3,380 research outputs found
Aspects of planar, oblique and interacting shock waves in an ideal dissociating gas
We develop a compact dimensionless framework for the analysis of canonical thermo-chemical nonequilibrium flow fields involving normal, oblique and interacting shock waves. Discontinuous solutions of the conservation equations are coupled with thermodynamic and kinetic models for an ideal dissociating gas. Convenient forms are provided for the variation of the relevant dimensionless parameters across shock waves in dissociating gases. The treatment is carried through in a consistent manner for the pressure–flow deflection angle plane representation of shock wave interaction problems. The contribution of the current paper is a careful nondimensionalization of the problem that yields a tractable formulation and allows results with considerable generality to be obtained
The influence of non-equilibrium dissociation on the flow produced by shock impingement on a blunt body
We describe an investigation of the effects of non-equilibrium thermochemistry on the interaction between a weak oblique shock and the strong bow shock formed by a blunt body in hypersonic flow. This type of shock-on-shock interaction, also known as an Edney type IV interaction, causes locally intense enhancement of the surface heat transfer rate. A supersonic jet is formed by the nonlinear interaction that occurs between the two shock waves and elevated heat transfer rates and surface pressures are produced by the impingement of the supersonic jet on the body. The current paper is motivated by previous studies suggesting that real gas effects would significantly increase the severity of the phenomenon.
Experiments are described in which a free-piston shock tunnel is used to produce shock interaction flows with significant gas dissociation. Surprisingly, the data that are obtained show no significant stagnation enthalpy dependence of the ratio of the peak heat transfer rates with and without shock interaction, in contrast to existing belief. The geometry investigated is the nominally two-dimensional flow about a cylinder with coplanar impinging shock wave. Holographic interferometry is used to visualize the flow field and to quantify increases in the stagnation density caused by shock interaction. Time-resolved heat transfer measurements are obtained from surface junction thermocouples about the model forebody.
An improved model is developed to elucidate the finite-rate thermochemical processes occurring in the interaction region. It is shown that severe heat transfer intensification is a result of a jet shock structure that minimizes the entropy rise of the supersonic jet fluid whereas strong thermochemical effects are promoted by conditions that maximize the entropy rise (and hence temperature). This dichotomy underlies the smaller than anticipated influence of real gas effects on the heat transfer intensification. The model accurately predicts the measured heat transfer rates. Improved understanding of the influence of real gas effects on the shock interaction phenomenon reduces a significant element of risk in the design of hypersonic vehicles. The peak heat transfer rate for the Edney type IV interaction is shown to be well-correlated, in the weak impinging shock regime, by an expression of the form [equation] for use in practical design calculations
Estudo dos efeitos da radiação ultravioleta nas propriedades termogravimétricas de amido de mandioca oxidado por hipoclorito de sódio.
Resumo
Modification of the simple mass balance equation for calculation of critical loads of acidity.
Over the last few years, the simple mass balance equation for the calculation of critical loads of acidity has been gradually modified as the underlying critical load concepts have developed and as problems with particular forms of the equation have been identified, through application in particular countries. The first major update of the equation took place following a workshop held in Vienna, Austria (Hojesky et al. 1993). The workshop was held to discuss problems which had been identified when the then current form of the equation was applied in countries with high rainfall. The problems had largely arisen because of simplifications and assumptions incorporated into the early formulation of the equation. The equation was reformulated to overcome the problems identified at the workshop. However, further problems were identified when the reformulated equation was applied in the UK in situations with a combination of high rainfall, large marine inputs and widespread occurrence of organic soils. A small workshop was, therefore held in Grange-over-Sands, UK in late 1993 to dicuss the problems and to further re-evaluate the equation. The problems had arisen in the UK because of simplifications and assumptions made in the formulation concerning, in particular, cation leaching and uptake. As a result, a more rigorous treatment of these variables was incorporated into the equation. The reformulation of the equation, as derived at the September 1993 workshop is described below
TG-DTA and DSC investigations of ''pinhão'' starch modified by calcium hypochlorite and UV light.
Starches, when in its native forms, usually do not have the characteristics required for industrial processing. ''Pinhão'', a seed from the Araucaria angustifolia tree, has starch as main presenting as a great alternative source of starch. Samples of native ''pinhão'' starch were treated with standard calcium hypochlorite solutions (0.1, 0.2 and 0.5 mol L-1) and exposed for one hour under UV light. The modification process applied altered the thermal behavior of the ''pinhão'' starch as the TGA-DTA and DSC results presented.Edição dos Anais do 7º Simpósio de Análise Térmica, 2015, Bauru
Induced effects of oxidation with potassium permanganate in the modification of corn starch.
CBRATEC
Near-inertial wave scattering by random flows
The impact of a turbulent flow on wind-driven oceanic near-inertial waves is
examined using a linearised shallow-water model of the mixed layer. Modelling
the flow as a homogeneous and stationary random process with spatial scales
comparable to the wavelengths, we derive a transport (or kinetic) equation
governing wave-energy transfers in both physical and spectral spaces. This
equation describes the scattering of the waves by the flow which results in a
redistribution of energy between waves with the same frequency (or,
equivalently, with the same wavenumber) and, for isotropic flows, in the
isotropisation of the wave field. The time scales for the scattering and
isotropisation are obtained explicitly and found to be of the order of tens of
days for typical oceanic parameters. The predictions inferred from the
transport equation are confirmed by a series of numerical simulations.
Two situations in which near-inertial waves are strongly influenced by flow
scattering are investigated through dedicated nonlinear shallow-water
simulations. In the first, a wavepacket propagating equatorwards as a result
from the -effect is shown to be slowed down and dispersed both zonally
and meridionally by scattering. In the second, waves generated by moving
cyclones are shown to be strongly disturbed by scattering, leading again to an
increased dispersion.Comment: Accepted for publication in Phys. Rev. Fluid
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