Probing vibrational modes in silica glass using inelastic neutron scattering with mass contrast

The effective vibrational density of states (VDOS) has been derived from inelastic neutron-scattering data, for isotopically substituted Si O 18 2 and Si O 16 2 glasses, to gain information about the relative contribution to the Si and O partial VDOS. This is a necessary point of comparison for vibrational mode analyses of molecular-dynamics models. The mass contrast has led to a measurable shift between vibrational mode frequencies in the effective VDOS of Si O 18 2 and Si O 16 2, which is well reproduced in an ab initio simulation. The vibrational band centered at 100.2 meV is confirmed to have significantly lower contribution from the oxygen partial VDOS, than the higher (150.3 and 135.8 meV) and lower energy bands (53.3 meV)

Interactions of heavy nuclei, Kr, Xe and Ho, in light targets

Over the past few years, the HEAO-3 measurements of the abundances of ultra-heavy cosmic ray nuclei (Z 26) at earth have been analyzed. In order to interpret these abundances in terms of a source composition, allowance must be made for the propagation of the nuclei in the interstellar medium. Vital to any calculation of the propagation is a knowlege of the total and partial interaction cross sections for these heavy nuclei on hydrogen. Until recently, data on such reactions have been scarce. However, now that relativistic heavy ion beams are available at the LBL Bevalac, some of the cross sections of interest can be measured at energies close to those of the cosmic ray nuclei being observed. During a recent calibration at the Bevalac of an array similar to the HEAO-C3 UH-nuclei detector, targets of raphite (C), polyethylene (CH2), and aluminum were exposed to five heavy ion beams ranging in charge (Z) from 36 to 92. Total and partial charge changing cross sections for the various beam nuclei on hydrogen can be determined from the measured cross sections on C and CH2, and will be applied to the propagation problem. The cross sections on Al can be used to correct the abundances of UH cosmic rays observed in the HEAO C-3 detector for interactions in the detector itself

X-ray diffraction studies of the effects of N incorporation in amorphous CNx, materials

The effects of nitrogen incorporation on the atomic-scale structure of amorphous CNx samples have been studied for 0, 5, 20, and 30 at. % N concentration, by x-ray diffraction. Significant differences in the structure are observed on the incorporation of only 5 at. % N, and the changes in structure continue as further N is added. From the experimental data, we are able to obtain directly the average bond distances and then calculate the average bond angles for each of the samples. The average first neighbor distance shows a gradual decrease from 1.55 Angstrom for 0 at. % N, to 1.44 Angstrom for 30 at. % N, and a similar trend is observed in the position of the second neighbor peak. This gives a corresponding increase in the average bond angle from 108 degrees to 114 degrees. The results show an increase in the fraction of sp(2) bonded carbon atoms with increasing N concentration, and there is evidence for the presence of significant numbers of C=N and C=N bonds. These results are also consistent with stress, hardness, and optical gap measurements for these samples. (C) 1998 American Institute of Physics. [S0021-8979(98)03907-3]

Power Spectrum Analysis of BNL Decay-Rate Data

Evidence for an anomalous annual periodicity in certain nuclear decay data has led to speculation concerning a possible solar influence on nuclear processes. As a test of this hypothesis, we here search for evidence in decay data that might be indicative of a process involving solar rotation, focusing on data for 32Si and 36Cl decay rates acquired at the Brookhaven National Laboratory. Examination of the power spectrum over a range of frequencies (10 - 15 year^-1) appropriate for solar synodic rotation rates reveals several periodicities, the most prominent being one at 11.18 year^-1 with power 20.76. We evaluate the significance of this peak in terms of the false-alarm probability, by means of the shuffle test, and also by means of a new test (the "shake" test) that involves small random time displacements. The last two tests indicate that the peak at 11.18 year^-1 would arise by chance only once out of about 10^7 trials. Since there are several peaks in the search band, we also investigate the running mean of the power spectrum, and identify a major peak at 11.93 year^-1 with peak running-mean power 4.08. Application of the shuffle test and the shake test indicates that there is less than one chance in 10^11, and one chance in 10^15, respectively, finding by chance a value as large as 4.08.Comment: 12 pages, 17 figures, to be published in Astroparticle Physic

The Non-Z^2 Response of the Heavy Nuclei Cosmic Ray Detector on HEAO-3

A combination of ion chambers and Cerenkov radiators similar to the Heavy Nuclei Experiment flown on HEAO-3 was calibrated at the Bevalac heavy-ion accelerator using beams of Mn-25 nuclei at kinetic energies up to about 1700 MeV/nucleon and Au-79 nuclei up to about 1000 MeV/nucleon. The data show only a small deviation (about 2-3 charge units at Au) from the Z^2 scaling used previously (Binns et al., 1981, 1982, 1983) to analyze the HNE data. Although at lower energy, the calibration indicates that the published relative abundances of the _(50)Sn/_(56)Ba group and the published upper-limit actinide abundances are not likely to be significantly affected by non-Z^2 effects

Do ‘passive’ medical titanium surfaces deteriorate in service in the absence of wear?

Globally, more than 1000 tonnes of titanium (Ti) is implanted into patients in the form of biomedical devices on an annual basis. Ti is perceived to be ‘biocompatible’ owing to the presence of a robust passive oxide film (approx. 4 nm thick) at the metal surface. However, surface deterioration can lead to the release of Ti ions, and particles can arise as the result of wear and/or corrosion processes. This surface deterioration can result in peri-implant inflammation, leading to the premature loss of the implanted device or the requirement for surgical revision. Soft tissues surrounding commercially pure cranial anchorage devices (bone-anchored hearing aid) were investigated using synchrotron X-ray micro-fluorescence spectroscopy and X-ray absorption near edge structure. Here, we present the first experimental evidence that minimal load-bearing Ti implants, which are not subjected to macroscopic wear processes, can release Ti debris into the surrounding soft tissue. As such debris has been shown to be pro-inflammatory, we propose that such distributions of Ti are likely to effect to the service life of the device

The Cosmic-Ray Abundances of the Platinum-Lead Elements as Measured on HEAO-3

The relative abundances of elements in the charge ranges of 75 ≤ Z ≤ 79 (platinum) and 80 ≤ Z ≤ 83 (lead) should be a sensitive indication of the contributions of the r- and s-processes in nucleosynthesis. Data from the HEAO 3 Heavy Nuclei Experiment are used to establish abundances, relative to iron, of these elements in the cosmic radiation, as well as the ratio of 'secondary' elements, in the 62 ≤ Z ≤ 74 range, to the primary lead-platinum elements. These results appear to suggest that either the source abundances are deficient in s-process elements or that they are not organized solely by first ionization potential. In addition, present propagation models can adequately represent the relative abundances of primary and secondary elements

The Response of Ionization Chambers to Relativistic Heavy Nuclei

As part of a recent calibration at the LBL Bevalac for the Heavy Nuclei Experiment on HEAO-3, we have compared the response of a set of laboratory ionization chambers to beams of _(26)Fe, _(36)Kr, _(54)Xe, _(67)Ho, and _(79)Au nuclei at maximum energies ranging from 1666 MeV/amu for Fe to 1049 MeV /amu for Au. The response of these chambers shows a significant deviation from the expected energy dependence, but only a slight deviation from Z^2 scaling

The specialty choices of graduates from Brighton and Sussex Medical School: a longitudinal cohort study

BACKGROUND Since 2007 junior doctors in the UK have had to make major career decisions at a point when previously many had not yet chosen a specialty. This study examined when doctors in this new system make specialty choices, which factors influence choices, and whether doctors who choose a specialty they were interested in at medical school are more confident in their choice than those doctors whose interests change post-graduation. METHODS Two cohorts of students in their penultimate year at one medical school (n = 227/239) were asked which specialty interested them as a career. Two years later, 210/227 were sent a questionnaire measuring actual specialty chosen, confidence, influence of perceptions of the specialty and experiences on choice, satisfaction with medicine, personality, self-efficacy, and demographics. Medical school and post-graduation choices in the same category were deemed 'stable'. Predictors of stability, and of not having chosen a specialty, were calculated using bootstrapped logistic regression. Differences between specialties on questionnaire factors were analysed. RESULTS 50% responded (n = 105/277; 44% of the 239 Year 4 students). 65% specialty choices were 'stable'. Factors univariately associated with stability were specialty chosen, having enjoyed the specialty at medical school or since starting work, having first considered the specialty earlier. A regression found doctors who chose psychiatry were more likely to have changed choice than those who chose general practice. Confidence in the choice was not associated with stability. Those who chose general practice valued lifestyle factors. A psychiatry choice was associated with needing a job and using one's intellect to help others. The decision to choose surgical training tended to be made early. Not having applied for specialty training was associated with being lower on agreeableness and conscientiousness. CONCLUSION Medical school experiences are important in specialty choice but experiences post-graduation remain significant, particularly in some specialties (psychiatry in our sample). Career guidance is important at medical school and should be continued post-graduation, with senior clinicians supported in advising juniors. Careers advice in the first year post-graduation may be particularly important, especially for specialties which have difficulty recruiting or are poorly represented at medical school