9,186 research outputs found
Radicals, Metals and Magnetism
The interaction between unpaired electrons governs many physical properties of materials. Although in a fundamental sense the interaction is simple, a full understanding of the interaction in molecular systems is complicated by the presence of other bonding and non-bonding electrons. The resulting many body problem is very challenging. Nevertheless, much qualitative understanding can be obtained from applying simple molecular orbital theory and considering only the partly filled orbitals. The resulting model can be used to describe existing diradical and metal-radical systems and also has predicative value in the search for molecular magnets and design of nanoscale devices
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Developing and sustaining a Community of Practice through Twitter for work-based learning
A revised parameterization for gaseous dry deposition in air-quality models
International audienceA parameterization scheme for calculating gaseous dry deposition velocities in air-quality models is revised based on recent study results on non-stomatal uptake of O3 and SO2 over 5 different vegetation types. Non-stomatal resistance, which includes in-canopy aerodynamic resistance, soil resistance and cuticle resistance, for SO2 and O3 is parameterized as a function of friction velocity, relative humidity, leaf area index, and canopy wetness. Non-stomatal resistance for all other species is scaled to those of SO2 and O3 based on their chemical and physical characteristics. Stomatal resistance is calculated using a leaf-stomatal-resistance model for all gaseous species of interest. The improvements in the present model compared to its earlier version include a newly developed non-stomatal resistance formulation, a realistic treatment of cuticle and ground resistance in winter and the handling of seasonally-dependent input parameters. Model evaluation shows that the revised parameterization can provide more realistic deposition velocities for both O3 and SO2, especially for wet canopies. Example model output shows that the parameterization provides reasonable estimates of dry deposition velocities for different gaseous species, land types and diurnal and seasonal variations. Maximum deposition velocities from model output are close to reported measurement values for different land types. The current parameterization can be easily adopted into different air-quality models that require inclusion of dry deposition processes
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Characteristics of successful interventions to reduce turnover and increase retention of early career nurses: a systematic review
Background
nurse shortages have been identified as central to workforce issues in healthcare systems globally and although interventions to increase the nursing workforce have been implemented, nurses leaving their roles, particularly in the first year after qualification, present a significant barrier to building the nurse workforce.
Objective
to evaluate the characteristics of successful interventions to promote retention and reduce turnover of early career nurses.
Design
this is a systematic review
Data sources
Online databases including Academic Search Complete, Medline, Health Policy reference Centre, EMBASE, Psychinfo, CINAHL and the Cochran Library were searched to identify relevant publications in English published between 2001 and April 2018. Studies included evaluated an intervention to increase retention or reduce turnover and used turnover or retention figures as a measure.
Review methods
The review was conducted according to the Preferred Reporting Items for Systematic Reviews and Meta-analyses (PRISMA) guidelines. Studies were quality-assessed using the Joanna Briggs Institute Critical Appraisal tools for Quasi Experimental and Randomised Controlled Trials. Retention/turnover data were used to guide the comparison between studies and appropriate measures of central tendency and dispersion were calculated and presented, based on the normality of the data.
Results
A total of 11, 656 papers were identified, of which 53 were eligible studies. A wide variety of interventions and components within those interventions were identified to improve nurse retention. Promising interventions appear to be either internship/residency programmes or orientation/transition to practice programmes, lasting between 27-52 weeks, with a teaching and preceptor and mentor component.
Conclusions
Methodological issues impacted on the extent to which conclusions could be drawn, even though a large number of studies were identified. Future research should focus on standardising the reporting of interventions and outcome measures used to evaluate these interventions and carrying out further research with rigorous methodology. Clinical practice areas are recommended to assess their current interventions against the identified criteria to guide development of their effectiveness. Evaluations of cost-effectiveness are considered an important next step to maximise return on investment
Volcanic smog and cardiometabolic health: Hawaiian hypertension?
Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/149349/1/jch13500.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/149349/2/jch13500_am.pd
A Comparison of Risk Exposure in Aquaculture and Agricultural Businesses
Agriculture and aquaculture have common features associated with their biological nature affecting risk exposure of the businesses. The aim of this paper is to compare risk exposure in salmon farming and agricultural enterprises in Norway by using an implicit error component model to examine the risk structure of yields, prices and economic returns at the farm level. Results indicate a higher farm-level year-to-year variability in yields, prices and economic returns in salmon farming than in agricultural enterprises. The variability in livestock enterprises was generally lower than for crop enterprises. Return on assets was highest in salmon farming with an average annual return of 9.2%. All of the agricultural farm types exhibited a negative average return on assets on average. Stochastic dominance tests of the distribution of economic returns from aquaculture and agricultural farm types showed salmon farming to be the most risk efficient alternative and salmon farming was most attractive from an investor’s perspective.Risk analysis, variability, Norway, Risk and Uncertainty,
Nighttime observations of thunderstorm electrical activity from a high altitude airplane
Nocturnal thunderstorms were observed from above and features of cloud structure and lightning which are not generally visible from the ground are discussed. Most, lightning activity seems to be associated with clouds with strong convective cauliflower tops. In both of the storms lightning channels were visible in the clear air above the cloud. It is shown that substances produced by thunderstorm electrical discharges can be introduced directly into the stratosphere. The cause and nature of the discharges above the cloud are not clear. They may be produced by accumulations of space charge in the clear air above the cloud. The discharges may arise solely because of the intense electric fields produced by charges within the cloud. In the latter case the ions introduced by these discharges will increase the electrical conductivity of the air above the cloud and increase the conduction current that flows from the cloud to the electrosphere. More quantitative data at higher resolution may show significant spectral differences between cloud to ground and intracloud strokes. It is shown that electric field change data taken with an electric field change meter mounted in an airplane provide data on lightning discharges from above that are quite similar to those obtained from the ground in the past. The optical signals from dart leaders, from return strokes, and from continuing currents are recognizable, can be used to provide information on the fine structure of lightning, and can be used to distinguish between cloud to ground and intracloud flashes
Hierarchical formation of bulgeless galaxies II: Redistribution of angular momentum via galactic fountains
Within a fully cosmological hydrodynamical simulation, we form a galaxy which
rotates at 140 km/s, and is characterised by two loose spiral arms and a bar,
indicative of a Hubble Type SBc/d galaxy. We show that our simulated galaxy has
no classical bulge, with a pure disc profile at z=1, well after the major
merging activity has ended. A long-lived bar subsequently forms, resulting in
the formation of a secularly-formed "pseudo" bulge, with the final
bulge-to-total light ratio B/T=0.21. We show that the majority of gas which
loses angular momentum and falls to the central region of the galaxy during the
merging epoch is blown back into the hot halo, with much of it returning later
to form stars in the disc. We propose that this mechanism of redistribution of
angular momentum via a galactic fountain, when coupled with the results from
our previous study which showed why gas outflows are biased to have low angular
momentum, can solve the angular momentum/bulgeless disc problem of the cold
dark matter paradigm.Comment: 9 Pages, 10 Figures, accepted MNRAS version. Comments welcom
Sound and fury? The impact of councillors’ LTN positions on voting behaviour in Greater London
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