Optical Control of Field-Emission Sites by Femtosecond Laser Pulses

We have investigated field emission patterns from a clean tungsten tip apex induced by femtosecond laser pulses. Strongly asymmetric modulations of the field emission intensity distributions are observed depending on the polarization of the light and the laser incidence direction relative to the azimuthal orientation of tip apex. In effect, we have realized an ultrafast pulsed field-emission source with site selectivity on the 10 nm scale. Simulations of local fields on the tip apex and of electron emission patterns based on photo-excited nonequilibrium electron distributions explain our observations quantitatively.Comment: 4 pages, submitted to Physical Review Letter

On the Nature of Black Holes in Loop Quantum Gravity

A genuine notion of black holes can only be obtained in the fundamental framework of quantum gravity resolving the curvature singularities and giving an account of the statistical mechanical, microscopic degrees of freedom able to explain the black hole thermodynamical properties. As for all quantum systems, a quantum realization of black holes requires an operator algebra of the fundamental observables of the theory which is introduced in this study based on aspects of loop quantum gravity. From the eigenvalue spectra of the quantum operators for the black hole area, charge and angular momentum, it is demonstrated that a strict bound on the extensive parameters, different from the relation arising in classical general relativity, holds, implying that the extremal black hole state can neither be measured nor can its existence be proven. This is, as turns out, a result of the specific form of the chosen angular momentum operator and the corresponding eigenvalue spectrum, or rather the quantum measurement process of angular momentum. Quantum mechanical considerations and the lowest, non-zero eigenvalue of the loop quantum gravity black hole mass spectrum indicate, on the one hand, a physical Planck scale cutoff of the Hawking temperature law and, on the other hand, give upper and lower bounds on the numerical value of the Immirzi parameter. This analysis provides an approximative description of the behavior and the nature of quantum black holes

Polyhedra in loop quantum gravity

Interwiners are the building blocks of spin-network states. The space of intertwiners is the quantization of a classical symplectic manifold introduced by Kapovich and Millson. Here we show that a theorem by Minkowski allows us to interpret generic configurations in this space as bounded convex polyhedra in Euclidean space: a polyhedron is uniquely described by the areas and normals to its faces. We provide a reconstruction of the geometry of the polyhedron: we give formulas for the edge lengths, the volume and the adjacency of its faces. At the quantum level, this correspondence allows us to identify an intertwiner with the state of a quantum polyhedron, thus generalizing the notion of quantum tetrahedron familiar in the loop quantum gravity literature. Moreover, coherent intertwiners result to be peaked on the classical geometry of polyhedra. We discuss the relevance of this result for loop quantum gravity. In particular, coherent spin-network states with nodes of arbitrary valence represent a collection of semiclassical polyhedra. Furthermore, we introduce an operator that measures the volume of a quantum polyhedron and examine its relation with the standard volume operator of loop quantum gravity. We also comment on the semiclassical limit of spinfoams with non-simplicial graphs.Comment: 32 pages, many figures. v2 minor correction

Measurements of the reaction pˉp→ϕη\bar{p}p \to \phi \eta of antiproton annihilation at rest at three hydrogen target densities

The proton-antiproton annihilation at rest into the $\phi\eta$ final state was measured for three different target densities: liquid hydrogen, gaseous hydrogen at NTP and at a low pressure of 5 mbar. The yield of this reaction in the liquid hydrogen target is smaller than in the low-pressure gas target. The branching ratios of the $\phi\eta$ channel were calculated on the basis of simultaneous analysis of the three data samples. The branching ratio for annihilation into $\phi\eta$ from the $^3S_1$ protonium state turns out to be about ten times smaller as compared to the one from the $^1P_1$ state.Comment: 10 pages, 3 Postscript figures. Accepted by Physics Letters

Asymptotic safety guaranteed

We study the ultraviolet behaviour of four-dimensional quantum field theories involving non-abelian gauge fields, fermions and scalars in the Veneziano limit. In a regime where asymptotic freedom is lost, we explain how the three types of fields cooperate to develop fully interacting ultraviolet fixed points, strictly controlled by perturbation theory. Extensions towards strong coupling and beyond the large-N limit are discussed

Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles

A continuing goal in catalysis is the transformation of processes from homogeneous to heterogeneous. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this conversion is supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of electrophilic platinum nanoparticles. These nanoparticles are selectively oxidized by the hypervalent iodine species PhICl{sub 2}, and catalyze a range of {pi}-bond activation reactions previously only homogeneously catalyzed. Multiple experimental methods are utilized to unambiguously verify the heterogeneity of the catalytic process. The discovery of treatments for nanoparticles that induce the desired homogeneous catalytic activity should lead to the further development of reactions previously inaccessible in heterogeneous catalysis. Furthermore, our size and capping agent study revealed that Pt PAMAM dendrimer-capped nanoparticles demonstrate superior activity and recyclability compared to larger, polymer-capped analogues