12,487 research outputs found
The mechanical resistance of saturated stones
This paper aims at investigating the effect of the presence of water on the mechanical resistance of stones. The presence of water, connected to the intrinsic properties of the stone (mineralogical composition, fabric, texture, etc.) and to the conditions of use (anchoring systems, climatic parameters, etc ), is the main cause of stone decay. However, the presence of water alone inside stone could cause a decrease in mechanical resistance . The obtained data could in fact be useful to correct the safety coefficient and should be taken into account in the planning of structural stonework. Moreover, useful suggestions can be drawn for the in situ monitoring, taking into account that non destructive tests, together with conventional mechanical methods, are influenced by the presence of water in stones and should be corrected. Three kinds of stones, which have historically been used for structural purposes, have been studied: Pietra di Luserna (gneiss, Piedmont, Italy), Pietra Verde Argento (gneiss, Piedmont, Italy) and Pietra di Courtil (mica-schist, Aosta Valley, Italy). The flexural strength, rupture energy, open porosity and ultrasonic pulse velocity (UPV) have been determined on specimens in dried and saturated conditions at different accelerated ageing steps. As far as the UPV test is concerned, its results are well correlated with the flexural strength values but, without other parameters, it cannot give information on whether the specimen is filled with water, therefore suitable procedures to correct the UPV value obtained in situ are suggested. Destructive methods, and in particular the flexural strength method, instead, give lower resistance values for saturated specimens than dried ones, thus confirming the weakness of the stone due to the water insid
Quasiparticle Electronic structure of Copper in the GW approximation
We show that the results of photoemission and inverse photoemission
experiments on bulk copper can be quantitatively described within
band-structure theory, with no evidence of effects beyond the
single-quasiparticle approximation. The well known discrepancies between the
experimental bandstructure and the Kohn-Sham eigenvalues of Density Functional
Theory are almost completely corrected by self-energy effects.
Exchange-correlation contributions to the self-energy arising from 3s and 3p
core levels are shown to be crucial.Comment: 4 pages, 2 figures embedded in the text. 3 footnotes modified and 1
reference added. Small modifications also in the text. Accepted for
publication in PR
Anomalous temperature dependence of the band-gap in Black Phosphorus
Black Phosphorus (BP) has gained renewed attention due to its singular
anisotropic electronic and optical properties that might be exploited for a
wide range of technological applications. In this respect, the thermal
properties are particularly important both to predict its room temperature
operation and to determine its thermoelectric potential. From this point of
view, one of the most spectacular and poorly understood phenomena is, indeed,
the BP temperature-induced band-gap opening: when temperature is increased the
fundamental band-gap increases instead of decreasing. This anomalous thermal
dependence has also been observed, recently, in its monolayer counterpart. In
this work, based on \textit{ab-initio} calculations, we present an explanation
for this long known, and yet not fully explained, effect. We show that it
arises from a combination of harmonic and lattice thermal expansion
contributions, which are, in fact, highly interwined. We clearly narrow down
the mechanisms that cause this gap opening by identifying the peculiar atomic
vibrations that drive the anomaly. The final picture we give explains both the
BP anomalous band-gap opening and the frequency increase with increasing volume
(tension effect).Comment: Published in Nano Letter
Metadynamic sampling of the free energy landscapes of proteins coupled with a Monte Carlo algorithm
Metadynamics is a powerful computational tool to obtain the free energy
landscape of complex systems. The Monte Carlo algorithm has proven useful to
calculate thermodynamic quantities associated with simplified models of
proteins, and thus to gain an ever-increasing understanding on the general
principles underlying the mechanism of protein folding. We show that it is
possible to couple metadynamics and Monte Carlo algorithms to obtain the free
energy of model proteins in a way which is computationally very economical.Comment: Submitted to Gen
Efficacy of Two Common Methods of Application of Residual Insecticide for Controlling the Asian Tiger Mosquito, Aedes albopictus (Skuse), in Urban Areas
After its first introduction in the 1980's the Asian tiger mosquito, Aedes albopictus (Skuse), has spread throughout Southern Europe. Ae. albopictus is considered an epidemiologically important vector for the transmission of many viral pathogens such as the yellow fever virus, dengue fever and Chikungunya fever, as well as several filarial nematodes such as Dirofilaria immitis or D. repens. It is therefore crucial to develop measures to reduce the risks of disease transmission by controlling the vector populations. The aim of the study was to compare the efficacy of two application techniques (mist vs. stretcher sprayer) and two insecticides (Etox based on the nonester pyrethroid Etofenprox vs. Microsin based on the pyrethroid type II Cypermetrin) in controlling adult tiger mosquito populations in highly populated areas. To test the effect of the two treatments pre- and post-treatment human landing rate counts were conducted for two years. After one day from the treatment we observed a 100% population decrease in mosquito abundance with both application methods and both insecticides. However, seven and 14 days after the application the stretcher sprayer showed larger population reductions than the mist sprayer. No effect of insecticide type after one day and 14 days was found, while Etox caused slightly higher population reduction than Microsin after seven days. Emergency measures to locally reduce the vector populations should adopt adulticide treatments using stretcher sprayers. However, more research is still needed to evaluate the potential negative effects of adulticide applications on non-target organisms
Vicoforte sandstone in Cultural Heritage
The large family of sandstone covers stones with different grains, porosity, cement or matrix, compactness, chemical composition etc. and it is widely used as cladding stone, even in historic buildings. From literature, its decay is usually connected to the action of salts or to black crusts because of pollution.
Being sandstone a sedimentary rock deposited in layers, often the quarry produce material with a high variability in aspects and mechanical properties. This can be also evident in the resistance to decay shown in the monuments that is typical of each facies though it has been exposed for the same lapse of time and under similar climatic conditions. This is the case of Arenaria di Vicoforte used on the facade of the Vicoforte Sanctuary (Vicoforte - Mondovì) and probably on the external pilaster of the Monte dei Cappuccini church in Turin. Both the catholic monuments were designed by architect Ascanio Vitozzi at the end of the XVI century . It is possible to compare the high degree of weathering of the pilasters of the Monte dei Cappuccini church with the good ageing behaviour shown by the Vicoforte Sanctuary sandstone.
Different durability tests were carried out: resistance to salt crystallisation, resistance to ageing due to SO2 action in the presence of humidity, frost resistance. The mass weight difference, method used to evaluate the forecast of decay in various european standardardized methodologies, does not always offer a satisfactory estimation of the decay of stone after salt crystallization while water absorption, which is well correlated to the physical mechanical characteristics of the stone, together with a visual inspection, is a good index of the decay in order to obtain a distinction, in terms of durability, between different sandstones even of a same geological district.
A visit to the quarry solved any doubts: two different facies of the Vicoforte sandstone were quarried, one yellowish and the other grey. The first, mainly silicatic, was used for the Sanctuary near the quarry, the grey one (with a carbonate content of 18%) could be the one sent to Turin.
The variability of the rock characteristics in the quarry should therefore be taken into account when evaluating the durability of the sandstone
Non-equilibrium fluctuations in a driven stochastic Lorentz gas
We study the stationary state of a one-dimensional kinetic model where a
probe particle is driven by an external field E and collides, elastically or
inelastically, with a bath of particles at temperature T. We focus on the
stationary distribution of the velocity of the particle, and of two estimates
of the total entropy production \Delta s_tot. One is the entropy production of
the medium \Delta s_m, which is equal to the energy exchanged with the
scatterers, divided by a parameter \theta, coinciding with the particle
temperature at E=0. The other is the work W done by the external field, again
rescaled by \theta. At small E, a good collapse of the two distributions is
found: in this case the two quantities also verify the Fluctuation Relation
(FR), indicating that both are good approximations of \Delta s_tot.
Differently, for large values of E, the fluctuations of W violate the FR, while
\Delta s_m still verifies it.Comment: 6 pages, 4 figure
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