1,815 research outputs found

    Molecular gold strings: aurophilicity, luminescence and structure–property correlations

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    This review covers the compound class of one-dimensional gold strings. These compounds feature a formally infinite repetition of gold complexes as monomers/repeating units that are held together by aurophilic interactions, i.e. direct gold–gold contacts. Their molecular structures are primarily determined in the solid state using single crystal X-ray diffraction. The chemical composition of the employed gold complexes is diverse and furthermore plays a key role in terms of structure characteristics and the resulting properties. One of the most common features of gold strings is their photoluminescence upon UV excitation. The emission energy is often dependent on the distance of adjacent gold ions and the electronic structure of the whole string. In terms of gold strings, these parameters can be fine-tuned by external stimuli such as solvent, pH value, pressure or mechanical stress. This leads to direct structure–property correlations, not only with regard to the photophysical properties, but also electric conductivity for potential application in nanoelectronics. Concerning these correlations, gold strings, consisting of self-assembled individual complexes as building blocks, are the ideal compound class to look at, as perturbations by an inhomogeneity in the ligand sphere (such as the end of a molecule) can be neglected. Therefore, the aim of this review is to shed light on the past achievements and current developments in this area

    State-resolved measurements of single-electron capture in slow Ne7+- and Ne8+-helium collisions

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    Single-electron capture in collisions of 9 keV x q Ne8+ and Ne7+ ions with He has been studied using cold-target recoil-ion momentum spectroscopy. With an improved apparatus a longitudinal momentum resolution of 0.07 au has been achieved. This momentum component is directly proportional to the difference in the binding energy of the active electron between the final and the initial state. For the first time state- resolved differential cross sections have been determined with respect to the main quantum number, subshell level and spin state of the captured electron. A comparison with recent theoretical results for energy levels in Be-like Ne is given

    Attosecond electron thermalization by laser-driven electron recollision in atoms

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    Nonsequential multiple ionization of atoms in intense laser fields is initiated by a recollision between an electron, freed by tunneling, and its parent ion. Following recollision, the initial electron shares its energy with several bound electrons. We use a classical model based on rapid electron thermalization to interpret recent experiments. For neon, good agreement with the available data is obtained with an upper bound of 460 attoseconds for the thermalization time.Comment: 5 pages revtex and 4 figures (eps files

    Single ionization of atoms in intense laser pulses: Evolution from multiphoton to tunnel ionization

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    We present results of high resolution fully differential measurements on single ionization of He, Ne, and Ar by 7-25 fs linearly polarized 800nm laser pulses at intensities of up to 2.1015 W/cm2. Using a 'Reaction-Microscope' we were able to trace signatures of multiphoton ionization deep into the tunnelling regime. Surprisingly, in the low-energy electron spectra we observed several features (absence of the ponderomotive shifts, splitting of the peaks, their degeneration for few-cycle laser pulses) typical for resonantly-enhanced ionization. Other remarkable features, as the sharp cusp-like momentum distributions in the direction perpendicular to the laser field or the observed minima at zero longitudinal momentum for He and Ne, can be reproduced by semiclassical models, where the electron motion in the combined laser and Coulomb field is treated classically after the tunnelling

    The Metaphor of Circle: Stanislavski, Phenomenology of Roundness and High Yoga

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    Stanislavski’s Eastern influence and his persistent fascination with Yoga is an established area of research. Stanislavski has two major yogic influences in the System: Hatha Yoga and Raja Yoga. The first is about training the body through postures, movements, stances and breathing exercises to make it active, relaxed and energetic. The second includes a range of exclusive practices on concentration and visualization that are an integral part of the actor’s creativity. However, in the current research, there is a clear lack of a comprehensive practical method that informs Stanislavski’s use of yogic practice in the System: what specific yogic exercises were used and what synergies were developed in the training? Scholars have, so far, only explored Stanislavski’s literary legacy of his encounter with yoga, identifying the Sanskrit terms appeared in his writings such as prana for breathing and the Indian anecdotes he used when answering the questions of his students. Focusing on the metaphor of the circle, the phenomenology of roundness and the Deleuzian notions of ‘the invisible forces of sensations’ and ‘the body becomes an event itself’, the present study, for the first time, offers useful insights into the fundamental principles of yoga and their methods of practice as a way of developing a new training to understand the significance of Stanislavski in the 21st century

    Experiences of learning through collaborative evaluation from a masters programme in professional education

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    This paper presents findings from a collaborative evaluation project within a masters programme in professional education. The project aimed to increase knowledge of research methodologies and methods through authentic learning where participants worked in partnership with the tutor to evaluate the module which they were studying. The project processes, areas of the course evaluated and the data collection methods are outlined. The findings focus on key themes from evaluating the effectiveness of using a collaborative evaluation approach, including: enhanced student engagement; creativity of the collaborative evaluation approach; equality between the tutor and students; and enhanced research skills. Discussion focuses on the outcomes and effectiveness of the project and tutor reflections on adopting a collaborative approach. This paper highlights lessons from the project relevant to those interested in staff-student partnership approaches and those facilitating postgraduate learning and teaching programmes and educational research courses

    Non-sequential triple ionization in strong fields

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    We consider the final stage of triple ionization of atoms in a strong linearly polarized laser field. We propose that for intensities below the saturation value for triple ionization the process is dominated by the simultaneous escape of three electrons from a highly excited intermediate complex. We identify within a classical model two pathways to triple ionization, one with a triangular configuration of electrons and one with a more linear one. Both are saddles in phase space. A stability analysis indicates that the triangular configuration has the larger cross sections and should be the dominant one. Trajectory simulations within the dominant symmetry subspace reproduce the experimentally observed distribution of ion momenta parallel to the polarization axis.Comment: 9 pages, 8 figures, accepted for publication in Phys. Rev.
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