18,109 research outputs found
Aerosol scattering of ultraviolet sunlight in the tropical maritime atmosphere
The effects of atmospheric aerosol scattering on the vertical profile of solar ultraviolet radiation are investigated. Measurements of diffuse and total ultraviolet radiation were made using a rocketborne optical sonde in the marine atmosphere of Antigua. During observations, the sun was at zenith. Vertical profiles of directly transmitted solar radiation were calculated by subtraction of the diffuse component from the total radiance. Using these values of direct downward solar UV-flux, the optical thickness of the atmosphere was derived as a function of altitude. Absorption by ozone was also considered. In the troposphere the values of observed optical thickness were in general equal to or lower than those expected theoretically from Rayleigh scattering alone. The measured radiation profiles were compared with those computed for a multiple scattering model atmosphere. Some computations regarding the interaction of UV-sunlight with maritime aerosols are presented
Soft-tissue specimens from pre-European extinct birds of New Zealand
We provide the first complete review of soft tissue remains from New Zealand birds that became extinct prior to European settlement (c. AD 1800). These rare specimens allow insights into the anatomy and appearance of the birds that are not attainable from bones. Our review includes previously unpublished records of ‘lost’ specimens, and descriptions of recently discovered specimens such as the first evidence of soft tissues from the South Island goose (Cnemiornis calcitrans). Overall, the soft tissue remains are dominated by moa (with specimens from each of the six genera), but also include specimens from Finsch's duck (Chenonetta finschi) and the New Zealand owlet-nightjar (Aegotheles novaezealandiae). All desiccated soft tissue specimens that have radiocarbon or stratigraphic dates are late Holocene in age, and most have been found in the semi-arid region of Central Otago
Clustering as an example of optimizing arbitrarily chosen objective functions
This paper is a reflection upon a common practice of solving various types of learning problems by optimizing arbitrarily chosen criteria in the hope that they are well correlated with the criterion actually used for assessment of the results. This issue has been investigated using clustering as an example, hence a unified view of clustering as an optimization problem is first proposed, stemming from the belief that typical design choices in clustering, like the number of clusters or similarity measure can be, and often are suboptimal, also from the point of view of clustering quality measures later used for algorithm comparison and ranking. In order to illustrate our point we propose a generalized clustering framework and provide a proof-of-concept using standard benchmark datasets and two popular clustering methods for comparison
A position sensitive phoswich hard X-ray detector system
A prototype position sensitive phoswich hard X-ray detector, designed for eventual astronomical usage, was tested in the laboratory. The scintillation crystal geometry was designed on the basis of a Monte Carlo simulation of the internal optics and includes a 3mm thick NaI(T1) primary X-ray detector which is actively shielded by a 20 mm thick CsI(T1) scintillation crystal. This phoswich arrangement is viewed by a number two inch photomultipliers. Measured values of the positional and spectral resolution of incident X-ray photons are compared with calculation
The nebular spectra of SN 2012aw and constraints on stellar nucleosynthesis from oxygen emission lines
We present nebular phase optical and near-infrared spectroscopy of the Type
IIP supernova SN 2012aw combined with NLTE radiative transfer calculations
applied to ejecta from stellar evolution/explosion models. Our spectral
synthesis models generally show good agreement with the ejecta from a MZAMS =
15 Msun progenitor star. The emission lines of oxygen, sodium, and magnesium
are all consistent with the nucleosynthesis in a progenitor in the 14 - 18 Msun
range. We also demonstrate how the evolution of the oxygen cooling lines of [O
I] 5577 A, [O I] 6300 A, and [O I] 6364 A can be used to constrain the mass of
oxygen in the non-molecularly cooled ashes to < 1 Msun, independent of the
mixing in the ejecta. This constraint implies that any progenitor model of
initial mass greater than 20 Msun would be difficult to reconcile with the
observed line strengths. A stellar progenitor of around MZAMS = 15 Msun can
consistently explain the directly measured luminosity of the progenitor star,
the observed nebular spectra, and the inferred pre-supernova mass-loss rate. We
conclude that there is still no convincing example of a Type IIP explosion
showing the nucleosynthesis expected from a MZAMS > 20 Msun progenitor.Comment: Accepted for publication in MNRA
Thermal Desorption of Water-Ice in the Interstellar Medium
Water (H2O) ice is an important solid constituent of many astrophysical
environments. To comprehend the role of such ices in the chemistry and
evolution of dense molecular clouds and comets, it is necessary to understand
the freeze-out, potential surface reactivity, and desorption mechanisms of such
molecular systems. Consequently, there is a real need from within the
astronomical modelling community for accurate empirical molecular data
pertaining to these processes. Here we give the first results of a laboratory
programme to provide such data. Measurements of the thermal desorption of H2O
ice, under interstellar conditions, are presented. For ice deposited under
conditions that realistically mimic those in a dense molecular cloud, the
thermal desorption of thin films (~50 molecular layers) is found to occur with
zero order kinetics characterised by a surface binding energy, E_{des}, of 5773
+/- 60 K, and a pre-exponential factor, A, of 10^(30 +/- 2) molecules cm^-2
s^-1. These results imply that, in the dense interstellar medium, thermal
desorption of H2O ice will occur at significantly higher temperatures than has
previously been assumed.Comment: 9 pages, 4 figures, accepted for publication in MNRA
Free energy barrier for molecular motions in bistable [2]rotaxane molecular electronic devices
Donor−acceptor binding of the π-electron-poor cyclophane cyclobis(paraquat-p-phenylene) (CBPQT^(4+)) with the π-electron-rich tetrathiafulvalene (TTF) and 1,5-dioxynaphthalene (DNP) stations provides the basis for electrochemically switchable, bistable [2]rotaxanes, which have been incorporated and operated within solid-state devices to form ultradense memory circuits (ChemPhysChem 2002, 3, 519−525; Nature 2007, 445, 414−417) and nanoelectromechanical systems. The rate of CBPQT^(4+) shuttling at each oxidation state of the [2]rotaxane dictates critical write-and-retention time parameters within the devices, which can be tuned through chemical synthesis. To validate how well computational chemistry methods can estimate these rates for use in designing new devices, we used molecular dynamics simulations to calculate the free energy barrier for the shuttling of the CBPQT^4+ ring between the TTF and the DNP. The approach used here was to calculate the potential of mean force along the switching pathway, from which we calculated free energy barriers. These calculations find a turn-on time after the rotaxane is doubly oxidized of ~10^9−7) s (suggesting that the much longer experimental turn-on time is determined by the time scale of oxidization). The return barrier from the DNP to the TTF leads to a predicted lifetime of 2.1 s, which is compatible with experiments
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Inferential models: A framework for prior-free posterior probabilistic inference
Posterior probabilistic statistical inference without priors is an important
but so far elusive goal. Fisher's fiducial inference, Dempster-Shafer theory of
belief functions, and Bayesian inference with default priors are attempts to
achieve this goal but, to date, none has given a completely satisfactory
picture. This paper presents a new framework for probabilistic inference, based
on inferential models (IMs), which not only provides data-dependent
probabilistic measures of uncertainty about the unknown parameter, but does so
with an automatic long-run frequency calibration property. The key to this new
approach is the identification of an unobservable auxiliary variable associated
with observable data and unknown parameter, and the prediction of this
auxiliary variable with a random set before conditioning on data. Here we
present a three-step IM construction, and prove a frequency-calibration
property of the IM's belief function under mild conditions. A corresponding
optimality theory is developed, which helps to resolve the non-uniqueness
issue. Several examples are presented to illustrate this new approach.Comment: 29 pages with 3 figures. Main text is the same as the published
version. Appendix B is an addition, not in the published version, that
contains some corrections and extensions of two of the main theorem
Selective Use of Pericardial Window and Drainage as Sole Treatment for Hemopericardium from Penetrating Chest Trauma
Background
Penetrating cardiac injuries (PCIs) are highly lethal, and a sternotomy is considered mandatory for suspected PCI. Recent literature suggests pericardial window (PCW) may be sufficient for superficial cardiac injuries to drain hemopericardium and assess for continued bleeding and instability. This study objective is to review patients with PCI managed with sternotomy and PCW and compare outcomes.
Methods
All patients with penetrating chest trauma from 2000 to 2016 requiring PCW or sternotomy were reviewed. Data were collected for patients who had PCW for hemopericardium managed with only pericardial drain, or underwent sternotomy for cardiac injuries grade 1–3 according to the American Association for the Surgery of Trauma (AAST) Cardiac Organ Injury Scale (OIS). The PCW+drain group was compared with the Sternotomy group using Fisher’s exact and Wilcoxon rank-sum test with P\u3c0.05 considered statistically significant.
Results
Sternotomy was performed in 57 patients for suspected PCI, including 7 with AAST OIS grade 1–3 injuries (Sternotomy group). Four patients had pericardial injuries, three had partial thickness cardiac injuries, two of which were suture-repaired. Average blood drained was 285mL (100–500 mL). PCW was performed in 37 patients, and 21 had hemopericardium; 16 patients proceeded to sternotomy and 5 were treated with pericardial drainage (PCW+drain group). All PCW+drain patients had suction evacuation of hemopericardium, pericardial lavage, and verified bleeding cessation, followed by pericardial drain placement and admission to intensive care unit (ICU). Average blood drained was 240mL (40–600 mL), and pericardial drains were removed on postoperative day 3.6 (2–5). There was no significant difference in demographics, injury mechanism, Revised Trauma Score exploratory laparotomies, hospital or ICU length of stay, or ventilator days. No in-hospital mortality occurred in either group.
Conclusions
Hemodynamically stable patients with penetrating chest trauma and hemopericardium may be safely managed with PCW, lavage and drainage with documented cessation of bleeding, and postoperative ICU monitoring.
Level of evidence
Therapeutic study, level IV
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