1,613 research outputs found
Dynamics of 8CB confined into porous silicon probed by incoherent neutron backscattering experiments
Confinement in the nanochannels of porous silicon strongly affects the phase
behavior of the archetype liquid-crystal 4-n-octyl-4-cyanobiphenyl (8CB). A
very striking phenom- enon is the development of a short-range smectic order,
which occurs on a very broad temperature range. It suggests in this case that
quenched disorder effects add to usual finite size and surface interaction
effects. We have monitored the temperature variation of the molecular dynamics
of the confined fluid by incoherent quasielastic neutron scat- tering. A
strongly reduced mobility is observed at the highest temperatures in the liquid
phase, which suggests that the interfacial molecular dynamics is strongly
hindered. A continuously increasing slowdown appears on cooling together with a
progressive growth of the static correlation lengt
Rich polymorphism of a rod-like liquid crystal (8CB) confined in two types of unidirectional nanopores
We present a neutron and X-rays scattering study of the phase transitions of
4-n-octyl-4'-cyanobiphenyl (8CB) confined in unidirectional nanopores of porous
alumina and porous silicon (PSi) membranes with an average diameter of 30 nm.
Spatial confinement reveals a rich polymorphism, with at least four different
low temperature phases in addition to the smectic A phase. The structural study
as a function of thermal treatments and conditions of spatial confinement
allows us to get insights into the formation of these phases and their relative
stability. It gives the first description of the complete phase behavior of 8CB
confined in PSi and provides a direct comparison with results obtained in bulk
conditions and in similar geometric conditions of confinement but with reduced
quenched disorder effects using alumina anopore membranesComment: Accepted in EPJ E - Soft Matte
Tracking the phase-transition energy in disassembly of hot nuclei
In efforts to determine phase transitions in the disintegration of highly
excited heavy nuclei, a popular practice is to parametrise the yields of
isotopes as a function of temperature in the form
, where 's are the measured yields
and and are fitted to the yields. Here would be
interpreted as the phase transition temperature. For finite systems such as
those obtained in nuclear collisions, this parametrisation is only approximate
and hence allows for extraction of in more than one way. In this work we
look in detail at how values of differ, depending on methods of
extraction. It should be mentioned that for finite systems, this approximate
parametrisation works not only at the critical point, but also for first order
phase transitions (at least in some models). Thus the approximate fit is no
guarantee that one is seeing a critical phenomenon. A different but more
conventional search for the nuclear phase transition would look for a maximum
in the specific heat as a function of temperature . In this case is
interpreted as the phase transition temperature. Ideally and would
coincide. We invesigate this possibility, both in theory and from the ISiS
data, performing both canonical () and microcanonical ()
calculations. Although more than one value of can be extracted from the
approximate parmetrisation, the work here points to the best value from among
the choices. Several interesting results, seen in theoretical calculations, are
borne out in experiment.Comment: Revtex, 10 pages including 8 figures and 2 table
Interplay of initial deformation and Coulomb proximity on nuclear decay
Alpha particles emitted from an excited projectile-like fragment (PLF*)
formed in a peripheral collision of two intermediate-energy heavy ions exhibit
a strong preference for emission towards the target-like fragment (TLF). The
interplay of the initial deformation of the PLF* caused by the reaction,
Coulomb proximity, and the rotation of the PLF* results in the observed
anisotropic angular distribution. Changes in the shape of the angular
distribution with excitation energy are interpreted as being the result of
forming more elongated initial geometries in the more peripheral collisions.Comment: 4 figure
Molecular dynamics of glycerol and glycerol-trehalose bioprotectant solutions nanoconfined in porous silicon
Glycerol and trehalose-glycerol binary solutions are glass-forming liquids
with remarkable bioprotectant properties. Incoherent quasielastic neutron
scattering (QENS) is used to reveal the different effects of nanoconfinement
and addition of trehalose on the molecular dynamics in the normal liquid and
supercooled liquid phases, on a nanosecond timescale. Confinement has been
realized in straight channels of diameter D=8 nm formed by porous silicon. It
leads to a faster and more inhomogeneous relaxation dynamics deep in the liquid
phase. This confinement effect remains at lower temperature where it affects
the glassy dynamics. The glass transitions of the confined systems are shifted
to low temperature with respect to the bulk ones. Adding trehalose tends to
slow down the overall glassy dynamics and increases the non-exponential
character of the structural relaxation. Unprecedented results are obtained for
the binary bioprotectant solution, which exhibits an extremely non-Debye
relaxation dynamics as a result of the combination of the effects of
confinement and mixing of two constituents
Thermally-induced expansion in the 8 GeV/c + Au reaction
Fragment kinetic energy spectra for reactions induced by 8.0 GeV/c
beams incident on a Au target have been analyzed in
order to deduce the possible existence and influence of thermal expansion. The
average fragment kinetic energies are observed to increase systematically with
fragment charge but are nearly independent of excitation energy. Comparison of
the data with statistical multifragmentation models indicates the onset of
extra collective thermal expansion near an excitation energy of E*/A
5 MeV. However, this effect is weak relative to the radial
expansion observed in heavy-ion-induced reactions, consistent with the
interpretation that the latter expansion may be driven primarily by dynamical
effects such as compression/decompression.Comment: 12 pages including 4 postscript figure
Excitation and decay of projectile-like fragments formed in dissipative peripheral collisions at intermediate energies
Projectile-like fragments (PLF:15<=Z<=46) formed in peripheral and
mid-peripheral collisions of 114Cd projectiles with 92Mo nuclei at E/A=50 MeV
have been detected at very forward angles, 2.1 deg.<=theta_lab<=4.2 deg.
Calorimetric analysis of the charged particles observed in coincidence with the
PLF reveals that the excitation of the primary PLF is strongly related to its
velocity damping. Furthermore, for a given V_PLF*, its excitation is not
related to its size, Z_PLF*. For the largest velocity damping, the excitation
energy attained is large, approximately commensurate with a system at the
limiting temperatureComment: 5 pages, 6 figure
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