134 research outputs found
Anomalous codeposition of cobalt and ruthenium from chloride-sulfate baths
Codeposition of Ru and Co was studied at room temperature and at 50oC with various Ru3+ and Co2+ concentrations in the electrolyte. The codeposition of Co and Ru proved to be anomalous since no pure Ru could be obtained in the presence of Co2+ in the electrolyte, but a significant Co incorporation into the deposit was detected at potentials where the deposition of pure Co was not possible. The composition of the deposits varied monotonously with the change of the concentration ratio of Co2+ and Ru3+. The deposition of Ru was much hindered and the current efficiency was a few percent only when the molar fraction of Co in the deposit was low. Continuous deposits could be obtained only when the molar fraction of Co in the deposit was at least 40 at.%. The deposit morphology was related to the molar fraction of Co in the deposit. The X-ray diffractograms are in conformity with a hexagonal close-packed alloy and indicate the formation of nanocrystalline deposits. Two-pulse plating did not lead to a multilayer but to a Co-rich alloy. Magnetoresistance of the samples decreased with increasing Ru content
THERMODYNAMICS OF A BROWNIAN BRIDGE POLYMER MODEL IN A RANDOM ENVIRONMENT
We consider a directed random walk making either 0 or moves and a
Brownian bridge, independent of the walk, conditioned to arrive at point on
time . The Hamiltonian is defined as the sum of the square of increments of
the bridge between the moments of jump of the random walk and interpreted as an
energy function over the bridge connfiguration; the random walk acts as the
random environment. This model provides a continuum version of a model with
some relevance to protein conformation. The thermodynamic limit of the specific
free energy is shown to exist and to be self-averaging, i.e. it is equal to a
trivial --- explicitly computed --- random variable. An estimate of the
asymptotic behaviour of the ground state energy is also obtained.Comment: 20 pages, uuencoded postscrip
Fundamentals of interface phenomena in advanced bulk nanoscale materials
The review is devoted to a study of interface phenomena influencing advanced properties of nanoscale materials processed by means of severe plastic deformation, high-energy ball milling and their combinations. Interface phenomena include processes of interface defect structure relaxation from a highly nonequilibrium state to an equilibrium condition, grain boundary phase transformations and enhanced grain boundary and triple junction diffusivity. On the basis of an experimental investigation, a theoretical description of the key interfacial phenomena controlling the functional properties of advanced bulk nanoscale materials has been conducted. An interface defect structure investigation has been performed by TEM, high-resolution x-ray diffraction, atomic simulation and modeling. The problem of a transition from highly non-equilibrium state to an equilibrium one, which seems to be responsible for low thermostability of nanoscale materials, was studied. Also enhanced grain boundary diffusivity is addressed. Structure recovery and dislocation emission from grain boundaries in nanocrystalline materials have been investigated by analytical methods and modeling
The maximum modulus of a trigonometric trinomial
Let Lambda be a set of three integers and let C_Lambda be the space of
2pi-periodic functions with spectrum in Lambda endowed with the maximum modulus
norm. We isolate the maximum modulus points x of trigonometric trinomials T in
C_Lambda and prove that x is unique unless |T| has an axis of symmetry. This
permits to compute the exposed and the extreme points of the unit ball of
C_Lambda, to describe how the maximum modulus of T varies with respect to the
arguments of its Fourier coefficients and to compute the norm of unimodular
relative Fourier multipliers on C_Lambda. We obtain in particular the Sidon
constant of Lambda
Recurrence of biased quantum walks on a line
The Polya number of a classical random walk on a regular lattice is known to
depend solely on the dimension of the lattice. For one and two dimensions it
equals one, meaning unit probability to return to the origin. This result is
extremely sensitive to the directional symmetry, any deviation from the equal
probability to travel in each direction results in a change of the character of
the walk from recurrent to transient. Applying our definition of the Polya
number to quantum walks on a line we show that the recurrence character of
quantum walks is more stable against bias. We determine the range of parameters
for which biased quantum walks remain recurrent. We find that there exist
genuine biased quantum walks which are recurrent.Comment: Journal reference added, minor corrections in the tex
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