Nuclear magnetic resonance spectroscopy: Abnormal splitting of ethyl groups due to molecular asymmetry

Nuclear magnetic resonance (n.m.r.) spectroscopy provides an excellent means for qualitative identification of ethyl groups by use of the familiar three-four pattern of spin-spin splitting (1). It has been observed previously (2) that the methylene protons of systems of the type R-CH2-CR1R2R3 (where R1 can be the same as R or different) may be magnetically nonequivalent and display AB rather than A2-type spectra (3). We now wish to report several examples of this type of behavior with ethyl groups, particularly ethoxy groups, knowledge of which could be important to anyone using n.m.r. for organic qualitative analysis

A large scale height galactic component of the diffuse 2-60 keV background

The diffuse 2-60 keV X-ray background has a galactic component clearly detectable by its strong variation with both galactic latitude and longitude. This galactic component is typically 10 percent of the extragalactic background toward the galactic center, half that strong toward the anticenter, and extrapolated to a few percent of the extragalactic background toward the galactic poles. It is acceptably modeled by a finite radius emission disk with a scale height of several kiloparsecs. The averaged galactic spectrum is best fitted by a thermal spectrum of kT about 9 keV, a spectrum much softer than the about 40 keV spectrum of the extragalactic component. The most likely source of this emission is low luminosity stars with large scale heights such as subdwarfs. Inverse Compton emission from GeV electrons on the microwave background contributes only a fraction of the galactic component unless the local cosmic ray electron spectrum and intensity are atypical

Comparison of the COBE FIRAS and DIRBE Calibrations

We compare the independent FIRAS and DIRBE observations from the COBE in the wavelength range 100-300 microns. This cross calibration provides checks of both data sets. The results show that the data sets are consistent within the estimated gain and offset uncertainties of the two instruments. They show the possibility of improving the gain and offset determination of DIRBE at 140 and 240 microns.Comment: Accepted for publication in the Astrophysical Journal 11 pages, plus 3 figures in separate postscript files. Figure 3 has three part

Measuring Molecular, Neutral Atomic, and Warm Ionized Galactic Gas Through X-Ray Absorption

We study the column densities of neutral atomic, molecular, and warm ionized Galactic gas through their continuous absorption of extragalactic X-ray spectra at |b| > 25 degrees. For N(H,21cm) < 5x10^20 cm^-2 there is an extremely tight relationship between N(H,21cm) and the X-ray absorption column, N(xray), with a mean ratio along 26 lines of sight of N(xray)/N(H,21cm) = 0.972 +- 0.022. This is significantly less than the anticpated ratio of 1.23, which would occur if He were half He I and half He II in the warm ionized component. We suggest that the ionized component out of the plane is highly ionized, with He being mainly He II and He III. In the limiting case that H is entirely HI, we place an upper limit on the He abundance in the ISM of He/H <= 0.103. At column densities N(xray) > 5x10^20 cm^-2, which occurs at our lower latitudes, the X-ray absorption column N(xray) is nearly double N(H,21cm). This excess column cannot be due to the warm ionized component, even if He were entirely He I, so it must be due to a molecular component. This result implies that for lines of sight out of the plane with |b| ~ 30 degrees, molecular gas is common and with a column density comprable to N(H,21cm). This work bears upon the far infrared background, since a warm ionized component, anticorrelated with N(H,21cm), might produce such a background. Not only is such an anticorrelation absent, but if the dust is destroyed in the warm ionized gas, the far infrared background may be slightly larger than that deduced by Puget et al. (1996).Comment: 1 AASTeX file, 14 PostScript figure files which are linked within the TeX fil

Are state laws granting pharmacists authority to vaccinate associated with HPV vaccination rates among adolescents?

We explored whether state laws allowing pharmacists to administer human papillomavirus (HPV) vaccinations to adolescents are associated with a higher likelihood of HPV vaccine uptake

Anytime Algorithms for Solving Possibilistic MDPs and Hybrid MDPs

The ability of an agent to make quick, rational decisions in an uncertain environment is paramount for its applicability in realistic settings. Markov Decision Processes (MDP) provide such a framework, but can only model uncertainty that can be expressed as probabilities. Possibilistic counterparts of MDPs allow to model imprecise beliefs, yet they cannot accurately represent probabilistic sources of uncertainty and they lack the efficient online solvers found in the probabilistic MDP community. In this paper we advance the state of the art in three important ways. Firstly, we propose the first online planner for possibilistic MDP by adapting the Monte-Carlo Tree Search (MCTS) algorithm. A key component is the development of efficient search structures to sample possibility distributions based on the DPY transformation as introduced by Dubois, Prade, and Yager. Secondly, we introduce a hybrid MDP model that allows us to express both possibilistic and probabilistic uncertainty, where the hybrid model is a proper extension of both probabilistic and possibilistic MDPs. Thirdly, we demonstrate that MCTS algorithms can readily be applied to solve such hybrid models. © Springer International Publishing Switzerland 2016.This work is partially funded by EPSRC PACES project (Ref: EP/J012149/1).Peer Reviewe