124 research outputs found
X-ray Dichroism and the Pseudogap Phase of Cuprates
A recent polarized x-ray absorption experiment on the high temperature
cuprate superconductor Bi2Sr2CaCu2O8 indicates the presence of broken parity
symmetry below the temperature, T*, where a pseudogap appears in photoemission.
We critically analyze the x-ray data, and conclude that a parity-breaking
signal of the kind suggested is unlikely based on the crystal structures
reported in the literature. Possible other origins of the observed dichroism
signal are discussed. We propose x-ray scattering experiments that can be done
in order to determine whether such alternative interpretations are valid or
not.Comment: final version to be published in Phys Rev B: some calculational
details added, clarification of XNLD contamination and biaxiality, more
discussion on possible space groups and previous optics result
The chemistry of La on the Si(001) surface
This paper reports state-of-the-art electronic structure calculations of La
adsorption on the Si(001) surface. We predict La chains in the low coverage
limit, which condense in a stable phase at a coverage of 1/5 monolayer. At 1/3
monolayer we predict a chemically rather inert, stable phase. La changes its
oxidation state from La(3+) at lower coverages to La(2+) at coverages beyond
1/3 monolayer. In the latter oxidation state, one electron resides in a state
with a considerable contribution from La-d and f states.Comment: 10 pages, 13 figures, 3 table
Large Low Temperature Magnetoresistance and Magnetic Anomalies in TbPdSi and DyPdSi
The results of heat-capacity, magnetic susceptibility, electrical resistivity
and magnetoresistance measurements on the compounds
TbPdSi and DyPdSi, are reported. The results establish that
these compounds undergo long-range magnetic ordering (presumably with a complex
magnetic structure) below (Tc=) 23 and 8 K respectively. The is negative in the vicinity of Tc and the magnitude grows as Tc is approached
from higher temperature as in the case of well-known giant magnetoresistance
systems (La manganite based perovskites); this is attributed to the formation
of some kind of magnetic polarons. The magnitude of magnetoresistance at low
temperatures is quite large, for instance, about 30% in the presence of 60 kOe
field at 5 K in the Dy sample.Comment: 4 pages, 3 figures, RevTe
First-principle solubilities of alkali and alkaline earth metals in Mg-B alloys
By devising a novel framework, we present a comprehensive theoretical study
of solubilities of alkali (Li, Na, K, Rb, Cs) and alkaline earth (Be, Ca, Sr,
Ba) metals in the he boron-rich Mg-B system. The study is based on
first-principle calculations of solutes formation energies in MgB, MgB,
MgB alloys and subsequent statistical-thermodynamical evaluation of
solubilities. The advantage of the approach consists in considering all the
known phase boundaries in the ternary phase diagram. Substitutional Na, Ca, and
Li demonstrate the largest solubilities, and Na has the highest (0.5-1 % in
MgB at K). All the considered interstitials have negligible
solubilities. The solubility of Be in MgB can not be determined because the
corresponding low-solubility formation energy is negative indicating the
existence of an unknown ternary ground state. We have performed a
high-throughput search of ground states in binary Mg-B, Mg-, and B-
systems, and we construct the ternary phase diagrams of Mg-B- alloys based
on the stable binary phases. Despite its high temperature observations, we find
that SrMg is not a low-temperature equilibrium structure. We also
determine two new possible ground states CaB and RbB, not yet
observed experimentally.Comment: 5 figure
Magnetic behaviour of Eu_2CuSi_3: Large negative magnetoresistance above Curie temperature
We report here the results of magnetic susceptibility,
electrical-resistivity, magnetoresistance (MR), heat-capacity and ^{151}Eu
Mossbauer effect measurements on the compound, Eu_2CuSi_3, crystallizing in an
AlB_2-derived hexagonal structure. The results establish that Eu ions are
divalent, undergoing long-range ferromagnetic-ordering below (T_C=) 37 K. An
interesting observation is that the sign of MR is negative even at temperatures
close to 3T_C, with increasing magnitude with decreasing temperature exhibiting
a peak at T_C. This observation, being made for a Cu containing magnetic
rare-earth compound for the first time, is of relevance to the field of
collosal magnetoresistance.Comment: To appear in PRB, RevTex, 4 pages text + 6 psFigs. Related to our
earlier work on Gd systems (see cond-mat/9811382, cond-mat/9811387,
cond-mat/9812069, cond-mat/9812365
Crystal Structure of the Compound Er3Cu4.8Ga6.2.
Рентгенівським методом полікристалу (дифрактометр ДРОН-3М, проміння Сu Ka) визначено кристалічну
структуру сполуки Er3Cu4,8Ga6,2: структурний тип La3Al11, символ Пірсона oI28, просторова група Immm,
a = 4,14849(5), b = 12,2345(2), c = 9,7185(1) Å, RI = 0,0819; Rp = 0,1292. У структурі можна виділити пари
атомів Купруму (dCu-Cu = 2,367 Å), орієнтовані вздовж [010], і нескінченні стрічки з квадратів атомів Галію
(dGa1-Ga2 = 2,765 Å), що простягаються вздовж [100]. The crystal structure of the compound Er 3Cu4,8Ga6,2 (structure type La3Al11, Pearson
symbol oI28, space group Immm, a = 4.14849(5), b = 12.2345(2), c = 9.7185(1) Å, RI = 0.0819; Rp = 0.1292) was
determined based on X-ray powder diffraction data. In the structure Cu-atom dumbbells ( dCu-Cu = 2.367 Å) oriented
along [010] and infinite chains of Ga-atom squares ( dGa1-Ga2 = 2.765 Å) running along [100] can be emphasized
Physical origin of the buckling in CuO: Electron-phonon coupling and Raman spectra
It is shown theoretically that the buckling of the CuO planes in
certain cuprate systems can be explained in terms of an electric field across
the planes which originates from different valences of atoms above and below
the plane. This field results also in a strong coupling of the Raman-active
out-of-phase vibration of the oxygen atoms ( mode) to the electronic
charge transfer between the two oxygens in the CuO plane. Consequently,
the electric field can be deduced from the Fano-type line shape of the
phonon. Using the electric field estimated from the electron-phonon coupling
the amplitude of the buckling is calculated and found to be in good agreement
with the structural data. Direct experimental support for the idea proposed is
obtained in studies of YBaCuO and
BiSr(CaY)CuO with different oxygen and
yttrium doping, respectively, including antiferromagnetic samples. In the
latter compound, symmetry breaking by replacing Ca partially by Y leads to an
enhancement of the electron-phonon coupling by an order of magnitude.Comment: 12 pages, 4 figures, and 1 tabl
Carrier relaxation, pseudogap, and superconducting gap in high-Tc cuprates: A Raman scattering study
We describe results of electronic Raman-scattering experiments in differently
doped single crystals of Y-123 and Bi-2212. The comparison of AF insulating and
metallic samples suggests that at least the low-energy part of the spectra
originates predominantly from excitations of free carriers. We therefore
propose an analysis of the data in terms of a memory function approach.
Dynamical scattering rates and mass-enhancement factors for the carriers are
obtained. In B2g symmetry the Raman data compare well to the results obtained
from ordinary and optical transport. For underdoped materials the dc scattering
rates in B1g symmetry become temperature independent and considerably larger
than in B2g symmetry. This increasing anisotropy is accompanied by a loss of
spectral weight in B2g symmetry in the range between the superconducting
transition at Tc and a characteristic temperature T* of order room temperature
which compares well with the pseudogap temperature found in other experiments.
The energy range affected by the pseudogap is doping and temperature
independent. The integrated spectral loss is approximately 25% in underdoped
samples and becomes much weaker towards higher carrier concentration. In
underdoped samples, superconductivity related features in the spectra can be
observed only in B2g symmetry. The peak frequencies scale with Tc. We do not
find a direct relation between the pseudogap and the superconducting gap.Comment: RevTeX, 21 pages, 24 gif figures. For PostScript with embedded eps
figures, see http://www.wmi.badw-muenchen.de/~opel/k2.htm
Nanocrystalline and Thin Film Germanium Electrodes with High Lithium Capacity and High Rate Capabilities
STM imaging of symmetry-breaking structural distortion in the Bi-based cuprate superconductors
A complicating factor in unraveling the theory of high-temperature (high-Tc)
superconductivity is the presence of a "pseudogap" in the density of states,
whose origin has been debated since its discovery [1]. Some believe the
pseudogap is a broken symmetry state distinct from superconductivity [2-4],
while others believe it arises from short-range correlations without symmetry
breaking [5,6]. A number of broken symmetries have been imaged and identified
with the pseudogap state [7,8], but it remains crucial to disentangle any
electronic symmetry breaking from pre-existing structural symmetry of the
crystal. We use scanning tunneling microscopy (STM) to observe an orthorhombic
structural distortion across the cuprate superconducting Bi2Sr2Can-1CunO2n+4+x
(BSCCO) family tree, which breaks two-dimensional inversion symmetry in the
surface BiO layer. Although this inversion symmetry breaking structure can
impact electronic measurements, we show from its insensitivity to temperature,
magnetic field, and doping, that it cannot be the long-sought pseudogap state.
To detect this picometer-scale variation in lattice structure, we have
implemented a new algorithm which will serve as a powerful tool in the search
for broken symmetry electronic states in cuprates, as well as in other
materials.Comment: 4 figure
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