Viscosity and tribology of copper oxide nanofluids

Nanofluids, a term proposed by Choi in 1995 [1], are composites consisting of solid nanoparticles with sizes varying generally from 1 to 100 nm dispersed in a liquid. Numerous nanoparticles used as oil additives have been investigated in recent years [2-7]. Results show that they deposit on the rubbing surface and improve the tribological properties of the base oil, displaying good friction and wear reduction characteristics even at concentrations below 2%wt. Although the viscosity of the nanofluids is a property of crucial importance for film forming, and hence friction and wear reduction, which are characteristic of lubricants, only Hwang et al. [8] have studied thermal characteristics, kinematic viscosity and tribological properties of nanofluids simultaneously. In this paper, we present measurements of dynamic viscosity of nanofluids formed by copper oxide nanoparticles dispersed in a polyalphaolefin, for temperatures and concentrations varying from 20 to 60ºC and 0.5 to 2% wt., respectively. Dependence of the nanofluid viscosity to the solid fraction and temperature was compared with existing models and its influence on lubrication was also analysed

Tomography of high-redshift clusters with OSIRIS

High-redshift clusters of galaxies are amongst the largest cosmic structures. Their properties and evolution are key ingredients to our understanding of cosmology: to study the growth of structure from the inhomogeneities of the cosmic microwave background; the processes of galaxy formation, evolution, and differentiation; and to measure the cosmological parameters (through their interaction with the geometry of the universe, the age estimates of their component galaxies, or the measurement of the amount of matter locked in their potential wells). However, not much is yet known about the properties of clusters at redshifts of cosmological interest. We propose here a radically new method to study large samples of cluster galaxies using microslits to perform spectroscopy of huge numbers of objects in single fields in a narrow spectral range-chosen to fit an emission line at the cluster redshift. Our objective is to obtain spectroscopy in a very restricted wavelength range (~100 A in width) of several thousands of objects for each single 8x8 square arcmin field. Approximately 100 of them will be identified as cluster emission-line objects and will yield basic measurements of the dynamics and the star formation in the cluster (that figure applies to a cluster at z~0.50, and becomes ~40 and ~20 for clusters at z~0.75 and z~1.00 respectively). This is a pioneering approach that, once proven, will be followed in combination with photometric redshift techniques and applied to other astrophysical problems.Comment: 4 pages, 3 figures. Proceedings of "Science with the GTC", Granada (Spain), February 2002, RMxAA in pres

Corrosion activity and solubility in polar oils of three bis(trifluoromethylsulfonyl) imide/bis(trifluoromethylsulfonyl) amide ([NTF2]) anion-based ionic liquids.

The corrosion behaviour and solubility of three bis(trifluoromethylsulfonyl)amide1 ([NTf2]) anion-based ionic liquids: 1-dodecyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([C12MIM][NTf2]), tributylmethylammonium bis(trifluoromethylsulfonyl)amide ([N4441][NTf2]), and methyltrioctylammonium bis(trifluoromethylsulfonyl)amide ([N1888][NTf2]), as a component in a mixture with different base oils were analysed. Six polar oils suitable for use in lubrication were utilized as base oil. Solubility tests were performed by using turbidimetry, and corrosion was checked at 4 v/v% by examining the roughness and chemical composition of the surface after 21 days. The results showed that long carbon chains in the cation improve the solubility greatly in diesters and slightly in polyolesters. Corrosion was not detected at this concentration

Crystal structure of cobalt hydroxide carbonate Co2CO3(OH)(2): density functional theory and X-ray diffraction investigation

The cobalt carbonate hydroxide Co2CO3(OH)2 is a technologically important solid which is used as a precursor for the synthesis of cobalt oxides in a wide range of applications. It also has relevance as a potential immobilizer of the toxic element cobalt in the natural environment, but its detailed crystal structure is so far unknown. The structure of Co2CO3(OH)2 has now been investigated using density functional theory (DFT) simulations and powder X-ray diffraction (PXRD) measurements on samples synthesized via deposition from aqueous solution. Two possible monoclinic phases are considered, with closely related but symmetrically different crystal structures, based on those of the minerals malachite [Cu2CO3(OH)2] and rosasite [Cu1.5Zn0.5CO3(OH)2], as well as an orthorhombic phase that can be seen as a common parent structure for the two monoclinic phases, and a triclinic phase with the structure of the mineral kolwezite [Cu1.34Co0.66CO3(OH)2]. The DFT simulations predict that the rosasite-like and malachite-like phases are two different local minima of the potential energy landscape for Co2CO3(OH)2 and are practically degenerate in energy, while the orthorhombic and triclinic structures are unstable and experience barrierless transformations to the malachite phase upon relaxation. The best fit to the PXRD data is obtained using a rosasite model [monoclinic with space group P1121/n and cell parameters a = 3.1408 (4) Å, b = 12.2914 (17) Å, c = 9.3311 (16) Å and γ = 82.299 (16)°]. However, some features of the PXRD pattern are still not well accounted for by this refinement and the residual parameters are relatively poor. The relationship between the rosasite and malachite phases of Co2CO3(OH)2 is discussed and it is shown that they can be seen as polytypes. Based on the similar calculated stabilities of these two polytypes, it is speculated that some level of stacking disorder could account for the poor fit of the PXRD data. The possibility that Co2CO3(OH)2 could crystallize, under different growth conditions, as either rosasite or malachite, or even as a stacking-disordered phase intermediate between the two, requires further investigation

Language and cultural awareness of a non-native ESP teacher

Introduction. The relation between culture and language is a central issue in foreign language teaching and research where the need to give cultural content the same value as language content and language skills has been stressed. However, conceptualization of teacher language awareness, by focusing largely on formal aspects of language, largely neglects culture as a component of teacher cognition. This paper expands the category of ESP-teacher language awareness suggesting the inclusion of cultural awareness as a separate component of teacher cognition. This concept extension actualizes ESP teaching in the situation shaped by unprecedented mobility and intercultural contacts. Materials and Methods. The historic-logical method was used to determine shortcomings of pedagogical experience and the need to teach culture in ESP. Grounded theory, as an inductive methodology, was utilized to generate conceptual expansion theoretically tied with research in medical and business communication as well as with data on population movement and international scientific cooperation. Results. We defined ESP-cultural knowledge as a system comprising the permanent (know-that) and temporary (know-of) cultural manifestations in a society as well as how they are manifested through language (know-how). That system practical representation is exemplified in medicine and business English discourse. The study expands the structure of ESP-TLA, claiming the focus on cultural awareness as part of ESP discourse which fosters cultural-response education. Discussion and Conclusion. Such claim is pertinent to practitioners involved in the tourism industry, health care, economics, and academic activities such as research and development. This paper is relevant for teachers of English for Specific purposes in the fields mentioned above as well as for researchers engaged in analyzing the problems and methods of teaching a foreign language. However, because of the multiple manifestations and complexity of student motivation to get ESP course, the paper acknowledges the difficulties in addressing cultural content salient to all students in class, an aspect meriting further research. © 2019 National Research Ogarev Mordovia State University. All rights reserved.This research was financially supported by the Russian Foundation for Basic Research (Grant No. 17-29-09136/18 «Multilingualism in the era of post-literacy: Philosophical and cultural studies and methodological and pedagogical development of a multilingual education model»).Российский Фонд Фундаментальных Исследований (РФФИ): 17-29-09136/1

Microstructure Evolution During Powder Compaction

The process of powder compaction consists of the synthesis of loose powders into a solid material. The applications of compaction of granular systems extend to pharmaceuticals, detergents, food, ceramic and metallurgical processes. It is indispensable to have a thorough understanding of the behavior of confined granular systems during compaction because the performance of the final desired product is related to the microstructural features that develop during the compaction process. To have a more realistic description of the compaction, it is also important to include the packing process of granular systems. However, there are different particle packing algorithms that account for the particle filling process. The Discrete Element Method (DEM) had been used to obtain a dynamic solution to this problem but requires high computational power. As an alternative to the computationally expensive DEM approach, a static based algorithm has recently been developed for the modelling and simulation of the particle packing process. The algorithm allows for the modelling of the packing process by placing spheres inside different shapes and sizes of containers. In this study, we present a new version of the nanoHUB Powder Compaction tool. It currently simulates the microstructure evolution of monodisperse, compressible granular systems up to high relative densities. The tool also models the plastic and elastic deformation of single particles described by different contact mechanics models. The new features use a general particle packing algorithm and thus allow the user to choose a particle size distribution in a specified range for the mean, standard deviation and number of particles to fill the die. The information is passed to the solver that in turn simulates the compaction in Purdue’s high-performance computer cluster

Lubrication performance of an ammonium cation-based ionic liquid used as an additive in a polar oil.

This paper studies the tribological behavior of the ionic liquid methyltrioctylammonium bis(trifluoromethylsulfonyl)imide ([N 1888 ][NTf 2 ]) as additive at different concentrations (1.25, 2.50, 3.75 and 5.00 wt%) in a polar base oil (diester). A tribometer using a ball-on-disk reciprocating configuration under fully flooded lubrication was used at a frequency of 15 Hz, at three different loads (40, 80 and 120 N), stroke length of 4 mm, and duration of 45 min. Worn surface on the disk was studied by confocal microscopy, SEM and XPS. Main results showed similar coefficient of friction for all lubricant samples; but different wear results were found at different loads, probably related with the chemical states found for fluorine on the worn surface and the temperature-dependent adsorption-desorption processes

The Effect of Conservation Agriculture and Environmental Factors on CO2 Emissions in a Rainfed Crop Rotation

There are many factors involved in the release of CO2 emissions from the soil, such as the type of soil management, the soil organic matter, the soil temperature and moisture conditions, crop phenological stage, weather conditions, residue management, among others. This study aimed to analyse the influence of these factors and their interactions to determine the emissions by evaluating the environmental cost expressed as the kg of CO2 emitted per kg of production in each of the crops and seasons studied. For this purpose, a field trial was conducted on a farm in Seville (Spain). The study compared Conservation Agriculture, including its three principles (no-tillage, permanent soil cover, and crop rotations), with conventional tillage. Carbon dioxide emissions measured across the four seasons of the experiment showed an increase strongly influenced by rainfall during the vegetative period, in both soil management systems. The results of this study confirm that extreme events of precipitation away from the normal means, result in episodes of high CO2 emissions into the atmosphere. This is very important because one of the consequences for future scenarios of climate change is precisely the increase of extreme episodes of precipitation and periods extremely dry, depending on the area considered. The total of emission values of the different plots of the study show how the soils under the conventional system (tillage) have been emitting 67% more than soils under the conventional agriculture system during the 2010/11 campaign and 25% for the last campaign where the most appreciable differences are observed