Complicated variations of early optical afterglow of GRB 090726

We report on a detection of an early rising phase of optical afterglow (OA) of a long GRB 090726. We resolve a complicated profile of the optical light curve. We also investigate the relation of the optical and X-ray emission of this event. We make use of the optical photometry of this OA obtained by the 0.5 m telescope of AI AS CR, supplemented by the data obtained by other observers, and the X-ray Swift/XRT data. The optical emission peaked at ~ 17.5 mag (R) at t-T0 ~ 500 s. We find a complex profile of the light curve during the early phase of this OA: an approximately power-law rise, a rapid transition to a plateau, a weak flare superimposed on the center of this plateau, and a slowly steepening early decline followed by a power-law decay. We discuss several possibilities to explain the short flare on the flat top of the optical light curve at t-T0 ~ 500 s; activity of the central engine is favored although reverse shock cannot be ruled out. We show that power-law outflow with Theta_obs/Theta_c > 2.5 is the best case for OA of GRB 090726. The initial Lorentz factor is Gamma_0 ~ 230-530 in case of propagation of the blast wave in a homogeneous medium, while propagation of this wave in a wind environment gives Gamma_0 ~ 80-300. The value of Gamma_0 in GRB 090726 thus falls into the lower half of the range observed in GRBs and it may even lie on the lower end. We also show that both the optical and X-ray emission decayed simultaneously and that the spectral profile from X-ray to the optical band did not vary. This OA belongs to the least luminous ones in the phase of its power-law decay corresponding to that observed for the ensemble of OAs of long GRBs.Comment: 5 pages, 5 figures, accepted to A&

Short-term streambed drying events alter amphipod population structure in a central European stream

Temporary streams are becoming increasingly common, but ecological responses to streambed drying are poorly characterized in the temperate continental region of central Europe. In addition, global research has focused on community responses to drying, whereas effects on individual populations remain unknown. We explored the population structure of Gammarus fossarum (Crustacea: Amphipoda) in a central European temporary stream. Benthic gammarids were sampled on five dates during a flow recession, one date between two drying events (of 10 and 20 days, respectively), and five dates after flow resumed. Additional benthic samples were taken from isolated pools and dry sediments during drying events, and freeze cores were collected to compare the vertical distribution of amphipods during wet and dry phases. Gammarids were measured, adults distinguished from juveniles, adults sexed, and female reproductive state determined. Densities increased during flow recession, potentially reflecting both a decline in submerged habitat availability and seasonal increases in juvenile abundance. Persistence within dry benthic sediments was minimal, whereas pools and saturated subsurface sediments supported high population densities. Juveniles comprised 80 % of the subsurface population, suggesting that their ability to inhabit small interstices promotes persistence within the dry reach. Juveniles also comprised 92 % of pool inhabitants, despite their potential exposure to predation. Adults dominated after flow resumed, and population structure was altered post-drying by the loss of spring-recruited juveniles and reproductive females. Our results suggest that streambed drying may have longer-term effects than typically characterized by community-level studies. We recommend management actions that support populations of ecologically important species as they adapt to changing flow regimes

2,8'-Disubstituted-1,1'-Binaphthyls:A New Pattern in Chiral Ligands

The title binaphthyls 19 and 26, which are the positional isomers of 2-methoxy-2'-(diphenylphosphino)-1,1'-binaphthyl (MOP, 19) and 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN, 26), have been synthesized by Suzuki coupling as the key step (10 + 15→18), followed by functional group transformations, involving C-P and C-N bond formation (18→19 and 18→23). Racemic intermediate 22 was resolved by cocrystallization with N-benzylcinchonidinium chloride and the absolute configuration determined by X-ray crystallography. These novel binaphthyls are configurationally stable and, as such, potentially usable as chiral ligands in asymmetric reactions. Michael addition of the glycine-derived enolate 40 to methyl acrylate, carried out in the presence of (R)-(-)-27 as the chiral phase-transfer catalyst, afforded L-glutamic acid (S)-(+)-43 of 92% ee (after hydrolysis of the primary product)