Decoherence of molecular wave packets in an anharmonic potential

The time evolution of anharmonic molecular wave packets is investigated under the influence of the environment consisting of harmonic oscillators. These oscillators represent photon or phonon modes and assumed to be in thermal equilibrium. Our model explicitly incorporates the fact that in the case of a nonequidistant spectrum the rates of the environment induced transitions are different for each transition. The nonunitary time evolution is visualized by the aid of the Wigner function related to the vibrational state of the molecule. The time scale of decoherence is much shorter than that of dissipation, and gives rise to states which are mixtures of localized states along the phase space orbit of the corresponding classical particle. This behavior is to a large extent independent of the coupling strength, the temperature of the environment and also of the initial state.Comment: 7 pages, 4 figure

Quantum rings as electron spin beam splitters

Quantum interference and spin-orbit interaction in a one-dimensional mesoscopic semiconductor ring with one input and two output leads can act as a spin beam splitter. Different polarization can be achieved in the two output channels from an originally totally unpolarized incoming spin state, very much like in a Stern-Gerlach apparatus. We determine the relevant parameters such that the device has unit efficiency.Comment: 4 pages, 3 figures; minor change

Wer bremst verliert - Antimon in Straßenrandböden

Seit dem weitreichenden Verbot von Asbest in den 1980er Jahren wurde verstärkt das Halbmetall Antimon (Sb) in Bremsbelägen von PKW und LKW verwendet. Im Zuge des Bremsvorganges wird dieses in Form von Feinstaub freigesetzt und straßennah in die Böden eingetragen. Grundsätzlich sind Antimoneinträge in Böden negativ zu bewerten, da das Halbmetall toxische Wirkungen hervorrufen kann. Um die räumliche Verteilung von Antimon und seinen Bindungsformen in Straßenrandböden zu untersuchen, wurden 5 parallele Transekte mit jeweils 7 Entfernungen und 4 Probentiefen entlang einer Kölner Kreisstraße (Verkehrsaufkommen ca. 9.600 Fahrzeuge pro Tag) beprobt. Neben einer allgemeinen physikochemischen Charakterisierung der Bodenproben wurden ihre königswasser-löslichen Antimongehalte bestimmt. Zusätzlich wurde an einem Transekt eine sequentielle Extraktion nach Wenzel et al. 2001 durchgeführt, um die Bindungsformen von Antimon zu ermitteln. Die Antimongehalte nahmen von bis zu 6,18 g kg–1 unmittelbar am Straßenrand bis auf 0,513 g kg–1 in 10 m Entfernung ab. Ebenfalls konnte eine deutliche Abnahme mit der Bodentiefe (0 bis 30 cm) festgestellt werden. Dieses Verteilungsmuster deutet auf den Verkehr als Antimoneintragsquelle hin. Als Hinweis auf einen durch den Bremsabrieb metallener Bremsscheiben dominierten Eintrag wurde die magnetische Suszeptibilität gemessen. Allerdings lieferte der Korrelationskoeffizient (Spearman) von Antimon gegenüber der magnetischen Suszeptibilität 0,423 (p = 0,023) nur einen eher schwachen Beleg. Die ursprünglich für Arsen entwickelte sequentielle Extraktion ließ sich reproduzierbar ebenfalls für Antimon anwenden. Anhand dieser konnten im Wesentlichen drei Trends der Bindungsformen erfasst werden: i) spezifisch gebundenes Antimon (Fraktion 2: 0,05 mol l–1 (NH4)H2P2O4) konnte lediglich innerhalb 1 m Entfernung zur Straße und mit der Bodentiefen abnehmenden Gehalten nachgewiesen werden, ii) der Anteil an schwachkristallinen Eisenoxiden gebundenem Antimon (Fraktion 3: 0,2 mol l–1 (NH4)2-Oxalatpuffer; pH 3,25) nahm signifikant mit steigender Entfernung zur Straße ab, während iii) die prozentualen Gehalte in den starkkristallinen Eisenoxiden (Fraktion 4: 0,2 mol l–1 (NH4)2-Oxalatpuffer + 0,1 mol l–1 Ascorbinsäure; pH 3,25) und in der Residualphase (Fraktion 5: Königswasser) zunahmen

Microwave emission from a crystal of molecular magnets -- The role of a resonant cavity

We discuss the effects caused by a resonant cavity around a sample of a magnetic molecular crystal (such as Mn${}_{12}$-Ac), when a time dependent external magnetic field is applied parallel to the easy axis of the crystal. We show that the back action of the cavity field on the sample significantly increases the possibility of microwave emission. This radiation process can be supperradiance or a maser-like effect, depending on the strength of the dephasing. Our model provides further insight to the theoretical understanding of the bursts of electromagnetic radiation observed in recent experiments accompanying the resonant quantum tunneling of magnetization. The experimental findings up to now can all be explained as being a maser effect rather than superradiance. The results of our theory scale similarly to the experimental findings, i.e., with increasing sweep rate of the external magnetic field, the emission peaks are shifted towards higher field values.Comment: 12 pages, 6 figures. To appear in Phys. Rev.

Hospitality, Culture and Regeneration: Urban decay, entrepreneurship and the "ruin" bars of Budapest

This paper considers the relationships between hospitality, culture and urban regeneration through an examination of rom (ruin) venues, which operate in dilapidated buildings in Budapest, Hungary. The paper reviews previous work on culture and urban regeneration in order to locate the role of hospitality within emerging debates. It subsequently interrogates the evolution of the rom phenomenon and demonstrates how, in this context, hospitality thrives because of social and physical decay in urban locations, how operators and entrepreneurs exploit conflicts among various actors involved in regeneration, and how hospitality may be mobilised purposefully in the regeneration process. The paper demonstrates how networked entrepreneurship maintains these operations and how various forms of cultural production are entangled and mobilised in the venues’ hospitality propositions

Bacteriological and cytological findings during the late puerperal period after two different treatments of retained placenta followed by acute puerperal metritis

The aim of the study was to compare the effect of two acute puerperal metritis (APM) treatment protocols on uterine condition during the late puerperal period (5th to 7th week). Late gestation healthy cows (n = 21) were divided randomly in three equal groups. Parturitions were induced. Treatments of APM were started on the third day postpartum (PP). Group A was treated with an oxytocin analogue carbetocin for three days and intrauterine administration of cephapirin between days 15 and 17. Group B was given intramuscular injection of ceftiofur for five days followed by two injections of prostaglandin F2α, at an interval of 12 h, on the eighth day PP. Group C served as the control group with no treatment. Body temperature was recorded daily for 14 days PP. Uterine biopsies for bacteriology, and uterobrush samples for cytology, were taken once a week from the 5th to 7th week postpartum. No differences were found in body temperature on day 14 PP, presence of bacteriological infections and disappearance of uterine inflammatory signs diagnosed by cytological examination between experimental groups

Wigner functions, squeezing properties and slow decoherence of atomic Schrodinger cats

We consider a class of states in an ensemble of two-level atoms: a superposition of two distinct atomic coherent states, which can be regarded as atomic analogues of the states usually called Schrodinger cat states in quantum optics. According to the relation of the constituents we define polar and nonpolar cat states. The properties of these are investigated by the aid of the spherical Wigner function. We show that nonpolar cat states generally exhibit squeezing, the measure of which depends on the separation of the components of the cat, and also on the number of the constituent atoms. By solving the master equation for the polar cat state embedded in an external environment, we determine the characteristic times of decoherence, dissipation and also the characteristic time of a new parameter, the non-classicality of the state. This latter one is introduced by the help of the Wigner function, which is used also to visualize the process. The dependence of the characteristic times on the number of atoms of the cat and on the temperature of the environment shows that the decoherence of polar cat states is surprisingly slow.Comment: RevTeX, 14 pages including 8 PostScript figures. High quality versions of Figures 1, 3, 5, 7 and 8 are available at http://www.jate.u-szeged.hu/~benedict/asc_figures.html . (Submitted to Physical Review A: March 26, 1999.

Quadratic-nonlinear Landau-Zener transition for association of an atomic Bose-Einstein condensate with inter-particle elastic interactions included

We study the strong coupling limit of a quadratic-nonlinear Landau-Zener problem for coherent photo- and magneto-association of cold atoms taking into account the atom-atom, atom-molecule, and molecule-molecule elastic scattering. Using an exact third-order nonlinear differential equation for the molecular state probability, we develop a variational approach which enables us to construct a highly accurate and simple analytic approximation describing the time dynamics of the coupled atom-molecule system. We show that the approximation describing time evolution of the molecular state probability can be written as a sum of two distinct terms; the first one, being a solution to a limit first-order nonlinear equation, effectively describes the process of the molecule formation while the second one, being a scaled solution to the linear Landau-Zener problem (but now with negative effective Landau-Zener parameter as long as the strong coupling regime is considered), corresponds to the remaining oscillations which come up when the process of molecule formation is over.Comment: 19 pages, 7 figures, accepted for publication in Eur. Phys. J.

The Molecular Assembly of Amyloid Aβ Controls Its Neurotoxicity and Binding to Cellular Proteins

Accumulation of β-sheet-rich peptide (Aβ) is strongly associated with Alzheimer's disease, characterized by reduction in synapse density, structural alterations of dendritic spines, modification of synaptic protein expression, loss of long-term potentiation and neuronal cell death. Aβ species are potent neurotoxins, however the molecular mechanism responsible for Aβ toxicity is still unknown. Numerous mechanisms of toxicity were proposed, although there is no agreement about their relative importance in disease pathogenesis. Here, the toxicity of Aβ 1–40 and Aβ 1–42 monomers, oligomers or fibrils, was evaluated using the N2a cell line. A structure-function relationship between peptide aggregation state and toxic properties was established. Moreover, we demonstrated that Aβ toxic species cross the plasma membrane, accumulate in cells and bind to a variety of internal proteins, especially on the cytoskeleton and in the endoplasmatic reticulum (ER). Based on these data we suggest that numerous proteins act as Aβ receptors in N2a cells, triggering a multi factorial toxicity