Correlation of Kondo effect and molecular conformation of the acceptor molecule in the TTF-TCNE charge transfer complex

A Kondo resonance has been observed on purely organic molecules in several combinations of charge transfer complexes on a metal surface. It has been regarded as a fingerprint of the transfer of one electron from the donor to the extended π orbital of the acceptor's LUMO. Here, we investigate the stoichiometric checkerboard structure of tetrathiafulvalene (TTF) and tetracyanoethylene (TCNE) on a Au(1 1 1) surface using scanning tunneling and atomic force microscopy at 4.8 K. We find a bistable state of the TCNE molecules with distinct structural and electronic properties. The two states represent different conformations of the TCNE within the structure. One of them exhibits a Kondo resonance, whereas the other one does not, despite of both TCNE types being singly charged

Structural Examination of Au/Ge(001) by Surface X-Ray Diffraction and Scanning Tunneling Microscopy

The one-dimensional reconstruction of Au/Ge(001) was investigated by means of autocorrelation functions from surface x-ray diffraction (SXRD) and scanning tunneling microscopy (STM). Interatomic distances found in the SXRD-Patterson map are substantiated by results from STM. The Au coverage, recently determined to be 3/4 of a monolayer of gold, together with SXRD leads to three non-equivalent positions for Au within the c(8x2) unit cell. Combined with structural information from STM topography and line profiling, two building blocks are identified: Au-Ge hetero-dimers within the top wire architecture and Au homo-dimers within the trenches. The incorporation of both components is discussed using density functional theory and model based Patterson maps by substituting Germanium atoms of the reconstructed Ge(001) surface.Comment: 5 pages, 3 figure

Phased array transducer for billet inspection

A phased array transducer design for billet inspection is presented. The transducer sweeps a uniform focus in both depth and angle to assure uniform coverage of the billet volume, particularly at the billet center, where coverage depends critically on transducer alignment. Design concepts are presented which enable the transducer to sweep a tight focus in both depth and angle using 63 discrete time delays. Design concepts and specifications are summarized, and experimental verification of design performance is presented. Data acquisition protocols are discussed enabling the phased array inspection to operate at production speeds

Length-Independent Voltage Fluctuations in Small Devices

Conductance fluctuations in one-dimensional lines of length L shorter than the phase-coherence length Lφ are not universal but diverge as L-2. Using the Onsager relations and voltage additivity, we show that the voltage fluctuations are independent of the distance between voltage probes. The antisymmetric (Hall-type) contribution to the voltage fluctuations is constant for all values of L. Measurements of the voltage fluctuations and correlation function between different regions in Au and Sb lines confirm these results

Temperature Dependence of the Normal-Metal Aharonov-Bohm Effect

The amplitude of h/e periodic oscillations in the magnetoresistance of very small normal-metal (Au) rings, as well as the harmonic h/2e, have been studied as a function of temperature. The amplitudes depend on the temperature T roughly as T-1/2, as expected from the averaging of conduction channels in the absence of inelastic scattering, but may not be entirely consistent with this model. At the lowest T, the size of the fluctuations in the conductance is about ΔG∼e2/h, as predicted recently

Ferromagnetic coupling of mononuclear Fe centers in a self-assembled metal-organic network on Au(111)

The magnetic state and magnetic coupling of individual atoms in nanoscale structures relies on a delicate balance between different interactions with the atomic-scale surrounding. Using scanning tunneling microscopy, we resolve the self-assembled formation of highly ordered bilayer structures of Fe atoms and organic linker molecules (T4PT) when deposited on a Au(111) surface. The Fe atoms are encaged in a three-dimensional coordination motif by three T4PT molecules in the surface plane and an additional T4PT unit on top. Within this crystal field, the Fe atoms retain a magnetic ground state with easy-axis anisotropy, as evidenced by X-ray absorption spectroscopy and X-ray magnetic circular dichroism. The magnetization curves reveal the existence of ferromagnetic coupling between the Fe centers

Site-selective adsorption of naphthalene-tetracarboxylic-dianhydride on Ag(110): First-principles calculations

The mechanism of adsorption of the 1,4,5,8-naphthalene-tetracarboxylic-dianhydride (NTCDA) molecule on the Ag(110) surface is elucidated on the basis of extensive density functional theory calculations. This molecule, together with its perylene counterpart, PTCDA, are archetype organic semiconductors investigated experimentally over the past 20 years. We find that the bonding of the molecule to the substrate is highly site-selective, being determined by electron transfer to the LUMO of the molecule and local electrostatic attraction between negatively charged carboxyl oxygens and positively charged silver atoms in [1-10] atomic rows. The adsorption energy in the most stable site is 0.9eV. A similar mechanism is expected to govern the adsorption of PTCDA on Ag(110) as well.Comment: 8 pages, 4 figures, high-quality figures available upon reques

Asymmetry in the Magnetoconductance of Metal Wires and Loops

Universal conductance fluctuations in wires and Aharonov-Bohm oscillations in loops are not symmetric about H=0. The observation of asymmetry in the periodic oscillations is possible when the phase-coherence length of the wave function is comparable to the separation of the voltage probes. In both cases, four-probe measurements yield resistances which depend on lead configuration. The asymmetries appear like Hall voltages, and are consistent with Onsager\u27s relations

Direct Observation of Ensemble Averaging of the Aharonov-Bohm Effect in Normal-Metal Loops

Aharonov-Bohm magnetoconductance oscillations have been measured in series arrays of 1, 3, 10, and 30 submicron-diameter Ag loops. At constant temperature, the amplitude of the h/e oscillations is observed to decrease as the square root of number of loops, while the amplitude of h/2e conductance oscillations, measured in the same samples, is independent of the number of series loops. This is direct confirmation of the ensemble averaging properties of h/e oscillations in multiloop systems. The amplitude of the h/e oscillations is in good agreement with recent calculations

Directional statistics and filtering using libDirectional

In this paper, we present libDirectional, a MATLAB library for directional statistics and directional estimation. It supports a variety of commonly used distributions on the unit circle, such as the von Mises, wrapped normal, and wrapped Cauchy distributions. Furthermore, various distributions on higher-dimensional manifolds such as the unit hypersphere and the hypertorus are available. Based on these distributions, several recursive filtering algorithms in libDirectional allow estimation on these manifolds. The functionality is implemented in a clear, well-documented, and object-oriented structure that is both easy to use and easy to extend