Ice sheets as a significant source of highly reactive nanoparticulate iron to the oceans

The Greenland and Antarctic Ice Sheets cover ~\n10% of global land surface, but are rarely considered as active components of the global iron cycle. The ocean waters around both ice sheets harbour highly productive coastal ecosystems, many of which are iron limited. Measurements of iron concentrations in subglacial runoff from a large Greenland Ice Sheet catchment reveal the potential for globally significant export of labile iron fractions to the near-coastal euphotic zone. We estimate that the flux of bioavailable iron associated with glacial runoff is 0.40–2.54?Tg per year in Greenland and 0.06–0.17?Tg per year in Antarctica. Iron fluxes are dominated by a highly reactive and potentially bioavailable nanoparticulate suspended sediment fraction, similar to that identified in Antarctic icebergs. Estimates of labile iron fluxes in meltwater are comparable with aeolian dust fluxes to the oceans surrounding Greenland and Antarctica, and are similarly expected to increase in a warming climate with enhanced melting

Inelastic neutron scattering studies of the quantum frustrated magnet clinoatacamite, γ\gamma-Cu2(OD)3Cl, a proposed valence bond solid (VBS)

The frustrated magnet clinoatacamite, $\gamma$-Cu$_2$(OH)$_3$Cl, is attracting a lot of interest after suggestions that at low temperature it forms an exotic quantum state termed a Valence Bond Solid (VBS) made from dimerised Cu$^{2+}$ ($S=1/2$) spins.\cite{Lee_clinoatacamite} Key to the arguments surrounding this proposal were suggestions that the kagom\'e planes in the magnetic pyrochlore lattice of clinoatacamite are only weakly coupled, causing the system to behave as a quasi-2-dimensional magnet. This was reasoned from the near 95$^\circ$ angles made at the bridging oxygens that mediate exchange between the Cu ions that link the kagom\'e planes. Recent work pointed out that this exchange model is inappropriate for $\gamma$-Cu$_2$(OH)$_3$Cl, where the oxygen is present as a $\mu_3$-OH.\cite{Wills_JPC} Further, it used symmetry calculations and neutron powder diffraction to show that the low temperature magnetic structure ($T<6$ K) was canted and involved significant spin ordering on all the Cu$^{2+}$ spins, which is incompatible with the interpretation of simultaneous VBS and N\'eel ordering. Correspondingly, clinoatacamite is best considered a distorted pyrochlore magnet. In this report we show detailed inelastic neutron scattering spectra and revisit the responses of this frustrated quantum magnet.Comment: Proceedings of The International Conference on Highly Frustrated Magnetism 2008 (HFM2008

Ab Initio Calculations of the Walls Shear Strength of Carbon Nanotubes

The dependence of the energy of interwall interaction in double-walled carbon nanotubes (DWNT) on the relative position of walls has been calculated using the density functional method. This dependence is used to evaluate forces that are necessary for the relative telescopic motion of walls and to calculate the shear strength of DWNT for the relative sliding of walls along the nanotube axis and for their relative rotation about this axis. The possibility of experimental verification of the obtained results is discussed.Comment: 4 pages, 1 figur

Broadband optical measurement of AC magnetic susceptibility of magnetite nanoparticles

This is the author accepted manuscript. The final version is available from AIP Publishing via the DOI in this recordCharacterization of magnetic nanoparticles in solution is challenging due to the interplay between magnetic relaxation and agglomeration. The AC magnetic susceptibility of magnetite nanoparticles in water has been studied using magneto-optical methods in the frequency range of 10 Hz–250 kHz. The Faraday effect is detected simultaneously with changes in the fluid configuration. It is shown that the relative sensitivity to the magnetic and structural response can be adjusted by varying the wavelength, paving the way toward spatially resolved studies at the micro-scaleEngineering and Physical Sciences Research Council (EPSRC

Effect of H on the crystalline and magnetic structures of the YCo3-H(D) system. I. YCo3 from neutron powder diffraction and first-principles calculations

This paper reports investigations into the influence of hydrogen on the magnetic properties of the YCo3-H system. We report results on the magnetic structure and magnetic transitions of YCo3 using a combination of neutron powder diffraction measurements and first-principles full potential augmented plane wave + local orbital calculations under the generalized gradient approximation. The ferromagnetic and ferrimagnetic structures are examined on an equal footing. However, we identify that, no matter which structure is used as the starting point, the neutron diffraction data always refines down to the ferrimagnetic structure with the Co2 atoms having antiparallel spins. In the ab initio calculations, the inclusion of spin-orbit coupling is found to be important in the prediction of the correct magnetic ground state. Here, the results suggest that, for zero external field and sufficiently low temperatures, the spin arrangement of YCo3 is ferrimagnetic rather than ferromagnetic as previously believed. The fixed spin moment calculation technique has been employed to understand the two successive field-induced magnetic transitions observed in previous magnetization measurements under increasing ultrahigh magnetic fields. We find that the magnetic transitions start from the ferrimagnetic phase �0.61�B/Co� and terminate with the ferromagnetic phase �1.16�B/Co�, while the spin on the Co2 atoms progressively changes from antiparallel ferrimagnetic to paramagnetic and then to ferromagnetic. Our neutron diffraction measurements, ab initio calculations, and the high field magnetization measurements are thus entirely self-consistent

Stochastic Modelling Approach to the Incubation Time of Prionic Diseases

Transmissible spongiform encephalopathies like the bovine spongiform encephalopathy (BSE) and the Creutzfeldt-Jakob disease (CJD) in humans are neurodegenerative diseases for which prions are the attributed pathogenic agents. A widely accepted theory assumes that prion replication is due to a direct interaction between the pathologic (PrPsc) form and the host encoded (PrPc) conformation, in a kind of an autocatalytic process. Here we show that the overall features of the incubation time of prion diseases are readily obtained if the prion reaction is described by a simple mean-field model. An analytical expression for the incubation time distribution then follows by associating the rate constant to a stochastic variable log normally distributed. The incubation time distribution is then also shown to be log normal and fits the observed BSE data very well. The basic ideas of the theoretical model are then incorporated in a cellular automata model. The computer simulation results yield the correct BSE incubation time distribution at low densities of the host encoded protein

Detection of prion protein in the cerebrospinal fluid of elk (\u3ci\u3eCervus canadensis nelsoni\u3c/i\u3e) with chronic wasting disease using protein misfolding cyclic amplification

Cerebrospinal fluid (CSF) has been examined as a possible source for preclinical diagnosis of prion diseases in hamsters and sheep. The present report describes the detection of chronic wasting disease (CWD) in the CSF of elk and evaluates its usefulness as an antemortem test for CWD. The CSF from 6 captive and 31 free-ranging adult elk was collected at necropsy and evaluated for the presence of the abnormal isoform of the prion protein that has been associated with CWD (PrPCWD) via protein misfolding cyclic amplification. Additionally, the obex from each animal was examined by immunohistochemistry (IHC). Four out of 6 captive animals were CWD-positive and euthanized due to signs of terminal CWD. The remaining 2 were CWD negative. None of the 31 free-range animals showed overt signs of CWD, but 12 out of 31 tested positive for CWD by IHC. Protein misfolding cyclic amplification detected PrPCWD from 3 of the 4 captive animals showing clinical signs of CWD and none of the nonclinical animals that were CWD positive by IHC. The data suggests that CWD prions can be detected in the CSF of elk, but only relatively late in the course of the disease

On the weak confinement of kinks in the one-dimensional quantum ferromagnet CoNb2O6

In a recent paper Coldea et al (2010 Science {\bf 327} 177) report observation of the weak confinement of kinks in the Ising spin chain ferromagnet CoNb2O6 at low temperatures. To interpret the entire spectra of magnetic excitations measured via neutron scattering, they introduce a phenomenological model, which takes into account only the two-kink configurations of the spin chain. We present the exact solution of this model. The explicit expressions for the two-kink bound-state energy spectra and for the relative intensities of neutron scattering on these magnetic modes are obtained in terms of the Bessel function.Comment: 18 pages, 9 figures; v2: figures 1,3,4 replaced, few misprints correcte

Dear Carnegie Hall [app]

The "Dear Carnegie Hall" app is part of a celebratory program of commissions, events, and digital projects to mark the 125th anniversary of Carnegie Hall in 2015–2016. Using image-recognition technology combined with augmented reality and interactive videos, any one of a series of postcards activates the magic of the "Dear Carnegie Hall" app that presents 12 stories as told by members of the Carnegie Hall family. Enjoy personal tales and beautiful graphics that reveal many unexpected aspects of the Carnegie Hall experience, and embrace its past, present, and future. Features include: - Augmented reality videos that tell 12 personal stories of Carnegie Hall, accessed when you scan one of our “Dear Carnegie Hall” postcards. - Exclusive interviews with Susan Graham, Nico Muhly, and many more. - Stories about The Beatles, Frank Sinatra, performance, dreams, and ghosts - Material from the Carnegie Hall Archives presented via engaging animations. - A gallery where you can play the videos directly through the app. - The option to record your own story or memory of Carnegie Hall, link it to a photo and send your digital postcard to a friend and Carnegie Hall