Thermodynamics, transition dynamics, and texturing in polymer-dispersed liquid crystals with mesogens exhibiting a direct isotropic/smectic-A transition

Experimental and modeling/simulation studies of phase equilibrium and growth morphologies of novel polymer-dispersed liquid crystal (PDLC) mixtures of PS (polystyrene) and liquid crystals that exhibit a direct isotropic/smectic-A (lamellar) mesophase transition were performed for PS/10CB (decyl- cyanobiphenyl) and PS/12CB (dodecyl-cyanobiphenyl). Partial phase diagrams were determined using polarized optical microscopy (POM) and differential scanning calorimetry (DSC) for different compositions of both materials, determining both phase separation (liquid/liquid demixing) and phase ordering (isotropic/smectic-A transition) temperatures. The Flory-Huggins theory of isotropic mixing and Maier-Saupe-McMillan theory for smectic-A liquid crystalline ordering were used to computationally determine phase diagrams for both systems, showing good agreement with the experimental results. In addition to thermodynamic observations, growth morphology relations were found depending on phase transition sequence, quench rate, and material composition. Three stages of liquid crystal-rich domain growth morphology were observed: spherical macroscale domain growth ("stage I"), highly anisotropic domain growth ("stage II"), and sub-micron spheroid domain growth ("stage III"). Nano-scale structure of spheroidal and spherocylindrical morphologies were then determined via two-dimensional simulation of a high-order Landau-de Gennes model. Morphologies observed during stage II growth are typical of di- rect isotropic/smectic-A phase transitions, such as highly anisotropic "batonnets" and filaments. These morphologies, which are found to be persistent in direct isotropic/smectic-A PDLCs, could provide new functionality and applications for these functional materials.Comment: First Revision, 21 pages, 11 figures, submitted to Macromolecules as an article 17JUL200

Estimating Dynamic Traffic Matrices by using Viable Routing Changes

Abstract: In this paper we propose a new approach for dealing with the ill-posed nature of traffic matrix estimation. We present three solution enhancers: an algorithm for deliberately changing link weights to obtain additional information that can make the underlying linear system full rank; a cyclo-stationary model to capture both long-term and short-term traffic variability, and a method for estimating the variance of origin-destination (OD) flows. We show how these three elements can be combined into a comprehensive traffic matrix estimation procedure that dramatically reduces the errors compared to existing methods. We demonstrate that our variance estimates can be used to identify the elephant OD flows, and we thus propose a variant of our algorithm that addresses the problem of estimating only the heavy flows in a traffic matrix. One of our key findings is that by focusing only on heavy flows, we can simplify the measurement and estimation procedure so as to render it more practical. Although there is a tradeoff between practicality and accuracy, we find that increasing the rank is so helpful that we can nevertheless keep the average errors consistently below the 10% carrier target error rate. We validate the effectiveness of our methodology and the intuition behind it using commercial traffic matrix data from Sprint's Tier-1 backbon

Sleep and protein synthesis-dependent synaptic plasticity: impacts of sleep loss and stress

Sleep has been ascribed a critical role in cognitive functioning. Several lines of evidence implicate sleep in the consolidation of synaptic plasticity and long-term memory. Stress disrupts sleep while impairing synaptic plasticity and cognitive performance. Here, we discuss evidence linking sleep to mechanisms of protein synthesis-dependent synaptic plasticity and synaptic scaling. We then consider how disruption of sleep by acute and chronic stress may impair these mechanisms and degrade sleep function

Design charts relating to the stalling of tapered wings

An aid in airplane design, charts have been prepared to show the effects of wing taper, thickness ratio, and Reynolds number on the spanwise location of the initial stalling point. Means of improving poor stalling characteristics resulting from certain combinations of the variables have also been considered; additional figures illustrate the influence of camber increase to the wing tips, washout, central sharp leading edges, and wing-tip slots on the stalling characteristics. Data are included from which the drag increases resulting from the use of these means can be computed. The application of the data to a specific problem is illustrated by an example

Fighting the social media wildfire: how crisis communication must adapt to prevent from fanning the flames

When a nine-month correspondence seeking reparations for musical instruments damaged by United Airlines employees stalemated, Canadian musician Dave Carroll took action online. Utilizing the video-sharing Web site YouTube, Carroll narrated his ordeal through the lyrics of a music video entitled United Breaks Guitars. Within hours, the video went viral generating a torrent of negative YouTube comments about United, commentary from the mainstream media, and more than 3 million views the first week of its launch. United Breaks Guitars embodies the new phenomenon of a social media wildfire in which the rapid proliferation of information through social media causes severe reputational damage to organizations whose crisis communication plans are ill equipped to handle online dilemmas. Using symbolic interactionist theory, this case analysis explores the phenomenon in detail and provides suggestions for how organizations must re-evaluate existing crisis communication plans to respond effectively to an online audience in the billions