522 research outputs found
Transnationalism and Migration: Chinese Migrants in New Zealand
Transnational migration is an integral part of the modern world. Immigration policies, economic initiatives and international agreements of modern natiion-states have shaped the growth of transnational migration. Nation-states classify migrants into different categories for the purpose of border control; they have favoured some groups of migrants over the others. This is particularly true for New Zealand, which has maintained close connections with the United Kingdom and preferred British migrants to other peoples since the nineteenth century. New Zealand has always emphasized the economic integration of migrants into the society. Against this background, Chinese migrants arrived and developed their transnational networks across the Pacific Ocean for familiar, social and economic reasons. This paper discusses the transformation of New Zealand\u27s immigration policies and its impact on transnational practices of Chinese migrants from the past to the present. It begins with a critical account of the early development of immigration policies in New Zealnd. Then it discusses the transnational networks of Chinese migrants in New Zealand throughout the late nineteenth and early twentieth centuries. The core of this study focuses on the different patterns of Chinese migration and settlement in New Zealand after the immigration reform in the 1980s and the emergence of Chinese transnational networks in the recent decades
Intermolecular 1,3-dipolar cycloadditions of azomethine imines
Dipolar cycloadditions of azomethine imines, formed in situ from aldehydes and N1-alkyl-N2-acylhydrazines, with electron-deficient dipolarophiles produce pyrazolidines: mono-substituted dipolarophiles afford principally 4-substituted pyrazolidines
An alkylation route to carbo- and heteroaromatic amino acids
Amino acids carrying aromatic carbo- and heterocycles in the side chain, such as naphthyl-, biphenyl- and pyridylalanines, have been prepared by alkylation of a glycine enolate with a haloalkyl carbocycle or heterocycle, with enantiomeric excess up to 87% using the ephedrine amide protocol
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A catalytic dipolar cycloaddition route to pyrroloimidazoles
A catalytic method involving carbenoid insertion onto dihydroimidazoles is reported for the generation of dihydroimidazolium ylides, and their subsequent diastereoselective cycloaddition to form pyrrolo[1,2-a]imidazole
Isolation of novel para-pentyl phenyl benzoate from Mondia whitei.(Hook.F.) skeels (periplocaceae), its structure, synthesis and neuropharmacological evaluation
Background: Mondia whitei L. (Hook. F.) Skeels (Periplocaceae) is a medicinal plant used locally in managing pain, fever, loss of appetite and as aphrodiasc in the South-Western states of Nigeria. However, the fruit is consumed habitually in the South-Eastern states of Nigeria, leading to speculation that it may possess some central nervous system effect but which has not been scientifically investigated, hence this study.Methodology: Fresh fruits of Mondia whitei were collected and identified by a taxonomist. They were chopped into small pieces and extracted with absolute ethanol. The crude extract was subjected to various chromatographic techniques to isolate a novel compound whose structure was elucidated from the analysis of the crystal data and by extensive use of spectroscopy. The structure was confirmed by synthesis. The compound was subjected to anxiolytic and sedative activity assay. Computational analysis of the receptor binding event of isolated compound at the gamma amino butyric acid A receptor was also evaluated.Results: The structure of the compound was elucidated as para pentyl phenyl benzoate. The neuropharmacological evaluation of the compound indicated significant (p<0.05) depression of the central nervous system. The binding characteristics of the compound to gamma amino butyric acid A receptors appears to be more favorable than those obtained for gamma amino butyric acid, chlorpromazine, benzamidine, and is comparable with the affinity obtained for pentobarbitone and diazepam.Conclusion: These present data provide evidence for the role of para pentyl phenyl benzoate in the habitual consumption of the fruit as well as its central nervous system activities.Keywords: Mondia whitei, Periplocaceae, isolation and synthesis, sedative and anxiolytic effect and Para pentylphenyl benzoat
Characterizing Multi-planet Systems with Classical Secular Theory
Classical secular theory can be a powerful tool to describe the qualitative
character of multi-planet systems and offer insight into their histories. The
eigenmodes of the secular behavior, rather than current orbital elements, can
help identify tidal effects, early planet-planet scattering, and dynamical
coupling among the planets, for systems in which mean-motion resonances do not
play a role. Although tidal damping can result in aligned major axes after all
but one eigenmode have damped away, such alignment may simply be fortuitous. An
example of this is 55 Cancri (orbital solution of Fischer et al., 2008) where
multiple eigenmodes remain undamped. Various solutions for 55 Cancri are
compared, showing differing dynamical groupings, with implications for the
coupling of eccentricities and for the partitioning of damping among the
planets. Solutions for orbits that include expectations of past tidal evolution
with observational data, must take into account which eigenmodes should be
damped, rather than expecting particular eccentricities to be near zero.
Classical secular theory is only accurate for low eccentricity values, but
comparison with other results suggests that it can yield useful qualitative
descriptions of behavior even for moderately large eccentricity values, and may
have advantages for revealing underlying physical processes and, as large
numbers of new systems are discovered, for triage to identify where more
comprehensive dynamical studies should have priority.Comment: Published in Celestial Mechanics and Dynamical Astronomy, 25 pages,
10 figure
Optical Imaging and Spectroscopic Observation of the Galactic Supernova Remnant G85.9-0.6
Optical CCD imaging with H and [SII] filters and spectroscopic
observations of the galactic supernova remnant G85.9-0.6 have been performed
for the first time. The CCD image data are taken with the 1.5m Russian-Turkish
Telescope (RTT150) at TUBITAK National Observatory (TUG) and spectral data are
taken with the Bok 2.3 m telescope on Kitt Peak, AZ.
The images are taken with narrow-band interference filters H, [SII]
and their continuum. [SII]/H ratio image is performed. The ratio
obtained from [SII]/H is found to be 0.42, indicating that the
remnant interacts with HII regions. G85.9-0.6 shows diffuse-shell morphology.
[SII] average flux ratio is calculated from the
spectra, and the electron density is obtained to be 395 . From
[OIII]/H ratio, shock velocity has been estimated, pre-shock density of
, explosion energy of ergs,
interstellar extinction of , and neutral hydrogen column density
of are reported.Comment: 20 pages, 4 tables, 4 figures. Accepted for publication in
Astrophysics & Space Scienc
A two-step learning approach for solving full and almost full cold start problems in dyadic prediction
Dyadic prediction methods operate on pairs of objects (dyads), aiming to
infer labels for out-of-sample dyads. We consider the full and almost full cold
start problem in dyadic prediction, a setting that occurs when both objects in
an out-of-sample dyad have not been observed during training, or if one of them
has been observed, but very few times. A popular approach for addressing this
problem is to train a model that makes predictions based on a pairwise feature
representation of the dyads, or, in case of kernel methods, based on a tensor
product pairwise kernel. As an alternative to such a kernel approach, we
introduce a novel two-step learning algorithm that borrows ideas from the
fields of pairwise learning and spectral filtering. We show theoretically that
the two-step method is very closely related to the tensor product kernel
approach, and experimentally that it yields a slightly better predictive
performance. Moreover, unlike existing tensor product kernel methods, the
two-step method allows closed-form solutions for training and parameter
selection via cross-validation estimates both in the full and almost full cold
start settings, making the approach much more efficient and straightforward to
implement
Isolation of novel para-pentyl phenyl benzoate from Mondia whitei. (Hook.F) Skeels (Periplocaceae), its structure, synthesis, and neuropharamacological evaluation
Background: Mondia whitei L. (Hook. F.) Skeels (Periplocaceae) is a medicinal plant used locally in managing pain, fever, loss of appetite and as aphrodiasc in the South-Western states of Nigeria. However, the fruit is consumed habitually in the South-Eastern states of Nigeria, leading to speculation that it may possess some central nervous system effect but which has
not been scientifically investigated, hence this study.
Methodology: Fresh fruits of Mondia whitei were collected and identified by a taxonomist. They were chopped into small
pieces and extracted with absolute ethanol. The crude extract was subjected to various chromatographic techniques to isolate a novel compound whose structure was elucidated from the analysis of the crystal data and by extensive use of spectroscopy. The structure was confirmed by synthesis. The compound was subjected to anxiolytic and sedative activity
assay. Computational analysis of the receptor binding event of isolated compound at the gamma amino butyric acid A receptor was also evaluated.
Results: The structure of the compound was elucidated as para pentyl phenyl benzoate. The neuropharmacological
evaluation of the compound indicated significant (p<0.05) depression of the central nervous system. The binding
characteristics of the compound to gamma amino butyric acid A receptors appears to be more favorable than those obtained
for gamma amino butyric acid, chlorpromazine, benzamidine, and is comparable with the affinity obtained for pentobarbitone and diazepam.
Conclusion These present data provide evidence for the role of para pentyl phenyl benzoate in the habitual consumption of
the fruit as well as its central nervous system activities
Equilibration processes in the Warm-Hot Intergalactic Medium
The Warm-Hot Intergalactic Medium (WHIM) is thought to contribute about 40-50
% to the baryonic budget at the present evolution stage of the universe. The
observed large scale structure is likely to be due to gravitational growth of
density fluctuations in the post-inflation era. The evolving cosmic web is
governed by non-linear gravitational growth of the initially weak density
fluctuations in the dark energy dominated cosmology. Non-linear structure
formation, accretion and merging processes, star forming and AGN activity
produce gas shocks in the WHIM. Shock waves are converting a fraction of the
gravitation power to thermal and non-thermal emission of baryonic/leptonic
matter. They provide the most likely way to power the luminous matter in the
WHIM. The plasma shocks in the WHIM are expected to be collisionless.
Collisionless shocks produce a highly non-equilibrium state with anisotropic
temperatures and a large differences in ion and electron temperatures. We
discuss the ion and electron heating by the collisionless shocks and then
review the plasma processes responsible for the Coulomb equilibration and
collisional ionisation equilibrium of oxygen ions in the WHIM. MHD-turbulence
produced by the strong collisionless shocks could provide a sizeable
non-thermal contribution to the observed Doppler parameter of the UV line
spectra of the WHIM.Comment: 13 pages, 4 figures, accepted for publication in Space Science
Reviews, special issue "Clusters of galaxies: beyond the thermal view",
Editor J.S. Kaastra, Chapter 8; work done by an international team at the
International Space Science Institute (ISSI), Bern, organised by J.S.
Kaastra, A.M. Bykov, S. Schindler & J.A.M. Bleeke
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