Bromostibine complexes of iron(II): hypervalency and reactivity

The halostibine complexes [CpFe(CO)2(SbMe2Br)][CF3SO3] and [CpFe(CO)2(SbMe2Br)][BF4] both contain significant interactions between the anion and the formally neutral Sb(III) ligand, which simultaneously displays Lewis acidic and Lewis basic properties. The unexpected secondary product [CpFe(CO)(Me2BrSb-?-Br-SbBrMe2)] is formed in the presence of excess ligand, the strongly associated Br– anion bridging the two Sb donors to form a four-membered FeSb2Br ring.<br/

A Documentary of High-Mass Star Formation: Probing the Dynamical Evolution of Orion Source I on 10-100 AU Scales using SiO Masers

A comprehensive picture of high-mass star formation has remained elusive, in part because examples of high-mass YSOs tend to be relatively distant, deeply embedded, and confused with other emission sources. These factors have impeded dynamical investigations within tens of AU of high-mass YSOs--scales that are critical for probing the interfaces where outflows from accretion disks are launched and collimated. Using observations of SiO masers obtained with the VLA and the VLBA, the KaLYPSO project is overcoming these limitations by mapping the structure and dynamical/temporal evolution of the material 10-1000 AU from the nearest high-mass YSO: Radio Source I in the Orion BN/KL region. Our data include ~40 epochs of VLBA observations over a several-year period, allowing us to track the proper motions of individual SiO maser spots and to monitor changes in the physical conditions of the emitting material with time. Ultimately these data will provide 3-D maps of the outflow structure over approximately 30% of the outflow crossing time. Here we summarize recent results from the KaLYPSO project, including evidence that high-mass star formation is occurring via disk-mediated accretion.Comment: 5 pages; to appear in the proceedings of IAU Symposium 242, Astrophysical Masers and their Environments, ed. J. Chapman & W. Baa

Toward a New Distance to the Active Galaxy NGC 4258: II. Centripetal Accelerations and Investigation of Spiral Structure

We report measurements of centripetal accelerations of maser spectral components of NGC 4258 for 51 epochs spanning 1994 to 2004. This is the second paper of a series, in which the goal is determination of a new geometric maser distance to NGC 4258 accurate to possibly ~3%. We measure accelerations using a formal analysis method that involves simultaneous decomposition of maser spectra for all epochs into multiple, Gaussian components. Components are coupled between epochs by linear drifts (accelerations) from their centroid velocities at a reference epoch. For high-velocity emission, accelerations lie in the range -0.7 to +0.7 km/s/yr indicating an origin within 13 degrees of the disk midline (the perpendicular to the line-of-sight to the black hole). Comparison of high-velocity emission projected positions in VLBI images, with those derived from acceleration data, provides evidence that masers trace real gas dynamics. High-velocity emission accelerations do not support a model of trailing shocks associated with spiral arms in the disk. However, we find strengthened evidence for spatial periodicity in high-velocity emission, of wavelength 0.75 mas. This supports suggestions of spiral structure due to density waves in the nuclear accretion disk of an active galaxy. Accelerations of low-velocity (systemic) emission lie in the range 7.7 to 8.9 km/s/yr, consistent with emission originating from a concavity where the thin, warped disk is tangent to the line-of-sight. A trend in accelerations of low-velocity emission as a function of Doppler velocity may be associated with disk geometry and orientation, or with the presence of spiral structure.Comment: Accepted to ApJ, 48 pages and 20 figure

Faint M-dwarfs and the structure of the Galactic disk

We use broadband photometry and low-resolution spectra of a complete sample of late-K and M dwarfs brighter than I=22 in three fields at high galactic latitude to study issues relating to galactic structure and large scale abundance gradients in the Galaxy. The observed starcounts in each field are a good match to the predictions of models based on deep starcount data in other intermediate-latitude fields, and these models identify the late-type stars as members of the Galactic disk. Abundances for these late type stars are estimated via narrowband indices that measure the strength of the TiO and CaH bands in their spectra. Our results show that the average abundance in the Galactic disk remains close to solar even at heights of more than 2 kpc above the Plane.Comment: to appear in PASP; 17 pages, including 7 embedded, postscript figures and 1 embedded table; uses AAS LaTeX style files (not included); also available at http://astro.caltech.edu/~map/map.bibliography.htm

Modeling near-field radiative heat transfer from sharp objects using a general 3d numerical scattering technique

We examine the non-equilibrium radiative heat transfer between a plate and finite cylinders and cones, making the first accurate theoretical predictions for the total heat transfer and the spatial heat flux profile for three-dimensional compact objects including corners or tips. We find qualitatively different scaling laws for conical shapes at small separations, and in contrast to a flat/slightly-curved object, a sharp cone exhibits a local \emph{minimum} in the spatially resolved heat flux directly below the tip. The method we develop, in which a scattering-theory formulation of thermal transfer is combined with a boundary-element method for computing scattering matrices, can be applied to three-dimensional objects of arbitrary shape.Comment: 5 pages, 4 figures. Corrected background information in the introduction, results and discussion unchange

Understanding the role of shame and its consequences in female hypersexual behaviours: A pilot study

Background and aims: Hypersexuality and sexual addiction among females is a little understudied phenomenon. Shame is thought to be intrinsic to hypersexual behaviours, especially in women. Therefore, the aim of this study was to understand both hypersexual behaviours and consequences of hypersexual behaviours and their respective contributions to shame in a British sample of females (n = 102). Methods: Data were collected online via Survey Monkey. Results: Results showed the Sexual Behaviour History (SBH) and the Hypersexual Disorder Questionnaire (HDQ) had significant positive correlation with scores on the Shame Inventory. The results indicated that hypersexual behaviours (HBI and HDQ) were able to predict a small percentage of the variability in shame once sexual orientation (heterosexual vs. non-heterosexual) and religious beliefs (belief vs. no belief) were controlled for. Results also showed there was no evidence that religious affiliation and/or religious beliefs had an influence on the levels of hypersexuality and consequences of sexual behaviours as predictors of shame. Conclusions: While women in the UK are rapidly shifting to a feminist way of thinking with or without technology, hypersexual disorder may often be misdiagnosed and misunderstood because of the lack of understanding and how it is conceptualised. The implications of these findings are discussed

Aquaculture and eelgrass Zostera marina interactions in temperate ecosystems

This paper reviews the impacts of shellfish and finfish aquaculture on eelgrassZostera marina, the most widely distributed seagrass species in the northern hemisphere. Shellfish aquaculture can have positive, neutral, and negative effects on eelgrass. Positive interactions can be generated by the filtering activity of cultured bivalves, which may improve water quality and reduce epiphyte loads, and shellfish biodeposits may provide more nutrients to eelgrass and other vegetation. However, negative responses are more commonly reported and can be causedby shading and sedimentation. These negative effects tend to occur directly under and immediately surrounding shellfish farms and rapidly diminish with increasing distance. In contrast to shellfish aquaculture, only one field study has investigated the effects of finfish aquaculture on eelgrass in a temperate setting, and the results were inconclusive. However, many studies have investigated the effects of Mediterranean finfish farms on 2 other species of seagrass (Posidoniaoceanica and Cymodocea nodosa). These studies reported clear negative interactions, which have been linked to increased nutrient concentrations, sulphides, sedimentation, epiphyte loads, and grazing pressure. It is unknown if these studies are relevant for finfish aquaculture in temperate regions due to differences in environmental conditions, and because the studies focused on differ-ent species of seagrass. Thus, further study in a temperate setting is warranted. We conclude by highlighting key research gaps that could help regulators establish unambiguous operational and siting guidelines that minimize the potential for negative interactions between aquaculture and eelgrass

Zeta-Function Regularization is Uniquely Defined and Well

Hawking's zeta function regularization procedure is shown to be rigorously and uniquely defined, thus putting and end to the spreading lore about different difficulties associated with it. Basic misconceptions, misunderstandings and errors which keep appearing in important scientific journals when dealing with this beautiful regularization method ---and other analytical procedures--- are clarified and corrected.Comment: 7 pages, LaTeX fil