1,440 research outputs found
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An Evaluation of Through-Thickness Changes in Primary Damage Production in Commercial Reactor Pressure Vessels
An extensive database of atomic displacement cascades in iron has been developed using the method of molecular dynamics (MD). More than 300 simulations have been completed at 100K with energies between 0.1 and 100 keV. This encompasses nearly all energies relevant to fission reactor irradiation environments since a 100 keV MD cascade corresponds to the average iron cascade following a collision with a 5.1 MeV neutron. Extensive statistical analysis of the database has determined representative average values for several primary damage parameters: the total number of surviving point defects, the fraction of the surviving point defects contained in clusters formed during cascade cooling, and a measure of the size distribution of the in-cascade point defect clusters. The cascade energy dependence of the MD-based primary damage parameters has been used to obtain spectrum-averaged defect production cross sections for typical fission reactor neutron energy spectra as a function of depth through the reactor pressure vessel. The attenuation of the spectrum-averaged cross sections for total point defect survival and the fraction of either interstitials or vacancies in clusters are quite similar to that for the NRT dpa. However, the cross sections derived to account for the energy dependence of the point defect cluster size distributions exhibit a potentially significant variation through the vessel. The production rate of large interstitial clusters decreases more rapidly than dpa whereas the production of large vacancy clusters is slower than dpa
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Point defect survival and clustering fractions obtained from molecular dynamics simulations of high energy cascades
Evolution of high-energy displacement cascades in iron has been investigated for times up to 200 ps using molecular dynamics simulation. The simulations were carried out using the MOLDY code and a modified version of the many-body interatomic potential developed by Finnis and Sinclair. Previously reported results have been supplemented by a series of 10 keV simulations at 900 K and 20 keV simulations at 100K. Results indicate that the fraction of the Frenkel pairs escaping in-cascade recombination is somewhat higher and the fraction of the surviving point defects that cluster is lower in iron than in materials such as copper. In particular, vacancy clustering appears to be inhibited in iron. Many of the larger interstitial clusters were observed to exhibit a complex, three-dimensional morphology. Apparent mobility of the crowdion and clusters of crowdions was very high
Tree Buffers
In runtime verification, the central problem is to decide if a given program execution violates a given property. In online runtime verification, a monitor observes a program’s execution as it happens. If the program being observed has hard real-time constraints, then the monitor inherits them. In the presence of hard real-time constraints it becomes a challenge to maintain enough information to produce error traces, should a property violation be observed. In this paper we introduce a data structure, called tree buffer, that solves this problem in the context of automata-based monitors: If the monitor itself respects hard real-time constraints, then enriching it by tree buffers makes it possible to provide error traces, which are essential for diagnosing defects. We show that tree buffers are also useful in other application domains. For example, they can be used to implement functionality of capturing groups in regular expressions. We prove optimal asymptotic bounds for our data structure, and validate them using empirical data from two sources: regular expression searching through Wikipedia, and runtime verification of execution traces obtained from the DaCapo test suite
The influence of transition metal solutes on dislocation core structure and values of Peierls stress and barrier in tungsten
Several transition metals were examined to evaluate their potential for
improving the ductility of tungsten. The dislocation core structure and Peierls
stress and barrier of screw dislocations in binary
tungsten-transition metal alloys (WTM) were investigated using
first principles electronic structure calculations. The periodic quadrupole
approach was applied to model the structure of dislocation. Alloying
with transition metals was modeled using the virtual crystal approximation and
the applicability of this approach was assessed by calculating the equilibrium
lattice parameter and elastic constants of the tungsten alloys. Reasonable
agreement was obtained with experimental data and with results obtained from
the conventional supercell approach. Increasing the concentration of a
transition metal from the VIIIA group, i.e. the elements in columns headed by
Fe, Co and Ni, leads to reduction of the elastic constant and
increase of elastic anisotropy A=. Alloying W with a group
VIIIA transition metal changes the structure of the dislocation core from
symmetric to asymmetric, similar to results obtained for WRe
alloys in the earlier work of Romaner {\it et al} (Phys. Rev. Lett. 104, 195503
(2010))\comments{\cite{WRECORE}}. In addition to a change in the core symmetry,
the values of the Peierls stress and barrier are reduced. The latter effect
could lead to increased ductility in a tungsten-based
alloy\comments{\cite{WRECORE}}. Our results demonstrate that alloying with any
of the transition metals from the VIIIA group should have similar effect as
alloying with Re.Comment: 12 pages, 8 figures, 3 table
Ultrahigh Surface Area Three-Dimensional Porous Graphitic Carbon from Conjugated Polymeric Molecular Framework
Porous graphitic carbon is essential for many applications such as energy storage devices, catalysts, and sorbents. However, current graphitic carbons are limited by low conductivity, low surface area, and ineffective pore structure. Here we report a scalable synthesis of porous graphitic carbons using a conjugated polymeric molecular framework as precursor. The multivalent cross-linker and rigid conjugated framework help to maintain micro- and mesoporous structures, while promoting graphitization during carbonization and chemical activation. The above unique design results in a class of highly graphitic carbons at temperature as low as 800 ??C with record-high surface area (4073 m2 g-1), large pore volume (2.26 cm-3), and hierarchical pore architecture. Such carbons simultaneously exhibit electrical conductivity >3 times more than activated carbons, very high electrochemical activity at high mass loading, and high stability, as demonstrated by supercapacitors and lithium-sulfur batteries with excellent performance. Moreover, the synthesis can be readily tuned to make a broad range of graphitic carbons with desired structures and compositions for many applications.clos
Gender identity change in a female adolescent transsexual
Two years of individual and milieu therapy are described of a 141/2-year-old girl who had presented with the persistent request to have a sex-change operation since age 12. Her past history was obtained from her parents and the records of the child guidance clinic which evaluated her at 3 years of age. She gives a history of remarkable tomboyism during her latency years and increasing withdrawal from peers and family during early adolescence. The patient's personal and family dynamics are explored, and these major therapeutic themes are discussed. The individual and milieu therapy are described and discussed with some speculation about the reasons for her positive response to psychotherapy. It would appear that this is a rare case of a postpubertal female transsexual reported to have made a gender identity change.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44103/1/10508_2005_Article_BF01541204.pd
Resolution and enhancement in nanoantenna-based fluorescence microscopy
Single gold nanoparticles can act as nanoantennas for enhancing the
fluorescence of emitters in their near-fields. Here we present experimental and
theoretical studies of scanning antenna-based fluorescence microscopy as a
function of the diameter of the gold nanoparticle. We examine the interplay
between fluorescence enhancement and spatial resolution and discuss the
requirements for deciphering single molecules in a dense sample. Resolutions
better than 20 nm and fluorescence enhancement up to 30 times are demonstrated
experimentally. By accounting for the tip shaft and the sample interface in
finite-difference time-domain calculations, we explain why the measured
fluorescence enhancements are higher in the presence of an interface than the
values predicted for a homogeneous environment.Comment: 10 pages, 3 figures. accepted for publication in Nano Letter
Measurements of atmospheric layers from the NASA DC-8 and P-3B aircraft during PEM-Tropics A
Tropospheric vertical structure was analyzed using in situ measurements of O₃, CO, CH₄, and H₂O taken on board the NASA DC-8 aircraft during three Pacific Exploratory Missions (PEMs): PEM-West A, September-October 1991 in the western Pacific; PEM-West B, February-March 1994 in the western Pacific; and PEM-Tropics A, September-October 1996 in the central and eastern Pacific. PEM-Tropics A added measurements from the NASA P3-B aircraft. We used a new mode-based method to define a background against which to find layers. Using only O₃ and H₂O, we found 472 layers in PEM-Tropics A (0.72 layers per vertical kilometer profiled), 237 layers in PEM-West A (0.54 layers/km), and 158 layers in PEM-West B (0.41 layers/km). Using all constituents, we found 187 layers in PEM-Tropics A (0.43 layers/km), 128 layers in PEM-West A (0.29 layers/km), and 80 layers in PEM-West B (0.21 layers/km). Stratospheric air, sometimes mixed with trapped pollution, was the dominant layer source in all three missions. The larger number of layers per kilometer in PEM-Tropics A was probably due to repeated profiling of several “superlayers” visible in many of the mission lidar and potential voracity profiles. The thickness of the superlayers was of order 1 km, and the horizontal extent was of order 1000 km. We found that layers have an important effect on the thermal structure. An example based on ozonesonde data from Tahiti is shown, where a dry, subsiding layer was stabilized by much greater radiative cooling at the base than at the top. The stabilized layer can trap pollution and force vertical plumes to spread into horizontal layers.United States. National Aeronautics and Space Administration (Grant NAG1-1758)United States. National Aeronautics and Space Administration (Grant NAG1-1901
Relativistic Calculation of two-Electron one-Photon and Hypersatellite Transition Energies for Elements
Energies of two-electron one-photon transitions from initial double K-hole
states were computed using the Dirac-Fock model. The transition energies of
competing processes, the K hypersatellites, were also computed. The
results are compared to experiment and to other theoretical calculations.Comment: accepted versio
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