1,136 research outputs found
SO2 oxidation in supercooled droplets in the presence of O2
Sulphur dioxide oxidation in supercooled monodisperse droplets at T4213 7C was studied in the presence of oxygen. The SO2 concentration was found to range from 0.08 to 7.1 ppmv and the contact time between gases and droplets was
210 s. The experimental results showed that sulphate concentration due to SO2 oxidation is independent of temperature, i.e. the increase of SO2 solubility in the
liquid phase balances the rate constant decrease of the oxidation reaction. Following McKay’s kinetics (Atmos. Environ., 5 (1971) 7), we calculated the rate constant at
T4213 7C and the activation energy. A comparison was made between experimental S(VI) oxidation concentrations due to oxygen and theoretical oxidation values due to O3, H2O2 and oxygen in the presence of catalyzers (Fe31, Mn21)
Internal-strain mediated coupling between polar Bi and magnetic Mn ions in the defect-free quadruple-perovskite BiMnMnO
By means of neutron powder diffraction, we investigated the effect of the
polar Bi ion on the magnetic ordering of the Mn ions in
BiMnMnO, the counterpart with \textit{quadruple} perovskite
structure of the \textit{simple} perovskite BiMnO. The data are consistent
with a \textit{noncentrosymmetric} spacegroup which contrasts the
\textit{centrosymmetric} one previously reported for the isovalent and
isomorphic compound LaMnMnO, which gives evidence of a
Bi-induced polarization of the lattice. At low temperature, the two
Mn sublattices of the and sites order antiferromagnetically
(AFM) in an independent manner at 25 and 55 K, similarly to the case of
LaMnMnO. However, both magnetic structures of
BiMnMnO radically differ from those of LaMnMnO.
In BiMnMnO the moments of the sites form
an anti-body AFM structure, whilst the moments \textbf{M} of the
sites result from a large and \textit{uniform} modulation along the b-axis of the moments \textbf{M} in the
-plane. The modulation is strikingly correlated with the displacements of
the Mn ions induced by the Bi ions. Our analysis unveils a strong
magnetoelastic coupling between the internal strain created by the Bi
ions and the moment of the Mn ions in the sites. This is ascribed to
the high symmetry of the oxygen sites and to the absence of oxygen defects, two
characteristics of quadruple perovskites not found in simple ones, which
prevent the release of the Bi-induced strain through distortions or
disorder. This demonstrates the possibility of a large magnetoelectric coupling
in proper ferroelectrics and suggests a novel concept of internal strain
engineering for multiferroics design.Comment: 9 pages, 7 figures, 5 table
Feedback cooling of the normal modes of a massive electromechanical system to submillikelvin temperature
We apply a feedback cooling technique to simultaneously cool the three
electromechanical normal modes of the ton-scale resonant-bar gravitational wave
detector AURIGA. The measuring system is based on a dc Superconducting Quantum
Interference Device (SQUID) amplifier, and the feedback cooling is applied
electronically to the input circuit of the SQUID. Starting from a bath
temperature of 4.2 K, we achieve a minimum temperature of 0.17 mK for the
coolest normal mode. The same technique, implemented in a dedicated experiment
at subkelvin bath temperature and with a quantum limited SQUID, could allow to
approach the quantum ground state of a kilogram-scale mechanical resonator.Comment: 4 pages, 4 figure
Integrin-Targeting Dye-Doped PEG-Shell/Silica-Core Nanoparticles Mimicking the Proapoptotic Smac/DIABLO Protein
Cancer cells demonstrate elevated expression levels of the inhibitor of apoptosis proteins (IAPs), contributing to tumor cell survival, disease progression, chemo-resistance, and poor prognosis. Smac/DIABLO is a mitochondrial protein that promotes apoptosis by neutralizing members of the IAP family. Herein, we describe the preparation and in vitro validation of a synthetic mimic of Smac/DIABLO, based on fluorescent polyethylene glycol (PEG)-coated silica-core nanoparticles (NPs) carrying a Smac/DIABLO-derived pro-apoptotic peptide and a tumor-homing integrin peptide ligand. At low \u3bcM concentration, the NPs showed significant toxicity towards A549, U373, and HeLa cancer cells and modest toxicity towards other integrin-expressing cells, correlated with integrin-mediated cell uptake and consequent highly increased levels of apoptotic activity, without perturbing cells not expressing the \u3b15 integrin subunit
Networks of gravitational wave detectors and three figures of merit
This paper develops a general framework for studying the effectiveness of
networks of interferometric gravitational wave detectors and then uses it to
show that enlarging the existing LIGO-VIRGO network with one or more planned or
proposed detectors in Japan (LCGT), Australia, and India brings major benefits,
including much larger detection rate increases than previously thought... I
show that there is a universal probability distribution function (pdf) for
detected SNR values, which implies that the most likely SNR value of the first
detected event will be 1.26 times the search threshold. For binary systems, I
also derive the universal pdf for detected values of the orbital inclination,
taking into account the Malmquist bias; this implies that the number of
gamma-ray bursts associated with detected binary coalescences should be 3.4
times larger than expected from just the beaming fraction of the gamma burst.
Using network antenna patterns, I propose three figures of merit that
characterize the relative performance of different networks... Adding {\em any}
new site to the planned LIGO-VIRGO network can dramatically increase, by
factors of 2 to 4, the detected event rate by allowing coherent data analysis
to reduce the spurious instrumental coincident background. Moving one of the
LIGO detectors to Australia additionally improves direction-finding by a factor
of 4 or more. Adding LCGT to the original LIGO-VIRGO network not only improves
direction-finding but will further increase the detection rate over the
extra-site gain by factors of almost 2, partly by improving the network duty
cycle... Enlarged advanced networks could look forward to detecting three to
four hundred neutron star binary coalescences per year.Comment: 38 pages, 7 figures, 2 tables. Accepted for publication in Classical
and Quantum Gravit
In vitro evaluation of the inhibitory activity of different selenium chemical forms on the growth of a fusarium proliferatum strain isolated from rice seedlings
In this study, the in vitro effects of different Se concentrations (5, 10, 15, 20, and 100 mg kg−1) from different Se forms (sodium selenite, sodium selenate, selenomethionine, and selenocystine) on the development of a Fusarium proliferatum strain isolated from rice were investigated. A concentration‐dependent effect was detected. Se reduced fungal growth starting from 10 mg kg−1 and increasing the concentration (15, 20, and 100 mg kg−1 ) enhanced the inhibitory effect. Se bioactivity was also chemical form dependent. Selenocystine was found to be the most effective at the lowest concentration (5 mg kg−1 ). Complete growth inhibition was observed at 20 mg kg−1 of Se from selenite, selenomethionine, and selenocystine. Se speciation analysis revealed that fungus was able to change the Se speciation when the lowest Se concentration was applied. Scanning Electron Microscopy showed an alteration of the fungal morphology induced by Se. Considering that the inorganic forms have a higher solubility in water and are cheaper than organic forms, 20 mg kg−1 of Se from selenite can be suggested as the best combination suitable to inhibit F. proliferatum strain. The addition of low concentrations of Se from selenite to conventional fungicides may be a promising alternative approach for the control of Fusarium species
Testing of optimal filters for gravitational wave signals: An experimental implementation
We have implemented likelihood testing of the performance of an optimal filter within the online analysis of AURIGA, a sub-Kelvin resonant-bar gravitational wave detector. We demonstrate the effectiveness of this technique in discriminating between impulsive mechanical excitations of the resonant-bar and other spurious excitations. This technique also ensures the accuracy of the estimated parameters such as the signal-to-noise ratio. The efficiency of the technique to deal with non-stationary noise and its application to data from a network of detectors are also discussed
Global regularity criterion for the 3D Navier-Stokes equations involving one entry of the velocity gradient tensor
In this paper we provide a sufficient condition, in terms of only one of the
nine entries of the gradient tensor, i.e., the Jacobian matrix of the velocity
vector field, for the global regularity of strong solutions to the
three-dimensional Navier-Stokes equations in the whole space, as well as for
the case of periodic boundary conditions
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