions remain about the catalytic mechanism of OxDC although it has been proposed that the reaction proceeds via substrate-based radical intermediates. Using coupled cluster theory combined with implicit solvation models we have examined the effects of radical formation on the structure and reactivity of oxalic acid-derived radicals in aqueous solution. Our results show that the calculated solution-phase free-energy barrier for C–C bond cleavage to form CO2 is decreased from 34.2 kcal/mol for oxalic acid to only 9.3 kcal/mol and a maximum of 3.5 kcal/mol for the cationic and neutral oxalic acid-derived radicals, respectively. These studies also show that the C–C σ bonding orbital of the radical cation contains only a single electron, giving rise to an elongated C–C bond distance of 1.7 Å; a similar lengthening of the C–C bond is not observed for the neutral radical. This study provides new chemical insights into the structure and stability of plausible intermediates in the catalytic mechanism of OxDC, and suggests that removal of an electron to form a radical (with or without the concomitant loss of a proton) may be a general strategy for cleaving the unreactive C–C bonds between adjacent sp2-hybridized carbon atoms

Structure and dynamics of a subglacial discharge plume in a Greenlandic fjord

Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 8670–8688, doi:10.1002/2016JC011764.Discharge of surface-derived meltwater at the submerged base of Greenland's marine-terminating glaciers creates subglacial discharge plumes that rise along the glacier/ocean interface. These plumes impact submarine melting, calving, and fjord circulation. Observations of plume properties and dynamics are challenging due to their proximity to the calving edge of glaciers. Therefore, to date information on these plumes has been largely derived from models. Here we present temperature, salinity, and velocity data collected in a plume that surfaced at the edge of Saqqarliup Sermia, a midsized Greenlandic glacier. The plume is associated with a narrow core of rising waters approximately 20 m in diameter at the ice edge that spreads to a 200 m by 300 m plume pool as it reaches the surface, before descending to its equilibrium depth. Volume flux estimates indicate that the plume is primarily driven by subglacial discharge and that this has been diluted in a ratio of 1:10 by the time the plume reaches the surface. While highly uncertain, meltwater fluxes are likely 2 orders of magnitude smaller than the subglacial discharge flux. The overall plume characteristics agree with those predicted by theoretical plume models for a convection-driven plume with limited influence from submarine melting.National Science Foundation (NSF) Grant Numbers: PLR-1418256 , OCE-1434041; Woods Hole Oceanographic Institution (WHOI) Ocean and Climate Change Institute (OCCI) Arctic Research Initiative OCCI; National Aeronautics and Space Administration Grant Number: NNX10AN83H2017-06-1

Development of the Variable Dexterity Test: construction, reliability and validity

Background/Aims: This article introduces a dexterity test designed to assess individual types of dexterity used to carry out activities of daily living (ADL). The Variable Dexterity Test (VDT) was developed as part of a wider study, the broader aim being to fully understand dexterity and its effect on human-product interaction during ADL. This was done with a view to improve occupational therapy methods when assessing dexterity and general hand function. Methods: The control group consisted of 24 healthy participants. Estimates of reliability and validity were evaluated in this pilot study. Inter-rater and test-retest reliability were assessed using a one-way ANOVA. The validity of the test was estimated by correlating participants’ VDT scores with their proficiency to complete four ADL task actions and a standardised dexterity test (Purdue Pegboard Test). Results: The test produced consistent results among the control group with both a single assessor (test‑retest reliability) and multiple assessors (inter‑rater reliability). High correlations between participants’ VDT scores and proficiency to perform ADL were found for most of the subtests. There was also a high correlation between participants’ scores from the Purdue Pegboard Test and the VDT. Conclusions: The VDT proved to be a flexible, reliable and valid tool that assesses dexterity based on ability to carry out ADL. Validity and reliability estimates show encouraging values, which recognises that the VDT can be used as an accurate method to assess more than one type of dexterity.</p

First results from 2+1 dynamical quark flavors on an anisotropic lattice: light-hadron spectroscopy and setting the strange-quark mass

We present the first light-hadron spectroscopy on a set of $N_f=2+1$ dynamical, anisotropic lattices. A convenient set of coordinates that parameterize the two-dimensional plane of light and strange-quark masses is introduced. These coordinates are used to extrapolate data obtained at the simulated values of the quark masses to the physical light and strange-quark point. A measurement of the Sommer scale on these ensembles is made, and the performance of the hybrid Monte Carlo algorithm used for generating the ensembles is estimated.Comment: 24 pages. Hadron Spectrum Collaboratio

Large spatial variations in the flux balance along the front of a Greenland tidewater glacier

The frontal flux balance of a medium-sized tidewater glacier in western Greenland in the summer is assessed by quantifying the individual components (ice flux, retreat, calving, and submarine melting) through a combination of data and models. Ice flux and retreat are obtained from satellite data. Submarine melting is derived using a high-resolution ocean model informed by near-ice observations, and calving is estimated using a record of calving events along the ice front. All terms exhibit large spatial variability along the  ∼ 5&thinsp;km wide ice front. It is found that submarine melting accounts for much of the frontal ablation in small regions where two subglacial discharge plumes emerge at the ice front. Away from the subglacial plumes, the estimated melting accounts for a small fraction of frontal ablation. Glacier-wide, these estimates suggest that mass loss is largely controlled by calving. This result, however, is at odds with the limited presence of icebergs at this calving front – suggesting that melt rates in regions outside of the subglacial plumes may be underestimated. Finally, we argue that localized melt incisions into the glacier front can be significant drivers of calving. Our results suggest a complex interplay of melting and calving marked by high spatial variability along the glacier front.</p

The institutional shaping of management: in the tracks of English individualism

Globalisation raises important questions about the shaping of economic action by cultural factors. This article explores the formation of what is seen by some as a prime influence on the formation of British management: individualism. Drawing on a range of historical sources, it argues for a comparative approach. In this case, the primary comparison drawn is between England and Scotland. The contention is that there is a systemic approach to authority in Scotland that can be contrasted to a personal approach in England. An examination of the careers of a number of Scottish pioneers of management suggests the roots of this systemic approach in practices of church governance. Ultimately this systemic approach was to take a secondary role to the personal approach engendered by institutions like the universities of Oxford and Cambridge, but it found more success in the different institutional context of the USA. The complexities of dealing with historical evidence are stressed, as is the value of taking a comparative approach. In this case this indicates a need to take religious practice as seriously as religious belief as a source of transferable practice. The article suggests that management should not be seen as a simple response to economic imperatives, but as shaped by the social and cultural context from which it emerges