390 research outputs found

    Switching Equivalence in Symmetric n-Sigraphs-V

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    Introducing a new notion S-antipodal symmetric n-sigraph of a symmetric n-sigraph and its properties are obtained. Also giving the relation between antipodal symmetric n-sigraphs and S-antipodal symmetric n-sigraphs. Further, discussing structural characterization of S-antipodal symmetric n-sigraphs

    Cationic complexes of platinum and palladium with p-tolyl isocyanide

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    Cationic complexes of platinum and palladium of the type [MCl(p-CH3C6H4NC)L2]ClO4 (M = Pt, Pd; L = p-tolyl3P, o-tolyl3P, Cy3P, Ph2MeAs, Ph2EtAs, Ph2PrAs, Cy3As; Cy = cyclohexyl) have been isolated. These show a v(CN) band at ca. 2200 cm-1 compared with 2130 cm-1 for the free isocyanide ligand, suggesting weak π-character in the metal-carbon bond. The PMR spectra of the cationic complexes indicate trans configurations for the complexes. © 1977

    Synthesis, characterization, antibacterial, antifungal and anthelmintic activities of a new 5-​nitroisatin Schiff base and its metal complexes

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    The copper (II)​, cobalt (II)​, nickel (II) and zinc (II) complexes of 5 - nitroisatin Schiff base (L) (L = Schiff base derived from 5-​nitroisatin and 2-​methyl-​4-​nitroaniline) were synthesized and characterized. The authenticity of the ligand and its metal complexes has been established by micro anal., IR, NMR, LC​/MS, UV-​VIS and elec. conductance measurements. The ligand acts as a bidentate agent in which the carbonyl oxygen and the azomethine nitrogen of 5-​nitroisatin are involved in co-​ordination. Square planar geometry was proposed for the Cu (II) and Ni (II) complexes and tetrahedral geometry was proposed for the Co (II) and Zn (II) complexes. The ligand and its metal complexes have been screened for antibacterial activity against Staphylococcus aureus, Escherichia coli, etc. and for antifungal activity against Aspergillus niger, Aspergillus flavous, etc. The Schiff base and its complexes were also screened for anthelmintic activity on earthworms. Both samples displayed significant activitie

    Comparative Degradation of LDPE, HDPE and HMHDPE under Different Soil Conditions

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    The Present work includes, degradation of polyethylene under different environmental conditions to know the effect of physical, chemical and biological factors prevailing in those conditions on degradation of polyethylene. Plastic films viz., Low density polyethylene (LDPE), High density polyethylene (HDPE) and High molecular weight high density polyethylene (HMHDPE) each were incubated in three different conditions viz., black soil, sandy soil and red soil for a period of 3 months. The changes in the properties of plastic films after incubation was studied by change in the weight of the plastic film and mechanical parameters like tensile strength, breaking load and percentage of elongation. Among all the plastic films HDPE was found to be highly susceptible with 33% weight loss and 40% reduction in percentage of elongation compared to LDPE with 26% weight loss and 34 % reduction in percentage of elongation in black soil. Whereas HMHDPE found to be highly resistant in all the soils with no significant weight loss and percentage of elongation (15%). None of the plastic films had shown degradation in sandy soil even after incubation for 3 months. FTIR spectroscopy results showed that HDPE film incubated in black soil had undergone extensive degradation when compared with un incubated HDPE film

    Automatic Raaga Identification System For Carnatic Music Using Hidden Markov Model

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    As for as the Human Computer Interactions (HCI) is concerned, there is broad range of applications in the area of research in respective of Automatic Melakarta Raaga Identification in music. The pattern of identification is the main object for which, the basic mathematical tool is utilized. On verification, it is observed that no model is proved consistently and effectively to be predicted in its classification. This paper is, therefore, introduces a procedure for Raaga Identification with the help of Hidden Markov Models (HMM) which is rather an appropriate approach in identifying Melakarta Raagas. This proposed approach is based on the standard speech recognition technology by using Hidden continuous Markov Model. Data is collected from the existing data base for training and testing of the method with due design process relating to Melakarta Raagas. Similarly, to solve the problem of automatic identification of raagas, a suitable approach from the existing database is presented. The system, particularly, this model is based on a Hidden Markov Model enhanced with Pakad string matching algorithm. The entire system is built on top of an automatic note transcriptor. At the end, detailed elucidations of the experiments are given. It clearly indicates the effectiveness and applicability of this method with its intrinsic value and significance

    Symptomatic “H” Type Duplex Gallbladder

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    A case of ductular type duplex gallbladder is presented that was diagnosed by magnetic resonance cholangiopancreatography and managed by laparoscopy

    Synthesis And Characterization Of Co-Doped SnO2/TiO2 Semiconductor Nano Crystallites Via Sol-Gel Method

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    SnO2/TiO2 nano particles are novel wide band gap semiconductors with modified applications of SnO2 and TiO2 in some fields including gas sensing, photo catalytic, solar cells and so on. The Co-doped SnO2/TiO2 nano particles were obtained via sol-gel method with different amounts of doping material as 2.5 %, 6 % and 10 mol %. The crystallite sizes of resulting material were from 3.8 nm for 0.1 wt % Co-doped SnO2/TiO2 to 19.1 nm for un-doped. Morphology and nanostructure of the crystalline SnO2/TiO2 nano particles were characterized by means of X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), Thermal gravimetric analysis (TGA), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray spectroscopy (EDX). It has been shown that fine semiconductor nano structures were formed. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/933

    A Simple Sol Gel Protocol Towards Synthesis Of Semiconducting Oxide Nanomaterial

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    Nanostructured Tin oxide (SnO2), powders was synthesized by employing a novel Sol-gel protocol at RT. A wide variety of techniques such as energy – dispersive spectroscopy(EDX), N2 sorption, X-ray diffraction (XRD), have been used to study the formation process and characterization of the nanoparticles obtained. Transmission electron microscopy (TEM) has been applied to find out about the shape and size distribution of the particles. The nanoparticles thus synthesized were monodispersed, with an average particle size of ~ 10 nm and spherical in shape. The EDX analysis revealed the presence of Sn, O signal in the synthesized nanoparticles confirming the purity of the synthesized samples. This protocol appears promising for application in large-scale synthesis of nanoparticles. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/933
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