Nozzle material requirements and the status of intermetallic matrix composites

The HSCT exhaust nozzle must manage high temperature exhaust gases and pressure gradients while meeting HSCT economic and noise goals. The important features and requirements for an HSCT exhaust nozzle are shown for a 2DCD (two-dimensional convergent-divergent) design. The same requirements would apply to an axisymmetric design. Exhaust nozzle weight has an adverse effect on the overall aircraft range, payload, and engine specific fuel consumption and is therefore the primary driver for advanced exhaust nozzle materials. Because of the large airflow and pressure gradients, exhaust nozzles are extremely large and heavy when made from current materials. The use of advanced materials with higher specific strength will reduce the weight of exhaust nozzle components. In addition to the flow of high-temperature exhaust gases into the exhaust nozzle, ambient air is entrained to reduce gas exit velocities and suppress sound. This leads to components exposed to extremely high temperature gradients and, hence, high thermal stresses. Further, exhaust gases are highly oxidizing; material environmental resistance will be an important factor for long life. Several viable concepts have been identified to reduce noise through the mixture of exhaust and ambient air. Sound can be further suppressed by acoustic panels that absorb high-frequency noise

Combustor materials requirements and status of ceramic matrix composites

The HSCT combustor will be required to operate with either extremely rich or lean fuel/air ratios to reduce NO(x) emission. NASA High Speed Research (HSR) sponsored programs at Pratt & Whitney (P&W) and GE Aircraft Engines (GEAE) have been studying rich and lean burn combustor design approaches which are capable of achieving the aggressive HSCT NO(x) emission goals. In both of the combustor design approaches under study, high temperature (2400-3000 F) materials are necessary to meet the HSCT emission goals of 3-8 gm/kg. Currently available materials will not meet the projected requirements for the HSCT combustor. The development of new materials is an enabling technology for the successful introduction to service of the HSCT

Development of magnetostrictive active members for control of space structures

The goal of this Phase 2 Small Business Innovative Research (SBIR) project was to determine the technical feasibility of developing magnetostrictive active members for use as truss elements in space structures. Active members control elastic vibrations of truss-based space structures and integrate the functions of truss structure element, actively controlled actuator, and sensor. The active members must control structural motion to the sub-micron level and, for many proposed space applications, work at cryogenic temperatures. Under this program both room temperature and cryogenic temperature magnetostrictive active members were designed, fabricated, and tested. The results of these performance tests indicated that room temperature magnetostrictive actuators feature higher strain, stiffness, and force capability with lower amplifier requirements than similarly sized piezoelectric or electrostrictive active members, at the cost of higher mass. Two different cryogenic temperature magnetostrictive materials were tested at liquid nitrogen temperatures, both with larger strain capability than the room temperature magnetostrictive materials. The cryogenic active member development included the design and fabrication of a cryostat that allows operation of the cryogenic active member in a space structure testbed

A Model for Ferromagnetic Nanograins with Discrete Electronic States

We propose a simple phenomenological model for an ultrasmall ferromagnetic grain, formulated in terms of the grain's discrete energy levels. We compare the model's predictions with recent measurements of the discrete tunneling spectrum through such a grain. The model can qualitatively account for the observed features if we assume (i) that the anisotropy energy varies among different eigenstates of one grain, and (ii) that nonequilibrium spin accumulation occurs.Comment: 4 pages, 2 figure

Nonequilibrium excitations in Ferromagnetic Nanoparticles

In recent measurements of tunneling transport through individual ferromagnetic Co nanograins, Deshmukh, Gu\'eron, Ralph et al. \cite{mandar,gueron} (DGR) observed a tunneling spectrum with discrete resonances, whose spacing was much smaller than what one would expect from naive independent-electron estimates. In a previous publication, \cite{prl_kleff} we had suggested that this was a consequence of nonequilibrium excitations, and had proposed a ``minimal model'' for ferromagnetism in nanograins with a discrete excitation spectrum as a framework for analyzing the experimental data. In the present paper, we provide a detailed analysis of the properties of this model: We delineate which many-body electron states must be considered when constructing the tunneling spectrum, discuss various nonequilibrium scenarios and compare their results with the experimental data of Refs. \cite{mandar,gueron}. We show that a combination of nonequilibrium spin- and single-particle excitations can account for most of the observed features, in particular the abundance of resonances, the resonance spacing and the absence of Zeeman splitting.Comment: 13 pages, 10 figure

Sequestered Alkaloid Defenses in the Dendrobatid Poison Frog Oophaga pumilio Provide Variable Protection from Microbial Pathogens

Most amphibians produce their own defensive chemicals; however, poison frogs sequester their alkaloid-based defenses from dietary arthropods. Alkaloids function as a defense against predators, and certain types appear to inhibit microbial growth. Alkaloid defenses vary considerably among populations of poison frogs, reflecting geographic differences in availability of dietary arthropods. Consequently, environmentally driven differences in frog defenses may have significant implications regarding their protection against pathogens. While natural alkaloid mixtures in dendrobatid poison frogs have recently been shown to inhibit growth of non-pathogenic microbes, no studies have examined the effectiveness of alkaloids against microbes that infect these frogs. Herein, we examined how alkaloid defenses in the dendrobatid poison frog, Oophaga pumilio, affect growth of the known anuran pathogens Aeromonas hydrophila and Klebsiella pneumoniae. Frogs were collected from five locations throughout Costa Rica that are known to vary in their alkaloid profiles. Alkaloids were isolated from individual skins, and extracts were assayed against both pathogens. Microbe subcultures were inoculated with extracted alkaloids to create dose-response curves. Subsequent spectrophotometry and cell counting assays were used to assess growth inhibition. GC-MS was used to characterize and quantify alkaloids in frog extracts, and our results suggest that variation in alkaloid defenses lead to differences in inhibition of these pathogens. The present study provides the first evidence that alkaloid variation in a dendrobatid poison frog is associated with differences in inhibition of anuran pathogens, and offers further support that alkaloid defenses in poison frogs confer protection against both pathogens and predators

Simulation of alnico coercivity

Micromagnetic simulations of alnico show substantial deviations from Stoner-Wohlfarth behavior due to the unique size and spatial distribution of the rod-like Fe-Co phase formed during spinodal decomposition in an external magnetic field. The maximum coercivity is limited by single-rod effects, especially deviations from ellipsoidal shape, and by interactions between the rods. Both the exchange interaction between connected rods and magnetostatic interaction between rods are considered, and the results of our calculations show good agreement with recent experiments. Unlike systems dominated by magnetocrystalline anisotropy, coercivity in alnico is highly dependent on size, shape, and geometric distribution of the Fe-Co phase, all factors that can be tuned with appropriate chemistry and thermal-magnetic annealing

Nonequilibrium and Parity Effects in the Tunneling Conductance of Ultrasmall Superconducting Grains

Recent experiment on the tunneling spectra of ultrasmall superconducting grains revealed an unusual structure of the lowest differential conductance peak for grains in the odd charging states. We explain this behavior by nonequilibrium ``gapless'' excitations associated with different energy levels occupied by the unpaired electron. These excitations are generated by inelastic cotunneling.Comment: 4 pages, 2 .eps figures include