1,050 research outputs found
The influence of molecular rotation on the direct subsurface absorption of H2 on Pd(111)
Within the generalized gradient approximation (GGA) of density functional theory (DFT) we have calculated a three-dimensional (3D) potential energy surface (PES) including an angular degree of freedom for a
Evaluation of soil phosphate residues by plant uptake and extractable phosphorus
Non-Peer ReviewedResidual phosphate from fertilizer P or manure seemed to accumulate mainly as octocalcium phosphate (OCP) in 23 alkaline and calcareous soils of eastern Colorado. These soils contained 37 to 162 ppm NaHCO3-soluble P. Phosphorus removed by cropping varied between 58 and 275 ppm with 5 to 8 crops before P deficiency re-appeared. Phosphorus uptake was highly correlated with NaHCO3-soluble P (four successive extracts), resin-extractable P, and labile P by 32P isotopic dilution. All of the OCP dissolved during cropping. This material seems to have a very high availability coefficient for plants. Accumulation of fertilizer P residues in this form would appear to be beneficial since this P is potentially all available to crops. Therefore, methods for estimating the amount of OCP in soils should be useful
An assessment of key risk factors for surgical site infection in patients undergoing surgery for spinal metastases
Objectives
This study aimed to determine the rate of surgical site infection (SSI) in patients undergoing surgery for spinal metastases, and identify key risk factors for SSI among this patient group.
Methods
A retrospective case note review was undertaken in 152 adult patients being treated at a single specialist centre for spinal surgery.
Results
Overall SSI rate was 11.2% per patients (9.7% per procedure). An increase in the risk of SSI was
observed when surgery involved a greater number of vertebral levels (odds ratio 1.26, P=0.019) when controlling for primary spinal region. Controlling for the number of spinal levels, the odds of SSI increased by a factor of 5.6 (P=0.103) when the primary surgical region was thoracic, as opposed
to cervical or lumbar.
Conclusions
In conclusion, surgery associated with multiple vertebral levels for treatment of spinal metastases,
particularly of the thoracic spine, is associated with increased risk of SSI
Direct subsurface absorption of hydrogen on Pd(111): Quantum mechanical calculations on a new two-dimensional potential energy surface.
Roughness Analysis In Strained Silicon-on-insulator Wires And Films
Strained silicon is used to enhance performance in state-of-the-art CMOS. Under device operating conditions, the effect of strain is to reduce the carrier scattering at the channel by a smoother semiconductor surface. This has never been completely understood. This paper gives first evidence of the variation in surface roughness under realistic strained conditions. At the nanoscale, the SiO2/Si interface roughness is dependent on the scale of observation (self-affinity). To date, there is no experimental study of the SiO2/Si interface roughness scaling with strain. This work presents the effect of uniaxial and biaxial strains on the surface roughness of strained silicon-on-insulator films and wires using atomic force microscopy. Levels of strain ranging from 0% to 2.3%, encompassing those used in present CMOS devices have been investigated. It is shown that the silicon surface is affected by uniaxial and biaxial strains differently. Three surface roughness parameters have been analyzed: root mean square roughness, correlation length, and the Hurst exponent, which is used to describe the scaling behavior of a self-affine surface. The results show that the root mean square roughness decreases (up to ∼ 40%) with increasing tensile strain, whereas the correlation length increases (up to ∼ 63nm/%) with increasing tensile strain. The Hurst exponent also varies with strain and with the undulation wavelength regime (between ∼ 0.8 and 0.2). This dependency explains why some models used to determine the carrier mobility from experiments fit the data better with a Gaussian form, whereas other models fit the data better with an exponential form.11612EPSRC; Engineering and Physical Sciences Research CouncilSong, Y., Zhou, H., Xu, Q., Luo, J., Yin, H., Yan, J., Zhong, H., (2011) J. Electron. Mater., 40, p. 1584Lee, M.L., Fitzgerald, E.A., Bulsara, M.T., Currie, M.T., Lochtefeld, A., (2005) J. Appl. 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Characterizing Soil Fertility by Ion Diffusive Flux Measurements
The general acceptance of diffusion as a rate-limiting step in transferring ions to plant roots was considered in characterizing soil fertility. Soil ion diffusive flux measurements to an exchange resin were measured with two soil: resin cells, one with untreated soil, the other with the same soil fertilized with P, K, and Cl. The P, K, and Cl that diffused to the resin of each cell was extracted and determined. Using only these measurements and some simplifying assumptions of diffusion theory, calculations were made of the soil's P and K solution concentration, adsorbed concentration, a capacity factor, transmission factor, and quantity of fertilizer needed to attain any desired flux. Excellent to fair correlations existed between these calculated values and traditionally measured chemical quantities. Plant uptake of P and K was generally well correlated with diffusive flux measurements as well as traditional chemical measurements
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The winds of (evolutionary) change: Breathing new life into microbiology
To date, over 1500 prokaryotes have been characterized by small subunit rRNA sequencing and molecular phylogeny has had an equally profound effect on our understanding of relationship among eukaryotic microorganisms. The universal phylogenetic tree readily shows however how artificial the strong distinction between the eukaryote and prokaryotes has become. The split between the Archaea and the Bacteria is now recognized as the primary phylogenetic division and that the Eucarya have branched from the same side of the tree as the Archaea. Both prokaryotic domains would seem to be of thermophilic origin suggesting that life arose in a very warm environment. Among the Archaea, all of the Crenarchaeota cultured to date are thermophiles, and the deepest euryarchaeal branchings are represented exclusively by thermophiles. Among the Bacteria, the deepest known branchings are again represented exclusively by thermophiles, and thermophilia is widely scattered throughout the domain. The Archaea comprise a small number of quite disparate phenotypes that grow in unusual niches. All are obligate or facultative anaerobes. All cultured crenarchaeotes are thermophilic, some even growing optimally above the normal boiling temperature of water. The Archaeoglobales are sulfate reducers growing at high temperatures. The extreme halophiles grow only in highly saline environments. The methanogens are confined to a variety of anaerobic niches, often thermophilic. The Bacteria, on the other hand, are notable as being the source of life`s photosynthetic capacity. Five kingdoms of bacteria contain photosynthetic species; and each of the five manifests a distinct type of (chlorophyll-based) photosynthesis
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