Evaluation of peptide alkylation side-resctions in common protein digestion protocols

Comunicaciones a congreso

Model Predictive Control-Based Optimized Operation of a Hybrid Charging Station for Electric Vehicles

This paper presents an energy management system (EMS) based on a novel approach using model predictive control (MPC) for the optimized operation of power sources in a hybrid charging station for electric vehicles (EVs). The hybrid charging station is composed of a photovoltaic (PV) system, a battery, a complete hydrogen system based on a fuel cell (FC), electrolyzer (EZ), and tank as an energy storage system (ESS), grid connection, and six fast charging units, all of which are connected to a common MVDC bus through Z-source converters (ZSC). The MPC-based EMS is designed to control the power flow among the energy sources of the hybrid charging station and reduce the utilization costs of the ESS and the dependency on the grid. The viability of the EMS was proved under a long-term simulation of 25 years in Simulink, using real data for the sun irradiance and a European load profile for EVs. Furthermore, this EMS is compared with a simpler alternative that is used as a benchmark, which pursues the same objectives, although using a states-based strategy. The results prove the suitability of the EMS, achieving a lower utilization cost (-25.3%), a notable reduction in grid use (-60% approximately) and an improvement in efficiency

Averaged Dynamic Modeling and Control of a Quasi-Z-Source Inverter for Wind Power Applications

Typically, permanent magnet synchronous generator (PMSG)-driven wind turbines (WTs) present a two-stage power converter topology based on a DC/DC boost converter and voltage source inverter. In this study, this configuration is substituted by a quasi-Z-source inverter (qZSI), which is an attractive solution for boosting and converting the voltage from DC to AC in a single stage. A 2 MW PMSG WT with qZSI was studied herein. A switched dynamic model (SDM) of the qZSI (including the modeling of all switches and firing pulses) is not recommended for steady-state stability studies, long-term simulations, or large electric power systems. For such studies, two averaged dynamic models are proposed in this work. Both models present the same control system as the SDM, except for the generation of firing pulses, which is not necessary in the averaged models. The two proposed models were evaluated and compared with the SDM in the large-scale WT under different operating conditions, such as wind speed fluctuations, variable power references, and grid disturbances (voltage sag and 3(rd) and 5(th) order harmonics injection), in order to demonstrate their adequacy to represent the system response with a high reduction in the simulation time and computational efforts.This work was supported in part by the Spain's Ministerio de Ciencia, Innovacion y Universidades (MCIU), Agencia Estatal de Investigacion (AEI), and Fondo Europeo de Desarrollo Regional (FEDER) Union Europea (UE) under Grant RTI2018-095720-B-C32, in part by the National Council of Technological and Scientific Development (CNPq), Brazil, in part by the Federal Center for Technological Education of Minas Gerais, Brazil, under Process 23062-010087/2017-51, and in part by the Regional Ministry of Economic Transformation, Industry, Knowledge and Universities of Junta de Andalucia under Grant PY20_00317

Decadal variability 2010-2021 of zooplankton community at the Guadalquivir estuary (southern Spain)

A Long Term Ecological Research Program has been monitoring the Guadalquivir estuary meso- and macro- zooplankton community monthly since January 2010. As an important nursery area for many marine species (fish and crustacean) from the Gulf of Cadiz, whose juveniles and recruits depend on zooplankton as main prey, understanding how abiotic and biotic factors determine zooplankton community structure it´s necessary to unreveal recruitment variability. We sampled throughout the whole salinity gradient, 2 locations, the two diurnal ebb and flood tides during the new moon days using a 100 μm zooplankton net. Zooplankton community is mainly composed by copepods and mysids. While the exotic Acartia tonsa calanoid copepod is the most abundant specie by abundance, mysid Mesopodopsis slabberi contribute the most to total biomass, followed by mysids Rhopalophthalmus tartessicus and Neomysis integer. Other abundant groups were copepods Acartia bifilosa and Acartia clausii, Calanipeda aquaedulcis, Paracalanus parvus and Acanthocyclops robustus, cladocera Pleopis polyphaemoides, together with veliger larvae, Cirripeda and Ostracoda, and Decapoda larvae. About total biodiversity, we found up to 183 species, estimating a total mean Species Richness of 9.7 (minimum 2- maximum 33) per sample, mean Shannon Diversity Index 3.27, Pielou Evenness 0.50 and mean betadiversity 0.630. While copepods area abundant form fall to early spring and summer, mysid density peaks form spring to fall. Community is structured by Salinity, but Temperature, Turbidity, Nitrate, Nitrite and Dissolved Oxygen were also important variables leading spatio-temporal variability, mainly when estuary recives high freshwater discharges from Alcala del Río dam

Hurricane Flood Hazard Assessment for the Archipelago of San Andres, Providencia and Santa Catalina, Colombia

Despite the low occurrence of tropical cyclones at the archipelago of San Andres, Providencia, and Santa Catalina (Colombia), Hurricane Iota in 2020 made evident the area vulnerability to tropical cyclones as major hazards by obliterating 56.4 % of housing, partially destroying the remaining houses in Providencia. We investigated the hurricane storm surge inundation in the archipelago by forcing hydrodynamic models with synthetic tropical cyclones and hypothetical hurricanes. The storm surge from synthetic events allowed identifying the strongest surges using the probability distribution, enabling the generation of hurricane storm surge flood maps for 100 and 500 year return periods. This analysis suggested that the east of San Andres and Providencia are the more likely areas to be flooded from hurricanes storm surges. The hypothetical events were used to force the hydrodynamic model to create worst-case flood scenario maps, useful for contingency and development planning. Additionally, Hurricane Iota flood levels were calculated using 2D and 1D models. The 2D model included storm surge (SS), SS with astronomical tides (AT), and SS with AT and wave setup (WS), resulting in a total flooded area (percentage related to Providencia's total area) of 67.05 ha (3.25 %), 65.23 ha (3.16 %), and 76.68 ha (3.68%), respectively. While Hurricane Iota occurred during low tide, the WS contributed 14.93 % (11.45 ha) of the total flooded area in Providencia. The 1D approximation showed that during the storm peak in the eastern of the island, the contribution of AT, SS, and wave runup to the maximum sea water level was -3.01%, 46.36%, and 56.55 %, respectively. This finding provides evidence of the water level underestimation in insular environments when modeling SS without wave contributions. The maximum SS derived from Iota was 1.25 m at the east of Providencia, which according to this study has an associated return period of 3,234 years. The methodology proposed in this study can be applied to other coastal zones and may include the effect of climate change on hurricane storm surges and sea-level rise. Results from this study are useful for emergency managers, government, coastal communities, and policymakers as civil protection measures

Molluscan assemblages associated with photophilous algae in the Alboran sea (western Mediterranean Sea)

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A proteored multi-centric study to assess reproducibility of relative quantification by LC-MS proteomic analysis

Comunicaciones a congreso

Exploración de beneficios de vainilla en el Área Natural Protegida Sierra de Otontepec, Veracruz en busca de coliformes

La vainilla mexicana (Vanilla planifolia Andrews) es utilizada en la industria agroalimentaria, refresquera, licorera, farmacéutica, cosmética, tabacalera y artesanal por su excelente calidad aromática con notas dulces e intensas y olor a tabaco con un carácter cremoso (Tenailleu  et al., 2004). Su beneficiado es un proceso de conservación del fruto, que se realiza mediante la deshidratación y fermentación del fruto verde sin aroma al fruto beneficiado, el cual adquiere un olor suave y agradable ante nuestro paladar. Al analizar las muestras de los cinco sitios ubicados en la Sierra de Otontepec se pudo comprobar que no se obtuvo presencia de colonias precursoras de coliformes dando negativa esta prueba, este resultado fue comparado con lo que marca la NOM-182-SCFI-2011 dentro de los parámetros de especificaciones microbiológicas para la vainilla, lo que refleja que no hay resto de microorganismos dañinos en vainas, obteniendo vainas de muy buena calidad. Todas las muestras obtenidas de los cinco sitios tienen las mismas condiciones, en cuanto a manejo y procesamiento de las vainas en el beneficio además de tener las mismas características de suelo y agua

Optimal energy management system using biogeography based optimization for grid-connected MVDC microgrid with photovoltaic, hydrogen system, electric vehicles and Z-source converters

Currently, the technology associated with charging stations for electric vehicles (EV) needs to be studied and improved to further encourage its implementation. This paper presents a new energy management system (EMS) based on a Biogeography-Based Optimization (BBO) algorithm for a hybrid EV charging station with a configuration that integrates Z-source converters (ZSC) into medium voltage direct current (MVDC) grids. The EMS uses the evolutionary BBO algorithm to optimize a fitness function defining the equivalent hydrogen consumption/generation. The charging station consists of a photovoltaic (PV) system, a local grid connection, two fast charging units and two energy storage systems (ESS), a battery energy storage (BES) and a complete hydrogen system with fuel cell (FC), electrolyzer (LZ) and hydrogen tank. Through the use of the BBO algorithm, the EMS manages the energy flow among the components to keep the power balance in the system, reducing the equivalent hydrogen consumption and optimizing the equivalent hydrogen generation. The EMS and the configuration of the charging station based on ZSCs are the main contributions of the paper. The behaviour of the EMS is demonstrated with three EV connected to the charging station under different conditions of sun irradiance. In addition, the proposed EMS is compared with a simpler EMS for the optimal management of ESS in hybrid configurations. The simulation results show that the proposed EMS achieves a notable improvement in the equivalent hydrogen consumption/generation with respect to the simpler EMS. Thanks to the proposed configuration, the output voltage of the components can be upgraded to MVDC, while reducing the number of power converters compared with other configurations without ZSC.This work was partially supported by Spain's Ministerio de Ciencia, Innovaci ' on y Universidades (MCIU), Agencia Estatal de Investigaci ' on (AEI) and Fondo Europeo de Desarrollo Regional (FEDER) Uni ' on Europea (UE) (grant number RTI2018-095720-B-C32), by the Federal Center for Technological Education of Minas Gerais, Brazil (process number 23062-010087/2017-51) and by the National Council of Technological and Scientific Development (CNPq-Brazil)

Posidonia oceanica (L.) Delile in its westernmost biogeographical limit (northwestern Alboran Sea): Meadows characterisation, phenology and flowering events

Posidonia oceanica is a Mediterranean endemic seagrass species that forms meadows covering ca. 2.5–4.5 millions of hectares, representing ca.25 % of the infralittoral and shallow circalittoral (down to 50m) bottoms of the Mediterranean. This seagrass is considered a habitat-engineer species and provides an elevated number of ecosystem services. In addition the Marine Strategy Framework Directive (MSFD, 2008/56/EC) includes seagrass like elements to evaluate the “Good Environmental Status” of the European coasts. Information about their phenological characteristic and structure of the meadows is needed for indicator estimations in order to establish their conservation status. The studied meadows are located in the westernmost limit of the P. oceanica distribution (North-western Alboran Sea) in the vecinity of the Strait of Gibraltar, an Atlantic-Mediterranean water transition area. Four sites were selected from East to West: Paraje Natural de Acantilados de Maro-Cerro Gordo (hereafter Maro), Special Area of Conservation “Calahonda” (hereafter Calahonda), Site of Community Importance Estepona (hereafter Estepona) and Punta Chullera (hereafter Chullera) where P. oceanica present their westernmost meadows. Phenological data were recorded from mid November to mid December in P. oceanica patches located at 2 – 3 m depth. At each site three types of patches (patch area 2 m2, large patches) were sampled. At each patch and site, 3 quadrants of 45 x 45 cm were sampled for shoot and inflorescences density measurements. In each quadrant, 10 random shoots were sampled for shoot morphology (shoot height and number of leaves). Shoot and inflorescences densities were standardized to squared meters. All the studied P. oceanica meadows develop on rocks and they present a fragmented structure with a coverage ranging between ca. 45% in Calahonda and Estepona and ca. 31% in Maro. The meadows of Chullera are reduced to a few small - medium patches with areas ranging between 0.5-1.5 m2 (Fig. 1). The meadows of Chullera and Estepona presented similar values of shoot density (ca. 752 – 662 shoots m-2, respectively) and leaf height (ca. 25 cm). Similarly, the Calahonda and Maro meadows also showed similar values of shoot density (ca. 510 – 550 shoots m-2, respectively) but displaying lower values than those of sites located closer to the Strait of Gibraltar. Regarding patch sizes and leaf height, the longest leaves (ca. 25 cm) were found in medium and large patches, but the number of leaves per shoot were higher in the small and the medium size patches (ca. 6.3 leaves per shoot). Flowering was only detected at the Calahonda meadows with maximum values of ca. 330 inflorescences m-2 (115.2 ± 98.2 inflorescences m-2, n= 9; mean ± SD) (Fig.1). Inflorescence density was not significant different among patches of different sizes. In the Alboran Sea and unlike the studied meadows, extensive beds of P. oceanica occur at the National Park of Cabo de Gata (northeastern Alboran Sea), but from east to west (Strait of Gibraltar), meadows are gradually fragmenting and their depth range decrease from 30m to 2m depth between Cabo de Gata and Chullera, respectively. Probably, the Atlantic influence and the characteristic oceanographic conditions of the Alboran Sea (i.e., higher turbidity, higher water turbulence) represent a developmental limiting factor for P. oceanica at higher depths. Similarities between the meadows located closer to Strait of Gibraltar (Chullera and Estepona) were detected as well as between those more distant (Calahonda and Maro). The first ones showed higher values of shoot densities and leaf heights than the formers, which could be relating to the higher hydrodynamic exposure found at Chullera and Estepona meadows. Regarding flowering events, sexual reproduction in P. oceanica is not common in different locations of the Mediterranean Sea. The available information seems to indicate that flowering represent an irregular event and it is related to high seawater temperature. In fact, the flowering episodes that occurred in Calahonda in November 2015, match with the warmest year ever recorded. This is the third flowering event registered in these meadows located close to the westernmost distributional limit of P. oceanica (Málaga, Alboran Sea), which could indicates that these meadows presents a healthy status. Furthermore, the absence of significant differences in relation to inflorescence density between patches of different sizes may be indicating that the fragmentation does not necessarily influence on the flowering of this seagrass species